Electro-deposition of the lithium metal anode on dendritic copper current collectors for lithium battery application

2020 ◽  
Vol 506 ◽  
pp. 144884 ◽  
Author(s):  
Bit Na Choi ◽  
Jung Yong Seo ◽  
Byeongkyu Kim ◽  
Yong Seok Kim ◽  
Chan-Hwa Chung
2019 ◽  
Vol 7 (11) ◽  
pp. 6267-6274 ◽  
Author(s):  
Wei Deng ◽  
Shanshan Liang ◽  
Xufeng Zhou ◽  
Fei Zhao ◽  
Wenhua Zhu ◽  
...  

An ultrathin and conformal ion conductive coating is realized on 3D current collectors for preventing the irreversible reaction between the electrolyte and Li metal, which has been confirmed by in situ optical observation. At the high areal capacity of 10 mA h cm−2 for the Li metal anode, a stable CE of 98.9% for 800 h can be achieved.


2011 ◽  
Vol 196 (18) ◽  
pp. 7750-7754 ◽  
Author(s):  
Masashi Kotobuki ◽  
Kiyoshi Kanamura ◽  
Yosuke Sato ◽  
Toshihiro Yoshida

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 300
Author(s):  
Jin Lou ◽  
Kanghua Chen ◽  
Nachuan Yang ◽  
Yi Shuai ◽  
Changjun Zhu

Lithium metal anode still confronts a series of problems at the way to commercialization though it has advantages in high energy density. The formation of Li dendrite is the major limitation need to be conquered. Here, a facile and simple LiSn alloy anode prepared by a direct metallurgy method is fabricated and evaluated in both liquid electrolyte and solid electrolyte. Structural analysis and electrochemical measurements reveal the promoted ionic transference of interface and enhanced cycling stability in different electrolyte systems, without dendrite formation. Furthermore, the application of this simple and sustainable LiSn alloy can be extended to more alloy anode and might unlock the next-generation anode in the future.


2021 ◽  
pp. 2009917
Author(s):  
Kun Wang ◽  
Xiaodong Li ◽  
Juan Gao ◽  
Quanhu Sun ◽  
Ze Yang ◽  
...  

Small Methods ◽  
2021 ◽  
pp. 2001035
Author(s):  
Zhiyuan Han ◽  
Chen Zhang ◽  
Qiaowei Lin ◽  
Yunbo Zhang ◽  
Yaqian Deng ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wei Guo ◽  
Wanying Zhang ◽  
Yubing Si ◽  
Donghai Wang ◽  
Yongzhu Fu ◽  
...  

AbstractThe interfacial instability of the lithium-metal anode and shuttling of lithium polysulfides in lithium-sulfur (Li-S) batteries hinder the commercial application. Herein, we report a bifunctional electrolyte additive, i.e., 1,3,5-benzenetrithiol (BTT), which is used to construct solid-electrolyte interfaces (SEIs) on both electrodes from in situ organothiol transformation. BTT reacts with lithium metal to form lithium 1,3,5-benzenetrithiolate depositing on the anode surface, enabling reversible lithium deposition/stripping. BTT also reacts with sulfur to form an oligomer/polymer SEI covering the cathode surface, reducing the dissolution and shuttling of lithium polysulfides. The Li–S cell with BTT delivers a specific discharge capacity of 1,239 mAh g−1 (based on sulfur), and high cycling stability of over 300 cycles at 1C rate. A Li–S pouch cell with BTT is also evaluated to prove the concept. This study constructs an ingenious interface reaction based on bond chemistry, aiming to solve the inherent problems of Li–S batteries.


2021 ◽  
Author(s):  
Yuping Wu ◽  
Xiaosong Xiong ◽  
Ruoyu Zhi ◽  
Qi Zhou ◽  
Wenqi Yan ◽  
...  

Metallic lithium is an promising next generation electrode material due to its ultrahigh specific capacity and the lowest potential. However, short cycling lifespan and safety hazards have hindered the practical...


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