Rational design of novel 3D flower-like praseodymium molybdate anchored graphitic carbon Nitride: An efficient and sustainable photocatalyst for mitigation of carcinogenic pollutants

2021 ◽  
Vol 569 ◽  
pp. 151104
Author(s):  
K. Prakash ◽  
V. Selvam ◽  
S. Ganesh Babu ◽  
S. Meena ◽  
S. Karuthapandian
Keyword(s):  
Rational Design ◽  
Carbon Nitride ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride

scholarly journals Graphitic Carbon Nitride Materials for Photocatalytic Hydrogen Production via Water Splitting: A Short Review

Catalysts ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 805 ◽  
Author(s):  
Seong Jun Mun ◽  
Soo-Jin Park
Keyword(s):  
Hydrogen Production ◽  
Water Splitting ◽  
Rational Design ◽  
Carbon Nitride ◽  
Clean Energy ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Future Research ◽  
Metal Doping ◽  
Photocatalytic Hydrogen Production

The generation of photocatalytic hydrogen via water splitting under light irradiation is attracting much attention as an alternative to solve such problems as global warming and to increase interest in clean energy. However, due to the low efficiency and selectivity of photocatalytic hydrogen production under solar energy, a major challenge persists to improve the performance of photocatalytic hydrogen production through water splitting. In recent years, graphitic carbon nitride (g-C3N4), a non-metal photocatalyst, has emerged as an attractive material for photocatalytic hydrogen production. However, the fast recombination of photoexcited electron–hole pairs limits the rate of hydrogen evolution and various methods such as modification, heterojunctions with semiconductors, and metal and non-metal doping have been applied to solve this problem. In this review, we cover the rational design of g-C3N4-based photocatalysts achieved using methods such as modification, metal and non-metal doping, and heterojunctions, and we summarize recent achievements in their application as hydrogen production photocatalysts. In addition, future research and prospects of hydrogen-producing photocatalysts are also reviewed.

Visible-Light-Responsive Graphitic Carbon Nitride: Rational Design and Photocatalytic Applications for Water Treatment

2016 ◽  
Vol 50 (23) ◽  
pp. 12938-12948 ◽  
Author(s):  
Qinmin Zheng ◽  
David P. Durkin ◽  
Justin E. Elenewski ◽  
Yingxue Sun ◽  
Nathan A. Banek ◽  
...  
Keyword(s):  
Water Treatment ◽  
Visible Light ◽  
Rational Design ◽  
Carbon Nitride ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Photocatalytic Applications

Metal Doped-C3N4/Fe2O4: Efficient and Versatile Heterogenous Catalysts for Organic Transformations

2019 ◽  
Vol 23 (12) ◽  
pp. 1284-1306
Author(s):  
Vijai K. Rai ◽  
Fooleswar Verma ◽  
Suhasini Mahata ◽  
Smita R. Bhardiya ◽  
Manorama Singh ◽  
...  
Keyword(s):  
Ring Opening ◽  
Carbon Nitride ◽  
Addition Reaction ◽  
High Surface ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Organic Transformations ◽  
Reduction Reactions ◽  
Activation Reaction ◽  
Metal Doped

The polymeric graphitic carbon nitride (g-C3N4) has been one of the interesting earth abundant elements. Though g-C3N4 finds application as a photocatalyst, its photocatalytic behaviour is limited because of low efficiency, mainly due to rapid charge recombination. To overcome this problem, several strategies have been developed including doping of metal/non-metal in the cavity of g-C3N4. Moreover, the CoFe2O4 NPs have been used in many organic transformations because of its high surface area and easy separation due to its magnetic nature. This review describes the role of cobalt ferrite as magnetic nanoparticles and metal-doped carbon nitride as efficient heterogeneous catalysts for new carbon-carbon and carbon-hetero atom bond formation followed by heterocyclization. Reactions which involved new catalysts for selective activation of readily available substrates has been reported herein. Since nanoparticles enhance the reactivity of catalyst due to higher catalytic area, they have been employed in various reactions such as addition reaction, C-H activation reaction, coupling reaction, cyclo-addition reaction, multi-component reaction, ring-opening reaction, oxidation reaction and reduction reactions etc. The driving force for choosing this topic is based-on huge number of good publications including different types of spinels/metal doped-/graphitic carbon nitride reported in the literature and due to interest of synthetic community in recent years. This review certainly will represent the present status in organic transformation and for exploring further their catalytic efficiency to new organic transformations involving C-H activation reaction through coupling, cyclo-addition, multi-component, ring-opening, oxidation and reduction reactions.

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