Recyclable and Reprocessable Epoxy-Polyhedral Oligomeric Silsesquioxane (POSS)/Mesogenic Azobenzene/Poly (ethylene-co-vinyl acetate) Composites with Thermal- and Light-responsive Programmable Shape-memory Performance

A POSS–PCL shape memory network is synthesized. The cage-like POSS not only serves as a chemical netpoint, also causes improvement in mechanical properties. Optimized networks exhibit both excellent tensile strength and nearly complete recovery.

Download Full-text

Nanoscale considerations responsible for diverse macroscopic phase behavior in monosubstituted isobutyl-POSS/poly(ethylene oxide) blends

Soft Matter ◽

10.1039/c7sm01788j ◽

2017 ◽

Vol 13 (46) ◽

pp. 8672-8677 ◽

Cited By ~ 4

Author(s):

Yavuz Caydamli ◽

Erol Yildirim ◽

Jialong Shen ◽

Xiaomeng Fang ◽

Melissa A. Pasquinelli ◽

...

Keyword(s):

Ethylene Oxide ◽

Phase Behavior ◽

Hybrid Materials ◽

Polyhedral Oligomeric Silsesquioxane ◽

Polymer Matrices ◽

Poly Ethylene Oxide ◽

Poly Ethylene ◽

Oligomeric Silsesquioxane

Nanocomposites prepared by incorporating polyhedral oligomeric silsesquioxane (POSS) into polymer matrices afford versatile hybrid materials but are exquisitely sensitive to even POSS monofunctionalization.

Download Full-text

Poly(ethylene glycol)-polyhedral oligomeric silsesquioxane as a novel plasticizer and thermal stabilizer for poly(vinyl chloride) nanocomposites

Polymer International ◽

10.1002/pi.5166 ◽

2016 ◽

Vol 65 (10) ◽

pp. 1172-1178 ◽

Cited By ~ 6

Author(s):

Shuyan Yang ◽

Wenjian Wu ◽

Yuanqi Jiao ◽

Hongbo Fan ◽

Zhuodi Cai

Keyword(s):

Ethylene Glycol ◽

Vinyl Chloride ◽

Polyhedral Oligomeric Silsesquioxane ◽

Poly Ethylene Glycol ◽

Thermal Stabilizer ◽

Poly Vinyl Chloride ◽

Poly Ethylene ◽

Oligomeric Silsesquioxane

Download Full-text

Tunable shape memory behaviors of poly(ethylene vinyl acetate) achieved by adding poly(L-lactide)

Smart Materials and Structures ◽

10.1088/0964-1726/24/12/125002 ◽

2015 ◽

Vol 24 (12) ◽

pp. 125002 ◽

Cited By ~ 12

Author(s):

Zhi-xing Zhang ◽

Fei Liao ◽

Zhen-zhen He ◽

Jing-hui Yang ◽

Ting Huang ◽

...

Keyword(s):

Shape Memory ◽

Vinyl Acetate ◽

Ethylene Vinyl Acetate ◽

Poly Ethylene

Download Full-text

Biobased multiblock copolymers: Synthesis, properties and shape memory performance of poly(ethylene 2,5-furandicarboxylate)-b-poly(ethylene glycol)

Polymer Degradation and Stability ◽

10.1016/j.polymdegradstab.2017.07.032 ◽

2017 ◽

Vol 144 ◽

pp. 121-127 ◽

Cited By ~ 29

Author(s):

Guoqiang Wang ◽

Min Jiang ◽

Qiang Zhang ◽

Rui Wang ◽

Guangyuan Zhou

Keyword(s):

Ethylene Glycol ◽

Shape Memory ◽

Memory Performance ◽

Multiblock Copolymers ◽

Poly Ethylene Glycol ◽

Synthesis Properties ◽

Poly Ethylene

Download Full-text

Crystallization derivation of amine functionalized T 12 polyhedral oligomeric silsesquioxane-conjugated poly(ethylene terephthalate)

Composites Science and Technology ◽

10.1016/j.compscitech.2017.04.015 ◽

2017 ◽

Vol 146 ◽

pp. 42-48 ◽

Cited By ~ 6

Author(s):

Albert S. Lee ◽

Hyeonyeol Jeon ◽

Seung-Sock Choi ◽

Jeyoung Park ◽

Sung Yeon Hwang ◽

...

Keyword(s):

Ethylene Terephthalate ◽

Polyhedral Oligomeric Silsesquioxane ◽

Amine Functionalized ◽

Poly Ethylene Terephthalate ◽

Poly Ethylene ◽

Oligomeric Silsesquioxane

Download Full-text

Polyethylene telechelics with POSS termini: synthesis, morphologies and shape memory properties

Polymer Chemistry ◽

10.1039/d0py01120g ◽

2020 ◽

Vol 11 (36) ◽

pp. 5819-5832

Author(s):

Bingjie Zhao ◽

Honggang Mei ◽

Sixun Zheng

Keyword(s):

Shape Memory ◽

Ring Opening ◽

Polyhedral Oligomeric Silsesquioxane ◽

Acyclic Diene Metathesis ◽

Ring Opening Metathesis Polymerization ◽

Metathesis Polymerization ◽

Shape Memory Properties ◽

Hydrogenation Reactions ◽

Diene Metathesis ◽

Oligomeric Silsesquioxane

Organic–inorganic polyethylene (PE) telechelics with polyhedral oligomeric silsesquioxane termini were synthesized via the combination of acyclic diene metathesis, ring-opening metathesis polymerization and hydrogenation reactions.

Download Full-text