Visible light assisted activation of peroxymonosulfate by bimetallic MOF based heterojunction MIL-53(Fe/Co)/CeO2 for Atrazine degradation: pivotal roles of dual redox cycle for reactive species generation

2021 ◽  
pp. 133069
Author(s):  
Debashis Roy ◽  
Sudarsan Neogi ◽  
Sirshendu De
RSC Advances ◽  
2017 ◽  
Vol 7 (81) ◽  
pp. 51046-51054 ◽  
Author(s):  
Jing Wu ◽  
Jian Li ◽  
Jin Liu ◽  
Jin Bai ◽  
Lina Yang

A novel Nb2O5/Bi2WO6 heterojunction catalyst was synthesized and applied in PODS of DBT. It shows higher activity than pure Nb2O5 and Bi2WO6 in visible light induced PODS of DBT, in which holes and superoxide radicals are the main reactive species.


2018 ◽  
Vol 6 (12) ◽  
pp. 4997-5005 ◽  
Author(s):  
Hongli Sun ◽  
Ho Yin Yip ◽  
Zhifeng Jiang ◽  
Liqun Ye ◽  
Irene M. C. Lo ◽  
...  

Oxygen deficient yolk–shell BiO2−x microspheres prepared by facile solvothermal method showed great inactivation ability toward Escherichia coli, due to its enhanced light absorption ability and separation ability of photoinduced carriers. Reactive species O2− and H2O2 guaranteed this prominent oxidation ability toward bacterial cells.


2016 ◽  
Vol 120 (34) ◽  
pp. 19242-19251 ◽  
Author(s):  
Shaonan Gu ◽  
Wenjun Li ◽  
Yongzhong Bian ◽  
Fangzhi Wang ◽  
Hongda Li ◽  
...  

2016 ◽  
Vol 45 (8) ◽  
pp. 2044-2056 ◽  
Author(s):  
Jia-Rong Chen ◽  
Xiao-Qiang Hu ◽  
Liang-Qiu Lu ◽  
Wen-Jing Xiao

Radicals are an important class of versatile and highly reactive species.


2019 ◽  
Vol 9 (16) ◽  
pp. 4413-4421 ◽  
Author(s):  
Xubo Huang ◽  
Jianjun Zhao ◽  
Xianqiang Xiong ◽  
Shengwei Liu ◽  
Yiming Xu

Catalyst activity is notably enhanced on simple addition of Fe3+ ions. The reaction is fast initially and then becomes slow, but the formation of reactive species is accelerated even in the slow process.


2015 ◽  
Vol 39 (12) ◽  
pp. 9242-9248 ◽  
Author(s):  
Manu Sharma ◽  
Kasinath Ojha ◽  
Aparna Ganguly ◽  
Ashok K. Ganguli

Light irradiation on Ag3PO4 decorated SiO2 generates three reactive species (˙OH, O2−˙, and hole) leading to efficient photocatalysis.


2012 ◽  
Vol 2012 ◽  
pp. 1-10 ◽  
Author(s):  
Douga Nassoko ◽  
Yan-Fang Li ◽  
Jia-Lin Li ◽  
Xi Li ◽  
Ying Yu

Titanium dioxide (TiO2) doped with neodymium (Nd), one rare earth element, has been synthesized by a sol-gel method for the photocatalytic degradation of rhodamine-B under visible light. The prepared samples are characterized by X-ray diffractometer, Raman spectroscopy, UV-Vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, and Brunauer-Emmett-Teller measurement. The results indicate that the prepared samples have anatase and brookite phases. Additionally, Nd as Nd3+may enter into the lattice ofTiO2and the presence of Nd3+substantially enhances the photocatalytic activity ofTiO2under visible light. In order to further explore the mechanism of photocatalytic degradation of organic pollutant, photoluminescence spectrometer and scavenger addition method have been employed. It is found that hydroxide radicals produced by Nd-dopedTiO2under visible light are one of reactive species for Rh-B degradation and photogenerated electrons are mainly responsible for the formation of the reactive species.


2018 ◽  
Vol 163 ◽  
pp. 620-628 ◽  
Author(s):  
Tarek S. Jamil ◽  
H.A. Abbas ◽  
Rabab A. Nasr ◽  
Rose-Noëlle Vannier

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