Incorporation of Mg and Cu metals to CoFe2O4 catalyst: Characterization and methane cracking performance for hydrogen and nano-carbon production

Author(s):  
Abdulrahman I. Alharthi ◽  
Mshari A. Alotaibi ◽  
Israf Ud Din ◽  
E. Abdel-Fattah ◽  
Md Afroz Bakht ◽  
...  
RSC Advances ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 1463-1475 ◽  
Author(s):  
Mohammad Amin Nazem ◽  
Masoud Habibi Zare ◽  
Saeed Shirazian

Production of activated nano-carbon from agricultural wastes was studied in this work.


Author(s):  
P.A. Crozier ◽  
M. Pan

Heterogeneous catalysts can be of varying complexity ranging from single or double phase systems to complicated mixtures of metals and oxides with additives to help promote chemical reactions, extend the life of the catalysts, prevent poisoning etc. Although catalysis occurs on the surface of most systems, detailed descriptions of the microstructure and chemistry of catalysts can be helpful for developing an understanding of the mechanism by which a catalyst facilitates a reaction. Recent years have seen continued development and improvement of various TEM, STEM and AEM techniques for yielding information on the structure and chemistry of catalysts on the nanometer scale. Here we review some quantitative approaches to catalyst characterization that have resulted from new developments in instrumentation.HREM has been used to examine structural features of catalysts often by employing profile imaging techniques to study atomic details on the surface. Digital recording techniques employing slow-scan CCD cameras have facilitated the use of low-dose imaging in zeolite structure analysis and electron crystallography. Fig. la shows a low-dose image from SSZ-33 zeolite revealing the presence of a stacking fault.


Author(s):  
Cristian Cocconcelli ◽  
Bongsuk Park ◽  
Jian Zou ◽  
George Lopp ◽  
Reynaldo Roque

Reflective cracking is frequently reported as the most common distress affecting resurfaced pavements. An asphalt rubber membrane interlayer (ARMI) approach has been traditionally used in Florida to mitigate reflective cracking. However, recent field evidence has raised doubts about the effectiveness of the ARMI when placed near the surface, indicating questionable benefits to reflective cracking and increased instability rutting potential. The main purpose of this research was to develop guidelines for an effective alternative to the ARMI for mitigation of near-surface reflective cracking in overlays on asphalt pavement. Fourteen interlayer mixtures, covering three aggregate types widely used in Florida, and two nominal maximum aggregate sizes (NMAS) were designed according to key characteristics identified for mitigation of reflective cracking, that is, sufficient gradation coarseness and high asphalt content. The dominant aggregate size range—interstitial component (DASR-IC) model was used for the design of all mixture gradations. A composite specimen interface cracking (CSIC) test was employed to evaluate reflective cracking performance of interlayer systems. In addition, asphalt pavement analyzer (APA) tests were performed to determine whether the interlayer mixtures had sufficient rutting resistance. The results indicated that interlayer mixtures designed with lower compaction effort, reduced design air voids, and coarser gradation led to more cost-effective fracture-tolerant and shear-resistant (FTSR) interlayers. Therefore, preliminary design guidelines including minimum effective film thickness and maximum DASR porosity requirements were proposed for 9.5-mm NMAS (35 µm and 50%) and 4.75-mm NMAS FTSR mixtures (20 µm and 60%) to mitigate near-surface reflective cracking.


Sign in / Sign up

Export Citation Format

Share Document