Lithium, boron and lead isotope and trace element systematics of Quaternary basaltic volcanic rocks in northeastern Japan: mineralogical controls on slab-derived fluid composition

2004 ◽  
Vol 212 (1-2) ◽  
pp. 81-100 ◽  
Author(s):  
Takuya Moriguti ◽  
Tomoyuki Shibata ◽  
Eizo Nakamura
2021 ◽  
pp. 1-26
Author(s):  
Taylor A. Ducharme ◽  
Christopher R.M. McFarlane ◽  
Deanne van Rooyen ◽  
David Corrigan

Abstract The Flowers River Igneous Suite of north-central Labrador comprises several discrete peralkaline granite ring intrusions and their coeval volcanic succession. The Flowers River Granite was emplaced into Mesoproterozoic-age anorthosite–mangerite–charnockite–granite (AMCG) -affinity rocks at the southernmost extent of the Nain Plutonic Suite coastal lineament batholith. New U–Pb zircon geochronology is presented to clarify the timing and relationships among the igneous associations exposed in the region. Fayalite-bearing AMCG granitoids in the region record ages of 1290 ± 3 Ma, whereas the Flowers River Granite yields an age of 1281 ± 3 Ma. Volcanism occurred in three discrete events, two of which coincided with emplacement of the AMCG and Flowers River suites, respectively. Shared geochemical affinities suggest that each generation of volcanic rocks was derived from its coeval intrusive suite. The third volcanic event occurred at 1271 ± 3 Ma, and its products bear a broad geochemical resemblance to the second phase of volcanism. The surrounding AMCG-affinity ferrodiorites and fayalite-bearing granitoids display moderately enriched major- and trace-element signatures relative to equivalent lithologies found elsewhere in the Nain Plutonic Suite. Trace-element compositions also support a relationship between the Flowers River Granite and its AMCG-affinity host rocks, most likely via delayed partial melting of residual parental material in the lower crust. Enrichment manifested only in the southernmost part of the Nain Plutonic Suite as a result of its relative proximity to multiple Palaeoproterozoic tectonic boundaries. Repeated exposure to subduction-derived metasomatic fluids created a persistent region of enrichment in the underlying lithospheric mantle that was tapped during later melt generation, producing multiple successive moderately to strongly enriched magmatic episodes.


1991 ◽  
Vol 86 (10) ◽  
pp. 459-472 ◽  
Author(s):  
Keiichi Shiraki ◽  
Kenji Nagao ◽  
Takashi Nagao ◽  
Susumu Kakubuchi ◽  
Yukio Matsumoto
Keyword(s):  

1983 ◽  
Vol 47 (345) ◽  
pp. 473-479 ◽  
Author(s):  
D. K. Hallbauer ◽  
K. von Gehlen

AbstractEvidence obtained from morphological and extensive trace element studies, and from the examination of mineral and fluid inclusions in Witwatersrand pyrites, shows three major types of pyrite: (i) detrital pyrite (rounded pyrite crystals transported into the depositional environment); (ii) synsedimentary pyrite (round and rounded aggregates of fine-grained pyrite formed within the depositional environmen); and (iii) authigenic pyrite (newly crystallized and/or recrystallized pyrite formed after deposition). The detrital grains contain mineral inclusions such as biotite, feldspar, apatite, zircon, sphene, and various ore minerals, and fluid inclusions with daughter minerals. Most of the inclusions are incompatible with an origin by sulphidization. Recrystallized authigenic pyrite occurs in large quantities but only in horizons or localities which have been subjected to higher temperatures during the intrusion or extrusion of younger volcanic rocks. Important additional findings are the often substantial amounts of pyrite and small amounts of particles of gold found in Archaean granites (Hallbauer, 1982) as possible source rocks for the Witwatersrand detritus. Large differences in Ag and Hg content between homogeneous single gold grains within a hand specimen indicate a lack of metamorphic homogenization. The influence of metamorphism on the Witwatersrand pyrites can therefore be described as only slight and generally negligible.


1984 ◽  
Vol 18 (6) ◽  
pp. 287-295 ◽  
Author(s):  
Mitsuru Ebihara ◽  
Yuji Nakamura ◽  
Hiroshi Wakita ◽  
Hajime Kurasawa ◽  
Tadashi Konda

Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 588
Author(s):  
Indrani Mukherjee ◽  
Mihir Deb ◽  
Ross R. Large ◽  
Jacqueline Halpin ◽  
Sebastien Meffre ◽  
...  

The Vindhyan Basin in central India preserves a thick (~5 km) sequence of sedimentary and lesser volcanic rocks that provide a valuable archive of a part of the Proterozoic (~1800–900 Ma) in India. Here, we present an analysis of key sedimentary pyrite textures and their trace element and sulfur isotope compositions in the Bijaigarh Shale (1210 ± 52 Ma) in the Vindhyan Supergroup, using reflected light microscopy, LA-ICP-MS and SHRIMP-SI, respectively. A variety of sedimentary pyrite textures (fine-grained disseminated to aggregates, framboids, lags, and possibly microbial pyrite textures) are observed reflecting quiet and strongly anoxic water column conditions punctuated by occasional high-energy events (storm incursions). Key redox sensitive or sensitive to oxidative weathering trace elements (Co, Ni, Zn, Mo, Se) and ratios of (Se/Co, Mo/Co, Zn/Co) measured in sedimentary pyrites from the Bijaigarh Shale are used to infer atmospheric redox conditions during its deposition. Most trace elements are depleted relative to Proterozoic mean values. Sulfur isotope compositions of pyrite, measured using SHRIMP-SI, show an increase in δ34S as we move up stratigraphy with positive δ34S values ranging from 5.9‰ (lower) to 26.08‰ (upper). We propose limited sulphate supply caused the pyrites to incorporate the heavier isotope. Overall, we interpret these low trace element signatures and heavy sulfur isotope compositions to indicate relatively suppressed oxidative weathering on land during the deposition of the Bijaigarh Shale.


Author(s):  
S. S. Goldich ◽  
J. S. Stuckless ◽  
N. H. Suhr ◽  
J. B. Bodkin ◽  
R. C. Wamser
Keyword(s):  

Minerals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 319 ◽  
Author(s):  
Sergei Rasskazov ◽  
Yi-Min Sun ◽  
Irina Chuvashova ◽  
Tatyana Yasnygina ◽  
Chen Yang ◽  
...  

In the Wudalianchi volcanic field, eruptions started with low-Mg potassic lava flows 2.5–2.0 Ma ago and later changed to both low- and moderate-Mg potassic compositions. Volcanic rocks from the Molabushan and Longmenshan volcanoes record an unusually wide range of Pb abundances (from 3.7 ppm to 21 ppm relative to predominant range of 10–15 ppm). To determine the cause of these, we performed a comparative trace-element and Pb isotope study of rocks from these volcanoes and older lava flows. On a uranogenic lead diagram, older low-Mg lavas from lithospheric mantle sources plot on a secondary isochron with a slope corresponding to an age of 1.88 Ga. This contrasts with moderate-Mg volcanic rocks from the Molabushan cone, interpreted to have been derived from a recent convective mantle source, which define a flat linear pattern. Low-Mg rocks from the Molabushan flow have lead isotopic compositions that indicate mixed Gelaqiu and Molabu sources. Relative to rocks from the Molabushan cone, moderate-Mg lavas and slags from the East Longmenshan volcano have modified compositions characterized by Pb, S, and Ni abundances, Ni/Co, Ni/MgO ratios as well as 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, Ce/Pb, Th/Pb, and U/Pb ratios. We infer that the older Wudalianchi magmas were likely derived from a Paleoproterozoic lithospheric fragment, related to the evolved primordial mantle, and that later magmas were generated in the convecting mantle. These were influenced by segregation of small amounts of sulfides.


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