Petrogenesis of the peralkaline Flowers River Igneous Suite and its significance to the development of the southern Nain Batholith

2021 ◽  
pp. 1-26
Author(s):  
Taylor A. Ducharme ◽  
Christopher R.M. McFarlane ◽  
Deanne van Rooyen ◽  
David Corrigan

Abstract The Flowers River Igneous Suite of north-central Labrador comprises several discrete peralkaline granite ring intrusions and their coeval volcanic succession. The Flowers River Granite was emplaced into Mesoproterozoic-age anorthosite–mangerite–charnockite–granite (AMCG) -affinity rocks at the southernmost extent of the Nain Plutonic Suite coastal lineament batholith. New U–Pb zircon geochronology is presented to clarify the timing and relationships among the igneous associations exposed in the region. Fayalite-bearing AMCG granitoids in the region record ages of 1290 ± 3 Ma, whereas the Flowers River Granite yields an age of 1281 ± 3 Ma. Volcanism occurred in three discrete events, two of which coincided with emplacement of the AMCG and Flowers River suites, respectively. Shared geochemical affinities suggest that each generation of volcanic rocks was derived from its coeval intrusive suite. The third volcanic event occurred at 1271 ± 3 Ma, and its products bear a broad geochemical resemblance to the second phase of volcanism. The surrounding AMCG-affinity ferrodiorites and fayalite-bearing granitoids display moderately enriched major- and trace-element signatures relative to equivalent lithologies found elsewhere in the Nain Plutonic Suite. Trace-element compositions also support a relationship between the Flowers River Granite and its AMCG-affinity host rocks, most likely via delayed partial melting of residual parental material in the lower crust. Enrichment manifested only in the southernmost part of the Nain Plutonic Suite as a result of its relative proximity to multiple Palaeoproterozoic tectonic boundaries. Repeated exposure to subduction-derived metasomatic fluids created a persistent region of enrichment in the underlying lithospheric mantle that was tapped during later melt generation, producing multiple successive moderately to strongly enriched magmatic episodes.

1985 ◽  
Vol 22 (7) ◽  
pp. 1048-1065 ◽  
Author(s):  
R. A. Frith ◽  
B. J. Fryer

The Regan Intrusive Suite of about 100 plutons of tonalite, granodiorite, and quartz diorite intruded the Yellowknife Supergroup and migmatite terrain in the northwest Slave Structural Province 2.59 Ga ago. Rare-earth-element (REE), trace-element, and major-element analyses from 39 representative whole rocks from the suite suggest it was derived by batch melting of the crust, producing a parental magma of tonalitic or granodioritic composition. By analysing REE from different parts of a zoned pluton, it was concluded that REE distribution was controlled by early separation of quartz diorite from the parent magma by flow differentiation and that the bulk of the REE were contained in early, cumulate, accessory apatite and monazite. The residual magma was further fractionated in pipelike magma chambers during ascent into more leucocratic rocks. Chondrite-normalized REE patterns of single-lithology plutons are similar to lithologies in zoned plutons, and it is proposed they initially segregated during ascent. It was found that granites, which were formerly grouped with the suite, formed in three ways, only one of which is related to the Regan Intrusive Suite.Study of 2.67 Ga old synvolcanic tonalite pluton revealed a strong covariance of light REE with those of the bimodal, calc-alkaline Hackett River Group of volcanic rocks. The data imply a common crustal source, but mass balance requires larger volumes of felsic volcanic rocks than are presently preserved, suggesting that much of the erupted felsic pyroclastic rocks were eroded. Partial melts from synvolcanic tonalite during subsequent regional metamorphism differentially depleted host rocks in REE and concentrated Eu and heavy rare-earth elements (HREE) in trondhjemite pegmatites.


Author(s):  
Mikael Vasilopoulos ◽  
Ferenc Molnár ◽  
Hugh O’Brien ◽  
Yann Lahaye ◽  
Marie Lefèbvre ◽  
...  

AbstractThe Juomasuo Au–Co deposit, currently classified as an orogenic gold deposit with atypical metal association, is located in the Paleoproterozoic Kuusamo belt in northeastern Finland. The volcano-sedimentary sequence that hosts the deposit was intensely altered, deformed, and metamorphosed to greenschist facies during the 1.93–1.76 Ga Svecofennian orogeny. In this study, we investigate the temporal relationship between Co and Au deposition and the relationship of metal enrichment with protolith composition and alteration mineralogy by utilizing lithogeochemical data and petrographic observations. We also investigate the nature of fluids involved in deposit formation based on sulfide trace element and sulfur isotope LA-ICP-MS data together with tourmaline mineral chemistry and boron isotopes. Classification of original protoliths was made on the basis of geochemically immobile elements; recognized lithologies are metasedimentary rocks, mafic, intermediate-composition, and felsic metavolcanic rocks, and an ultramafic sill. The composition of the host rocks does not control the type or intensity of mineralization. Sulfur isotope values (δ34S − 2.6 to + 7.1‰) and trace element data obtained for pyrite, chalcopyrite, and pyrrhotite indicate that the two geochemically distinct Au–Co and Co ore types formed from fluids of different compositions and origins. A reduced, metamorphic fluid was responsible for deposition of the pyrrhotite-dominant, Co-rich ore, whereas a relatively oxidized fluid deposited the pyrite-dominant Au–Co ore. The main alteration and mineralization stages at Juomasuo are as follows: (1) widespread albitization that predates both types of mineralization; (2) stage 1, Co-rich mineralization associated with chlorite (± biotite ± amphibole) alteration; (3) stage 2, Au–Co mineralization related to sericitization. Crystal-chemical compositions for tourmaline suggest the involvement of evaporite-related fluids in formation of the deposit; boron isotope data also allow for this conclusion. Results of our research indicate that the metal association in the Juomasuo Au–Co deposit was formed by spatially coincident and multiple hydrothermal processes.


2015 ◽  
Vol 52 (12) ◽  
pp. 1093-1108 ◽  
Author(s):  
Bruno Lafrance

The Larder Lake – Cadillac deformation zone (LLCDZ) is one of two major, auriferous, deformation zones in the southern Abitibi subprovince of the Archean Superior Province. It hosts the Cheminis and the giant Kerr Addison – Chesterville deposits within a strongly deformed band of Fe-rich tholeiitic basalt and komatiite of the Larder Lake Group (ca. 2705 Ma). The latter is bounded on both sides by younger, less deformed, Timiskaming turbidites (2674–2670 Ma). The earliest deformation features are F1 folds affecting the Timiskaming rocks, which formed either during D1 extensional faulting or during early D2 north–south shortening related to the opening and closure, respectively, of the Timiskaming basin. Continued shortening during D2 imbricated the older volcanic rocks and turbidites and produced regional F2 folds with an axial planar S2 cleavage. D2 deformation was partitioned into the weaker band of volcanic rocks, producing the strong S2 foliation, L2 stretching lineation, and south-side-up shear sense indicators, which characterize the LLCDZ. Gold is present in quartz–carbonate veins in deformed fuchsitic komatiites (carbonate ore) and turbiditic sandstone (sandstone-hosted ore), and in association with disseminated pyrite in altered Fe-rich tholeiitic basalts (flow ore). All host rocks underwent strong mass gains in CO2, S, K2O, Ba, As, and W, during sericitization, carbonatization, and sulphidation of the host rocks, suggesting that they interacted with the same hydrothermal fluids. Textural relationships between alteration minerals and S2 cleavage indicate that mineralization is syn-cleavage. Thus, gold was deposited as hydrothermal fluids migrated upward along the LLCDZ during contractional, D2 south-side-up shearing. The gold zones were subsequently modified during D3 reactivation of the LLCDZ as a dextral transcurrent fault zone.


2019 ◽  
Vol 55 (1) ◽  
pp. 202
Author(s):  
Foteini Aravani ◽  
Lambrini Papadopoulou ◽  
Vasileios Melfos ◽  
Triantafillos Soldatos ◽  
Triantafillia Zorba ◽  
...  

The volcanic rocks of Kornofolia area, Evros, host a number of epithermal-type veins. The host rocks are Oligocene calc-alkaline andesites to rhyo-dacites. The andesites form hydrothermal breccias and show hydrothermal alteration. The veins comprise mainly silica polymorphs such as quartz, chalcedony and three types of opal (milky white, transparent and green). Amethyst also forms in veins at the same area. Apart from the silica polymorphs, the veins are accompanied by calcite and zeolites. The main aim of this study is the characterization of the silica polymorphs. Using FT-IR analyses, variations in the crystal structure of the three opals were recognized. The green opal is found to be more amorphous than the other two types. Fluid-inclusion measurements were performed in calcite and were compared with amethyst from previous studies. The Th is between 121-175 °C and the Te between -22.9 and -22.4 °C. The salinities range from 0.9 to 4.5 wt % NaCl equiv.


1991 ◽  
Vol 86 (10) ◽  
pp. 459-472 ◽  
Author(s):  
Keiichi Shiraki ◽  
Kenji Nagao ◽  
Takashi Nagao ◽  
Susumu Kakubuchi ◽  
Yukio Matsumoto
Keyword(s):  

1983 ◽  
Vol 47 (345) ◽  
pp. 473-479 ◽  
Author(s):  
D. K. Hallbauer ◽  
K. von Gehlen

AbstractEvidence obtained from morphological and extensive trace element studies, and from the examination of mineral and fluid inclusions in Witwatersrand pyrites, shows three major types of pyrite: (i) detrital pyrite (rounded pyrite crystals transported into the depositional environment); (ii) synsedimentary pyrite (round and rounded aggregates of fine-grained pyrite formed within the depositional environmen); and (iii) authigenic pyrite (newly crystallized and/or recrystallized pyrite formed after deposition). The detrital grains contain mineral inclusions such as biotite, feldspar, apatite, zircon, sphene, and various ore minerals, and fluid inclusions with daughter minerals. Most of the inclusions are incompatible with an origin by sulphidization. Recrystallized authigenic pyrite occurs in large quantities but only in horizons or localities which have been subjected to higher temperatures during the intrusion or extrusion of younger volcanic rocks. Important additional findings are the often substantial amounts of pyrite and small amounts of particles of gold found in Archaean granites (Hallbauer, 1982) as possible source rocks for the Witwatersrand detritus. Large differences in Ag and Hg content between homogeneous single gold grains within a hand specimen indicate a lack of metamorphic homogenization. The influence of metamorphism on the Witwatersrand pyrites can therefore be described as only slight and generally negligible.


1984 ◽  
Vol 18 (6) ◽  
pp. 287-295 ◽  
Author(s):  
Mitsuru Ebihara ◽  
Yuji Nakamura ◽  
Hiroshi Wakita ◽  
Hajime Kurasawa ◽  
Tadashi Konda

Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 588
Author(s):  
Indrani Mukherjee ◽  
Mihir Deb ◽  
Ross R. Large ◽  
Jacqueline Halpin ◽  
Sebastien Meffre ◽  
...  

The Vindhyan Basin in central India preserves a thick (~5 km) sequence of sedimentary and lesser volcanic rocks that provide a valuable archive of a part of the Proterozoic (~1800–900 Ma) in India. Here, we present an analysis of key sedimentary pyrite textures and their trace element and sulfur isotope compositions in the Bijaigarh Shale (1210 ± 52 Ma) in the Vindhyan Supergroup, using reflected light microscopy, LA-ICP-MS and SHRIMP-SI, respectively. A variety of sedimentary pyrite textures (fine-grained disseminated to aggregates, framboids, lags, and possibly microbial pyrite textures) are observed reflecting quiet and strongly anoxic water column conditions punctuated by occasional high-energy events (storm incursions). Key redox sensitive or sensitive to oxidative weathering trace elements (Co, Ni, Zn, Mo, Se) and ratios of (Se/Co, Mo/Co, Zn/Co) measured in sedimentary pyrites from the Bijaigarh Shale are used to infer atmospheric redox conditions during its deposition. Most trace elements are depleted relative to Proterozoic mean values. Sulfur isotope compositions of pyrite, measured using SHRIMP-SI, show an increase in δ34S as we move up stratigraphy with positive δ34S values ranging from 5.9‰ (lower) to 26.08‰ (upper). We propose limited sulphate supply caused the pyrites to incorporate the heavier isotope. Overall, we interpret these low trace element signatures and heavy sulfur isotope compositions to indicate relatively suppressed oxidative weathering on land during the deposition of the Bijaigarh Shale.


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