Multi-component behavior of fixed-bed adsorption of dioxins by activated carbon fiber

Chemosphere ◽  
2005 ◽  
Vol 61 (7) ◽  
pp. 941-946 ◽  
Author(s):  
Kozo Mori ◽  
Hisaji Matsui ◽  
Naoki Yamaguchi ◽  
Yoshiteru Nakagawa
2020 ◽  
Vol 82 (4) ◽  
pp. 732-746
Author(s):  
Jian Liu ◽  
Zhengji Yi ◽  
Ziling Ou ◽  
Tianhui Yang

Abstract The application of activated carbon fiber supported nanoscale zero-valent iron (ACF-nZVI) in the continuous removal of Cr(VI) and methyl orange (MO) from aqueous solution was studied in depth. The breakthrough curves of Cr(VI) in a fixed bed with ACF-nZVI were measured, and compared with those in the fixed bed with ACF. The catalytic wet peroxide oxidation (CWPO) process for MO was also carried out using ACF-nZVI after reacting with Cr(VI) in the same fixed bed. The results showed that the breakthrough time of ACF-nZVI was significantly longer than that of ACF. Higher pH values were unfavorable for the Cr(VI) removal. The breakthrough time increased with decreasing inlet Cr(VI) concentration or increasing bed height. The Yoon–Nelson and bed depth service time (BDST) models were found to show good agreement with the experimental data. The Cr(VI) removal capacity when using ACF-nZVI was two times higher than that when using ACF. Under the optimal empty bed contact time of 1.256 min, the fixed bed displayed high MO conversion (99.2%) and chemical oxygen demand removal ratio (55.7%) with low Fe leaching concentration (<5 mg/L) after continuous running for 240 min. After three cycles, the conversion of MO remained largely unchanged.


2001 ◽  
Vol 11 (PR3) ◽  
pp. Pr3-279-Pr3-286
Author(s):  
X. Dabou ◽  
P. Samaras ◽  
G. P. Sakellaropoulos

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