scholarly journals Biodegradation of aromatic hydrocarbons by Haloarchaea and their use for the reduction of the chemical oxygen demand of hypersaline petroleum produced water

Chemosphere ◽  
2011 ◽  
Vol 84 (11) ◽  
pp. 1671-1676 ◽  
Author(s):  
Maricy R.L. Bonfá ◽  
Matthew J. Grossman ◽  
Encarnacion Mellado ◽  
Lucia R. Durrant
Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3132
Author(s):  
Tahir Haneef ◽  
Muhammad Raza Ul Mustafa ◽  
Khamaruzaman Wan Yusof ◽  
Mohamed Hasnain Isa ◽  
Mohammed J.K. Bashir ◽  
...  

Polycyclic aromatic hydrocarbons (PAHs) are mutagenic and carcinogenic contaminants made up of fused benzene rings. Their presence has been reported in several wastewater streams, including produced water (PW), which is the wastewater obtained during oil and gas extraction from onshore or offshore installations. In this study, ferrate (VI) oxidation was used for the first time for the treatment of 15 PAHs, with the total concentration of 1249.11 μg/L in the produced water sample. The operating parameters viz., ferrate (VI) dosage, pH, and contact time were optimized for maximum removal of PAHs and chemical oxygen demand (COD). Central composite design (CCD) based on response surface methodology (RSM) was used for optimization and modeling to evaluate the optimal values of operating parameters. PAH and COD removal percentages were selected as the dependent variables. The study showed that 89.73% of PAHs and 73.41% of COD were removed from PW at the optimal conditions of independent variables, i.e., ferrate (VI) concentration (19.35 mg/L), pH (7.1), and contact time (68.34 min). The high values of the coefficient of determination (R2) for PAH (96.50%) and COD (98.05%) removals show the accuracy and the suitability of the models. The results showed that ferrate (VI) oxidation was an efficient treatment method for the successful removal of PAHs and COD from PW. The study also revealed that RSM is an effective tool for the optimization of operating variables, which could significantly help to reduce the time and cost of experimentation.


Author(s):  
Omer Al Haiqi ◽  
Abdurahman Hamid Nour ◽  
Bamidele Victor Ayodele ◽  
Rushdi Bargaa

This study investigates the interaction effects of process variables on photocatalytic phenol degradation in oil produce water. A series of ZnO/Fe2O3 nanocomposite prepared using the sol-gel method and calcined at a temperature range of 400-600 oC were employed as photocatalysts. The characterization analysis using different instrument techniques revealed that the ZnO/Fe2O3 nanocomposites have suitable physicochemical properties as photocatalysts. The photocatalytic activity of the ZnO/Fe2O3 nanocomposite was examined in photo-reactor considering the degradation of the phenol and the reduction in chemical oxygen demand (COD) in the oilfield produced water under direct sunlight. It was ascertained that process variables such as irradiation time, calcination temperature of the ZnO/Fe2O3 nanocomposites, and the ZnO/Fe2O3 nanocomposites concentration significantly influenced the chemical oxygen demand and phenol removal. Based on the analysis of variance (ANOVA), the effects of the process variables on the phenol and COD removal can be ranked as irradiation time (p-value < 0.0001) > calcination temperature of the ZnO/Fe2O3 nanocomposite (p-value = 0.0003) > ZnO/Fe2O3 concentration (p-value = 0.0013). The interaction between the parameters was observed to have a substantial effect on COD and phenol removal. However, the interaction effect that produced the most significant influence on the COD and phenol removal was recorded between the irradiation time and the ZnO/Fe2O3 nanocomposite concentration.


Chemosphere ◽  
2006 ◽  
Vol 62 (2) ◽  
pp. 322-331 ◽  
Author(s):  
Jinren Lu ◽  
Xiulin Wang ◽  
Baotian Shan ◽  
Ximing Li ◽  
Weidong Wang

Author(s):  
Adel Abdelkader ◽  
Basem M. Hussien ◽  
Eman M. Fawzy ◽  
Asma A. Ibrahim

AbstractIn the present study, high surface area boehmite nanopowder was recovered from aluminum cans waste. The sodium aluminate solution was first prepared by dissolving aluminum cans in NaOH solution and then, H2O2 solution was added to precipitate boehmite. The prepared boehmite was characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM) and N2 adsorption–desorption techniques. The thermal stability of the boehmite sample was investigated using thermogravimetry (TG) and differential scanning calorimetry (DSC) techniques. The feasibility of using the prepared boehmite powder as a new low-cost adsorbent for the treatment of oilfield produced water was investigated. For comparison, commercial activated carbon was used for the treatment of the produced water under the same conditions. The efficiency of both of boehmite and activated carbon in the treatment of produced water was determined by monitoring the values of a number of pollution indicators [i.e. turbidity, sulfides, sulfates, total organic carbon (TOC), total petroleum hydrocarbon (TPH), and chemical oxygen demand (COD)] before and after the treatment. The boehmite powder showed very good efficiency in the treatment of the produced water, which is very close to that of commercial activated carbon under the same conditions. The effect of adsorbent dose, treatment time, and pH of the media on the adsorption efficiency of both of boehmite and activated carbon was examined at room temperature using chemical oxygen demand as a pollution indicator. The maximum capacity for COD reduction was 69.6% for boehmite and 83.5% for activated carbon at 40 g/l adsorbent dosage, pH7, and 24-h contact time. Graphic abstract


Author(s):  
V.E. Kotova ◽  
◽  
Yu.А. Andreev ◽  
О.А. Mikhaylenko ◽  
I.А. Ryazantseva

Here, we report the results of petroleum component contamination assessment of the Temernik river and the Don river. Our aim was to study the hydrocarbon group content of petroleum components in the river water. Thus, we determined the mass concentrations of chemical oxygen demand, petroleum components, and aliphatic and polycyclic aromatic hydrocarbons. In the Temernik river, the concentrations of chemical oxygen demand, petroleum components, sum of aliphatic and polycyclic aromatic hydrocarbons were 21.4–34.4 mg/L, 0.14–6.0 mg/L, 10–18 μg/L, and 0.17–2.9 μg/L, respectively. The concentrations of chemical oxygen demand, petroleum components, and benzo[a]pyrene exceeded the maximum permissible concentration by 1.4–2.3, 2.8-120, and 1.3–5.8 times, respectively. In the Don river, the concentrations of chemical oxygen demand, petroleum components, sum of aliphatic and polycyclic aromatic hydrocarbons were 18.7-29.5 mg/L, 0.08- 0.16 mg/L, 8.2-12 μg/L, and 0.03-0.13 μg/L, respectively. The Severnoe reservoir was the less contaminated part of the river. The Temernik river estuary was the most contaminated part of the river. The pollutant concentrations increased in the Don River downstream of the Temernik river estuary. Therefore, the Temernik river influences on the Don river contamination. The chemical oxygen demand, petroleum components, and polycyclic aromatic hydrocarbons had the close distribution of concentrations in the rivers. However, the aliphatic hydrocarbon concentration changed in another way. The results of the study showed that the hydrocarbon groups of petroleum components can have different sources.


2014 ◽  
Vol 13 (1) ◽  
pp. 43-50 ◽  
Author(s):  
Ghasem Najafpour Darzi ◽  
Reza Katal ◽  
Hossein Zare ◽  
Seyed Omid Rastegar ◽  
Poorya Mavaddat

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