scholarly journals Optimum reaction ratio of coal fly ash to blast furnace cement for effective removal of hydrogen sulfide

Chemosphere ◽  
2017 ◽  
Vol 168 ◽  
pp. 384-389 ◽  
Author(s):  
Satoshi Asaoka ◽  
Hideo Okamura ◽  
Kyunghoi Kim ◽  
Yuzuru Hatanaka ◽  
Kenji Nakamoto ◽  
...  
Author(s):  
Satoshi Asaoka ◽  
Hiroyuki Saito ◽  
Tsuyoshi Ichinari ◽  
Shinjiro Hayakawa ◽  
Takahito Oikawa

Abstract The number of complaints regarding offensive odors from service industries, such as restaurants and garages, has recently increased. In this study, we aimed to develop an adsorbent for hydrogen sulfide gas derived from domestic wastewater and reveal the mechanisms of its removal. The adsorbent used for hydrogen sulfide gas removal was prepared by mixing coal fly ash and blast furnace cement with a mixing ratio of 87:13 by mass percentage. The optimum calcination temperature of the adsorbent was 700 °C to achieve a high removal performance for both dry and humid hydrogen sulfide gas. The X-ray absorption fine structure analysis revealed that hydrogen sulfide was removed on the adsorbent by oxidizing to sulfate. A pilot-scale experiment was conducted to evaluate the removal performance of hydrogen sulfide gas derived from domestic wastewater using the developed adsorbent. For a week, the average removal percentage of hydrogen sulfide gas derived from domestic wastewater remained at 99.1%. Therefore, the developed adsorbent for hydrogen sulfide gas is promising and cost-effective for promoting the recycling of coal fly ash.


2021 ◽  
Vol 406 ◽  
pp. 124780
Author(s):  
Satoshi Asaoka ◽  
Kohei Kawakami ◽  
Hiroyuki Saito ◽  
Tsuyoshi Ichinari ◽  
Hideaki Nohara ◽  
...  

2017 ◽  
Vol 29 (8) ◽  
pp. 313-321
Author(s):  
Rimvydas Kaminskas ◽  
Vytautas Cesnauskas ◽  
Raimonda Kubiliute

Minerals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 493 ◽  
Author(s):  
Farrah Hanum ◽  
Erda Desfitri ◽  
Yukio Hayakawa ◽  
Shinji Kambara

The application of paper sludge ash as an additive in controlling the leaching of trace elements has been satisfactorily effective to date. Previous studies have found that paper sludge ash has a promising effect in controlling the leaching of arsenic, selenium and boron. The content of calcium oxide in paper sludge ash is believed to be one of the important factors in decreasing the concentration of trace elements in leachate. Therefore, this study aimed to verify the effect of paper sludge ash in the leaching process and to propose an effective and applicable suppressing material that can control the leaching of As, Se, B and F simultaneously. In light of this aim, Ca(OH)2, PS ash 8 and blast furnace cement (BF cement) were tested as single and mixed additives in two different coal fly ashes (FA C and FA H). The results indicate that the application of a mixture of additives is necessary to control the leaching of trace elements. A mixture of PS ash 8, Ca(OH)2 and blast furnace cement (BF cement) was proposed to be an applicable and suitable additive that could suppress arsenic, selenium, boron, and fluorine leaching simultaneously.


Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3239
Author(s):  
Rosa Abnelia Rivera ◽  
Miguel Ángel Sanjuán ◽  
Domingo Alfonso Martín ◽  
Jorge Luis Costafreda

Ternary Portland cements are new cementitious materials that contain different amounts of cement replacements. Ternary Portland cements composed of granulated blast-furnace slag (GBFS), coal fly ash (CFA), and clinker (K) can afford some environmental advantages by lowering the Portland cement clinker use. Accordingly, this is an opportunity to reduce carbon dioxide emissions and achieve net-zero carbon emissions by 2050. Furthermore, GBFS and CFA possess pozzolanic properties and enhance the mechanical strength and durability at later ages. Compressive strength and natural carbonation tests were performed in mortar and concrete. Cement-based materials made with GBFS and/or CFA presented a delay in the compressive strength development. In addition, they exhibited lower carbonation resistance than that of mortar and concrete made with plain Portland cements. Concrete reinforcement remains passive in common conditions; however, it could be corroded if the concrete pore solution pH drops due to the carbonation process. Service life estimation was performed for the ternary cements regarding the carbonation process. This information can be useful to material and civil engineers in designing concretes made with these ternary cements.


2020 ◽  
Vol 12 (14) ◽  
pp. 5783 ◽  
Author(s):  
Rosa Abnelia Rivera ◽  
Miguel Ángel Sanjuán ◽  
Domingo Alfonso Martín

Granulated blast-furnace slag (GBFS) and coal fly ash (CFA) are two well-known constituents in Portland cements. Ternary Portland cements (GBFS-CFA-K) provide environmental advantages by reducing Portland cement clinker (K) production and, therefore, promote lower CO2 emissions. Nevertheless, both of them cause a delay in the compressive strength gain. Given that, the early compressive strength for both constituents is low, but they improve the compressive strength at medium and later ages as consequence of the pozzolanic reaction. In this paper, a full factorial design with two levels was developed for the mortar compressive strength estimation at 2, 7 and 28 days. Mortar prisms made with 25% and 40% of granulated blast-furnace slag (GBFS) and/or coal fly ash (CFA) were tested. The effects of the interaction between GBFS and CFA on the compressive strength development of ternary Portland cement mortars were reported. Results show that the contribution of both cement constituents to the ternary mortar mix reduces the compressive strength for all the tested ages. Nevertheless, the finer the GBFS, the better ternary cement performance was achieved, showing that the synergistic effect is more effective when the finer GBFS is used, probably due to a more adequate particle size distribution. Finally, a relationship between compressive strength, fineness, GBFS content and CFA content was found for each age.


2015 ◽  
Vol 1105 ◽  
pp. 346-354 ◽  
Author(s):  
Gianluca Nestovito ◽  
Francesco Messina

This study deals with the paramount topic of sustainable and durable composite materials for repair of damaged existing bridge. Reinforced concrete is the most used composite system in structural design but, across several decades, it has shown some fragilities related to chemico-physical resistance. Durability improvement by means of innovative repair systems represent, therefore, a crucial economic parameter allowing a highly significant reduction of maintenance cost. A maintenance scenario is here simulated, considering a repair composite realized with a binary geopolymer binder, obtained by activating two industrial by-products, namely coal fly ash and blast furnace slag, in alkaline environment. Physico-mechanical characterization of geopolymer concrete is also performed, showing the suitability of this innovative repair system. In order to investigate the effectiveness of geopolymer, a 3D finite element model is developed in Sap2000 to represent the complex behavior of a full-scale Italian highway bridge. Numerical simulations are conducted by modeling the geopolymer concrete as a jacketing applied to the damaged piers. Results reveal that the designed repair system could increase shear capacity of bridge piers under seismic conditions, not neglecting the low cost of raw materials and the high durability of geopolymers.


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