scholarly journals Performance of Ground Granulated Blast-Furnace Slag and Coal Fly Ash Ternary Portland Cements Exposed to Natural Carbonation

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3239
Author(s):  
Rosa Abnelia Rivera ◽  
Miguel Ángel Sanjuán ◽  
Domingo Alfonso Martín ◽  
Jorge Luis Costafreda
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Coal Fly Ash ◽  
Portland Cements ◽  
Carbonation Process ◽  
Granulated Blast Furnace Slag ◽  
Natural Carbonation ◽  
Furnace Slag

Ternary Portland cements are new cementitious materials that contain different amounts of cement replacements. Ternary Portland cements composed of granulated blast-furnace slag (GBFS), coal fly ash (CFA), and clinker (K) can afford some environmental advantages by lowering the Portland cement clinker use. Accordingly, this is an opportunity to reduce carbon dioxide emissions and achieve net-zero carbon emissions by 2050. Furthermore, GBFS and CFA possess pozzolanic properties and enhance the mechanical strength and durability at later ages. Compressive strength and natural carbonation tests were performed in mortar and concrete. Cement-based materials made with GBFS and/or CFA presented a delay in the compressive strength development. In addition, they exhibited lower carbonation resistance than that of mortar and concrete made with plain Portland cements. Concrete reinforcement remains passive in common conditions; however, it could be corroded if the concrete pore solution pH drops due to the carbonation process. Service life estimation was performed for the ternary cements regarding the carbonation process. This information can be useful to material and civil engineers in designing concretes made with these ternary cements.

scholarly journals Granulated Blast-Furnace Slag and Coal Fly Ash Ternary Portland Cements Optimization

2020 ◽  
Vol 12 (14) ◽  
pp. 5783 ◽  
Author(s):  
Rosa Abnelia Rivera ◽  
Miguel Ángel Sanjuán ◽  
Domingo Alfonso Martín
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Portland Cement ◽  
Blast Furnace Slag ◽  
Coal Fly Ash ◽  
Cement Clinker ◽  
Portland Cements ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

Granulated blast-furnace slag (GBFS) and coal fly ash (CFA) are two well-known constituents in Portland cements. Ternary Portland cements (GBFS-CFA-K) provide environmental advantages by reducing Portland cement clinker (K) production and, therefore, promote lower CO2 emissions. Nevertheless, both of them cause a delay in the compressive strength gain. Given that, the early compressive strength for both constituents is low, but they improve the compressive strength at medium and later ages as consequence of the pozzolanic reaction. In this paper, a full factorial design with two levels was developed for the mortar compressive strength estimation at 2, 7 and 28 days. Mortar prisms made with 25% and 40% of granulated blast-furnace slag (GBFS) and/or coal fly ash (CFA) were tested. The effects of the interaction between GBFS and CFA on the compressive strength development of ternary Portland cement mortars were reported. Results show that the contribution of both cement constituents to the ternary mortar mix reduces the compressive strength for all the tested ages. Nevertheless, the finer the GBFS, the better ternary cement performance was achieved, showing that the synergistic effect is more effective when the finer GBFS is used, probably due to a more adequate particle size distribution. Finally, a relationship between compressive strength, fineness, GBFS content and CFA content was found for each age.

scholarly journals Protective Geopolymer Coatings Containing Multi-Componential Precursors: Preparation and Basic Properties Characterization

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3448
Author(s):  
Chenhui Jiang ◽  
Aiying Wang ◽  
Xufan Bao ◽  
Zefeng Chen ◽  
Tongyuan Ni ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Portland Cement ◽  
Adhesive Strength ◽  
Blast Furnace Slag ◽  
Setting Time ◽  
Rapid Test ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

This paper presents an experimental investigation on geopolymer coatings (GPC) in terms of surface protection of civil structures. The GPC mixtures were prepared with a quadruple precursor simultaneously containing fly ash (FA), ground granulated blast-furnace slag (GBFS), metakaolin (MK), and Portland cement (OPC). Setting time, compressive along with adhesive strength and permeability, were tested and interpreted from a perspective of potential applications. The preferred GPC with favorable setting time (not shorter than 120 min) and desirable compressive strength (not lower than 35 MPa) was selected from 85 mixture formulations. The results indicate that balancing strength and setting behavior is viable with the aid of the multi-componential precursor and the mixture design based on total molar ratios of key oxides or chemical elements. Adhesive strength of the optimized GPC mixtures was ranged from 1.5 to 3.4 MPa. The induced charge passed based on a rapid test of coated concrete specimens with the preferred GPC was 30% lower than that of the uncoated ones. Setting time of GPC was positively correlated with η[Si/(Na+Al)]. An abrupt increase of setting time occurred when the molar ratio was greater than 1.1. Compressive strength of GPC was positively affected by mass contents of ground granulated blast furnace slag, metakaolin and ordinary Portland cement, and was negatively affected by mass content of fly ash, respectively. Sustained seawater immersion impaired the strength of GPC to a negligible extent. Overall, GPC potentially serves a double purpose of satisfying the usage requirements and achieving a cleaner future.

scholarly journals The effect of fly ash and granulated blast furnace slag on slip and tensile adhesion strength of tile adhesives mortars

2020 ◽  
Vol 322 ◽  
pp. 01017
Author(s):  
Michał Wieczorek
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Adhesion Strength ◽  
Blast Furnace Slag ◽  
Portland Cements ◽  
Optimal Amount ◽  
Functional Parameters ◽  
Granulated Blast Furnace Slag ◽  
Tensile Adhesion ◽  
Furnace Slag

In the formulations of adhesive mortars for tiles almost exclusively CEM I Portland cements are used. Practically no CEM II - CEM V cements with additives are used, although they are often produced with strength classes 32.5 R and some even 42.5R. Relationship between strengths of tile adhesives in which cement was partially replaced with fly ash and granulated blast furnace slag was studied. A fly ash was used in three different replacement levels from 5% to 25% by weight of either cement. The tensile adhesion were determined at 28 and 90 days after various conditioning conditions of the samples. The influence on the flexibility of mortars was also assessed. In small substitution levels, fly ash replacement increased the tensile adhesion strength. The results indicate that the optimal amount of fly ash and granulated blast furnace slag additive replacing a given amount of cement allows to obtain adhesive mortars for tiles with high functional parameters.

scholarly journals Investigation of Mechanical Properties, Durability and Microstructure of Low-Clinker High-Performance Concretes Incorporating Ground Granulated Blast Furnace Slag, Siliceous Fly Ash and Silica Fume

2021 ◽  
Vol 11 (2) ◽  
pp. 830
Author(s):  
Katarzyna Konieczna ◽  
Karol Chilmon ◽  
Wioletta Jackiewicz-Rek
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
High Performance ◽  
Cement Clinker ◽  
Water Penetration ◽  
Granulated Blast Furnace Slag ◽  
Portland Cement Clinker ◽  
Furnace Slag

The main assumption of eco-efficient High-Performance Concrete (HPC) design is the reduction of Portland cement clinker content without negatively affecting the composite’s mechanical and durability properties. In this paper, three low-clinker HPC mixtures incorporating slag cement (CEM III/B as per EN 197-1) and Supplementary Cementitious Materials (SCMs)—Ground Granulated Blast Furnace Slag (GGBFS), Siliceous Fly Ash (SFA) and Silica Fume (SF)—were designed. The maximum amount of Portland cement clinker from CEM III/B varied from 64 to 116 kg in 1 m3 of concrete mix. The compressive strength of HPC at 2, 7, 14, 28, 56, 90 days, and 2 years after casting, as well as the modulus of elasticity on 2-year-old specimens, was tested. The depth of water penetration under pressure and internal frost resistance in freeze–thaw tests were evaluated after 56 days of curing. Additionally, the concrete pH value tests were performed. The microstructure of 2-year-old HPC specimens was analyzed using Scanning Electron Microscopy (SEM). The research proved that it is possible to obtain low-clinker High-Performance Concretes that reach compressive strength of 76–92 MPa after 28 days of curing, show high values of modulus of elasticity (49–52 GPa) as well as increased resistance to frost and water penetration under pressure.

scholarly journals Preparation of Foamed Phosphogypsum Lightweight Materials by Incorporating Cementitious Additives

2019 ◽  
Vol 25 (3) ◽  
pp. 340-347
Author(s):  
Ting WANG ◽  
Xiaojian GAO ◽  
Jian WANG
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Portland Cement ◽  
Blast Furnace Slag ◽  
Building Materials ◽  
Water Resistance ◽  
Hydrated Lime ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

As a byproduct of phosphoric acid industry, phosphogypsum has many environmental problems. In order to recycle phosphogypsum to manufacture lightweight building materials, cementitious additives including fly ash, ground granulate blast-furnace slag and Portland cement were added to improve strength and water-resistance and different volume of foam was added to reduce the bulk density. The results show that hydrated lime can improve mechanical strength and water resistance of PG paste and the optimal dosage of hydrated lime is 6 %. Higher addition of fly ash or ground granulated blast-furnace slag improves the fluidity and delays the setting time of PG paste. The addition of 10 ~ 20 % fly ash results in a little reducing influence and 10 % ground granulated blast-furnace slag leads to an increase of 20.7 % for 28 days compressive strength of hardened PG specimen. The higher addition of Portland cement results in the better mechanical strength and water resistance of PG specimens. The 28day compressive and flexural strength reaches 25.9 MPa and 8.9 MPa respectively for the 25 % Portland cement mixture. PG based lightweight building materials can prepared by the addition of 60 % volume of air foam, with compressive strength of 1.7 MPa, bulk density of 521.7 kg/m3 and thermal conductivity of 0.0724 W/(m·K). DOI: http://dx.doi.org/10.5755/j01.ms.25.3.19910

scholarly journals Evolution of Mechanical Properties with Time of Fly-Ash-Based Geopolymer Mortars under the Effect of Granulated Ground Blast Furnace Slag Addition

Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1135 ◽  
Author(s):  
Mateusz Sitarz ◽  
Izabela Hager ◽  
Marta Choińska
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Modulus Of Elasticity ◽  
Blast Furnace Slag ◽  
Energy Savings ◽  
Pulse Velocity ◽  
Partial Replacement ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

Geopolymers are considered to alternatives to Portland cement, providing an opportunity to exploit aluminosilicate wastes or co-products with promising performances in the construction sector. This research is aimed at investigating the strength of fly-ash-geopolymers of different ages. The effect of granulated blast furnace slag (GGBFS) as a partial replacement of fly ash (FA) on the tensile (ft) and compressive strength (fc), as well as the modulus of elasticity, is investigated. The main advantage of the developed geopolymer mixes containing GGBFS is their ability to set and harden at room temperature with no need for heating to obtain binding properties, reducing the energy consumption of their production processes. This procedure presents a huge advantage over binders requiring heat curing, constituting a significant energy savings and reduction of CO2 emissions. It is found that the development of strength strongly depends on the ratio of fly-ash to granulated blast furnace slag. With the highest amount of GGBFS, the compressive strength of geopolymers made of fly-ash reached 63 MPa after 28 days of curing at ambient temperature. The evolution of compressive strength with time is correlated with the development of ultrasound pulse velocity methods, which are used to evaluate maturity. The modulus of elasticity changes with strength and the relationship obtained for the geopolymer is presented on the basis of typical models used for cement-based materials. The tensile to compressive strength ratios of the tested geopolymers are identified as higher than for cementitious binders, and the ft(fc) relationship is juxtaposed with dependencies known for cement binders, showing that the square root function gives the best fit to the results.

Physico chemical and thermal resistance properties of fly ash/ground granulated blast furnace slag based geopolymer mortar

2021 ◽  
Vol 25 (8) ◽  
pp. 110-120
Author(s):  
M. Sivasakthi ◽  
R. Jeyalakshmi ◽  
N.P. Rajamane ◽  
J. Baskarasundararaj
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Elevated Temperatures ◽  
Linear Thermal Expansion ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

The present study investigated the physicochemical and thermal properties of fly ash and ground granulated blast furnace slag (GGBS) based geopolymer mortars exposed to elevated temperatures under different reaction conditions. The compressive strength results shows that fly ash based geopolymer mortar exhibits retention of compressive strength up to 800⁰C whereas the addition of GGBS increases the ambient temperature compressive strength, however, thereafter the retention of strength is observed as 66% at 400˚C and 30% at 800˚C. Fourier transform infra-red spectroscopy (FT- IR) and 29Si and 27Al Magic angle spinning nuclear magnetic resonance (MAS-NMR) spectrum confirmed the alumino-silicate network structure of the geopolymer. Thermogravimetry with differential thermal analysis (TGA/DTA) showed that most of the % weight loss occurred in the temperature range between 30-250ºC due to the water loss after that it was stabilized till 1000⁰C. Thermal conductivity has the direct relationship with the temperature whereas it is vice versa for the % linear thermal expansion. The Scanning electron microscopy (SEM) analysis was performed to identify the morphology changes before and after thermal exposure.

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