Estimating the Chemical Oxygen Demand of Petrochemical Wastewater Treatment Plants Using Linear and Nonlinear Statistical Models – A case study

Chemosphere ◽  
2021 ◽  
pp. 129465
Author(s):  
Milad Abouzari ◽  
Parham Pahlavani ◽  
Fatemeh Izaditame ◽  
Behnaz Bigdeli
Keyword(s):  
Wastewater Treatment ◽  
Chemical Oxygen Demand ◽  
Statistical Models ◽  
Wastewater Treatment Plants ◽  
Oxygen Demand ◽  
Petrochemical Wastewater ◽  
Linear And Nonlinear

scholarly journals Excessive greenhouse gas emissions from wastewater treatment plants by using the chemical oxygen demand standard

2021 ◽  
Author(s):  
Zongqing Lv ◽  
Xiaoyu Shan ◽  
Xilin Xiao ◽  
Ruanhong Cai ◽  
Yao Zhang ◽  
...  
Keyword(s):  
Organic Matter ◽  
Wastewater Treatment ◽  
Chemical Oxygen Demand ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Carbon Sink ◽  
Oxygen Demand ◽  
Organic Pollution ◽  
Municipal Wastewater Treatment ◽  
Recalcitrant Organic Matter

AbstractChemical oxygen demand (COD) is widely used as an organic pollution indicator in wastewater treatment plants. Large amounts of organic matter are removed during treatment processes to meet environmental standards, and consequently, substantial greenhouse gases (GHGs) such as methane (CH4) are released. However, the COD indicator covers a great amount of refractory organic matter that is not a pollutant and could be a potential carbon sink. Here, we collected and analysed COD data from 86 worldwide municipal wastewater treatment plants (WWTPs) and applied a model published by the Intergovernmental Panel on Climate Change to estimate the emission of CH4 due to recalcitrant organic compound processing in China’s municipal wastewater treatment systems Our results showed that the average contribution of refractory COD to total COD removal was 55% in 86 WWTPs. The amount of CH4 released from the treatment of recalcitrant organic matter in 2018 could have been as high as 38.22 million tons of carbon dioxide equivalent, which amounts to the annual carbon sequestered by China’s wetlands. This suggests that the use of COD as an indicator for organic pollution is undue and needs to be revised to reduce the emission of GHG. In fact, leaving nontoxic recalcitrant organic matter in the wastewater may create a significant carbon sink and will save energy during the treatment process, aiming at carbon neutrality in the wastewater treatment industry.

Performance evaluation of anaerobic baffled reactor (ABR) treating pulp and paper wastewater in start-up period

2015 ◽  
Vol 10 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Abolghasem Alighardashi ◽  
Meghdad Modanlou ◽  
Shervin Jamshidi
Keyword(s):  
Wastewater Treatment ◽  
Chemical Oxygen Demand ◽  
Volatile Fatty Acids ◽  
Wastewater Treatment Plants ◽  
Treatment Plant ◽  
Oxygen Demand ◽  
Pulp And Paper ◽  
Anaerobic Baffled Reactor ◽  
Start Up ◽  
Paper Wastewater

This essay outlines the use of an anaerobic baffled reactor (ABR) treating pulp and paper wastewater during its start-up period. For this purpose, a pilot with four chambers and overall volume of 45 liters was fed continuously through the equalization tank of Mazandaran wood and paper wastewater treatment plant, in the north of Iran. The influent was classified as low strength slowly biodegradable wastewater. The average soluble chemical oxygen demand (SCOD) and biochemical oxygen demand (BOD) of the influent were about 1,130 and 320 mg/L, respectively. Results show that the start-up was accomplished in 90 days in which the ABR reached its maximum SCOD removal of 60%. This was achieved at the controlled mesophilic temperature (37 °C) and optimum hydraulic retention time (HRT) of 24 hours. In spite of the influent characteristics, the performance of ABR has not been inhibited and mostly influenced by HRT. The gradual hydrolysis and acidogenesis were observed within the ABR. The majority of chemical oxygen demand (COD) removal takes place in the first chamber. In addition, the concentrations of readily biodegradable organics (BOD to COD ratio) have been increased and doubled through the reactor. Moreover, the total values of pH, volatile fatty acids and alkalinity remained constant. Consequently, this system can be approved for application as a pretreatment unit for paper mill industrial wastewater treatment plants.

scholarly journals Precious Data from Tiny Samples: Revealing the Correlation Between Energy Content and the Chemical Oxygen Demand of Municipal Wastewater by Micro-Bomb Combustion Calorimetry

2021 ◽  
Vol 9 ◽  
Author(s):  
Benjamin Korth ◽  
Claudia Heber ◽  
Monika Normant-Saremba ◽  
Thomas Maskow ◽  
Falk Harnisch
Keyword(s):  
Wastewater Treatment ◽  
Chemical Oxygen Demand ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Energy Content ◽  
Treatment Plant ◽  
Oxygen Demand ◽  
Combustion Calorimetry ◽  
Energy Potential ◽  
Combustion Enthalpy

Wastewater treatment plants (WWTP) are aimed to be transformed from sinks into sources of energy and material. For fostering corresponding engineering efforts and economic assessments, comprehensive knowledge of the energy content of wastewater is required. We show in this proof-of-concept study that these data can be gathered by combining micro-bomb combustion calorimetry with freeze-drying. Thereby, the methodology for measuring the combustion enthalpy (ΔcH) of wastewater is significantly improved by decreasing the time demand for the drying process as only tiny amounts of samples are required. Here, the effluent of the primary clarifier of a wastewater treatment plant treating low-strength municipal wastewater was sampled on a weekly basis for 1 year, yielding 53 composite samples that were analyzed for ΔcH and standard wastewater parameters. A robust correlation between the chemical oxygen demand (COD) and ΔcH of −14.9 ± 3.5 kJ gCOD−1 (r = 0.51) was determined, verifying previous results obtained with more laborious and time-demanding methodologies. The global chemical energy potential of the sampled WWTP is presumably higher as the first treatment steps and losses during sample preparation reduced the amount of energy-rich compounds. A stronger correlation was observed between ΔcH and the biochemical oxygen demand (BOD5, r = 0.64), suggesting its usage for predicting the potential of wastewater as feedstock for biotechnological applications. This demonstrates that micro-bomb combustion calorimetry can be applied for deriving precious information on the energy content of wastewater from simple COD measurements.

Controlling the Settling of Activated Sludge in Pulp and Paper Wastewater Treatment Plants

1999 ◽  
Vol 40 (11-12) ◽  
pp. 223-229 ◽  
Author(s):  
Frédéric Clauss ◽  
Christel Balavoine ◽  
Delphine Hélaine ◽  
Gaëtan Martin
Keyword(s):  
Wastewater Treatment ◽  
Activated Sludge ◽  
Wastewater Treatment Plants ◽  
Pulp And Paper ◽  
Organic Load ◽  
Forest Industry ◽  
Filamentous Bulking ◽  
Mineral Particles ◽  
Mineral Powder

Forest industry wastewaters are difficult to clean: hydraulic and organic load variations, filamentous bulking or pin-point flocs negatively impact depollution processes. The addition of a fine, mineral, talc-based powder, Aquatal, into the aeration tanks of wastewater treatment plants connected to pulp and paper factories has been successfully tested since end of '97. The first case-study presents full results obtained over a period of 18 months in a 20,000 p.e. plant connected to a paper factory. The mineral powder was regularly added to control sludge volume index, thereby ensuring low suspended solids concentration in the outfluent. Plant operators could easily adapt biomass concentration to match organic load variation, thereby maintaining pollution micro-organisms ratio constant. In a second case study, a trouble-shooting strategy was implemented to counteract filamentous bulking. A one-off, large dosage enabled the plant operator to deal effectively with poor settleability sludge and rapidly control sludge blanket expansion. In both cases, the main common characteristics observed were an increase in floc aggregation and the production of heavier and well-structured flocs. The sludge settling velocity increased and an efficient solid/liquid separation was obtained. After a few days, the mineral particles of Aquatal were progressively integrated into the sludge floc structure. When the mineral powder was added to the activated sludge in the aeration basin, chemical interactions frequently encountered with other wastewater treatment additives did not pose a problem. Moreover, with this mineral additive, the biological excess sludge displayed good thickening properties and dewatering was improved. Despite the addition of the insoluble mineral particles, the amount of wet sludge expelled did not increase. Aquatal offers a rapid solution to floc settleability problems which so frequently arise when physical or biological disorders appear in forest industry wastewater treatment plants.

Metro-environmental data approach for the prediction of chemical oxygen demand in new Nicosia wastewater treatment plant

2021 ◽  
Vol 221 ◽  
pp. 31-40
Author(s):  
A.S. Mubarak ◽  
Parvaneh Esmaili ◽  
Z.S. Ameen ◽  
R.A. Abdulkadir ◽  
M.S. Gaya ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Chemical Oxygen Demand ◽  
Wastewater Treatment Plant ◽  
Treatment Plant ◽  
Oxygen Demand ◽  
Environmental Data

scholarly journals Study on layout optimization of sewage outfalls: a case study of wastewater treatment plants in Xiamen

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Cui Wang ◽  
Zhouhua Guo ◽  
Qingsheng Li ◽  
Jing Fang
Keyword(s):  
Wastewater Treatment ◽  
Water Reuse ◽  
Evaluation System ◽  
Evaluation Method ◽  
Wastewater Treatment Plants ◽  
Comprehensive Evaluation ◽  
Ecological Impact ◽  
Layout Optimization ◽  
Marine Environmental

AbstractIn order to protect the offshore environment and strengthen the comprehensive rectification of sewage outfalls, an evaluation method of regional sewage outfalls by combining the marine numerical simulation and comprehensive evaluation technology was constructed, considering the marine environmental capacity and the ecological impact of sewage discharge from outfalls on the marine eco-environment sensitive areas. Then the layout rationality of each outfall was evaluated and the discharge scale was optimized with a case study of existing sewage outfalls in Xiamen. The results show that, the comprehensive evaluation score of Yundang outfall was 3 points in 2025, evaluated as the outfall with irrational layout. In 2035, the comprehensive evaluation scores of Fenglin and Dalipu outfalls were 3 and 2 points respectively, evaluated as the outfall with irrational discharge scale. It is suggested to control the scale of expansion or increase the reclaimed water reuse rate in Jimei and Gaoqi Wastewater Treatment Plants. This method has enriched the evaluation system for layout optimization of sewage outfalls, providing scientific supports for comprehensive improvement of sewage outfalls and marine environmental management.

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