A study on pozzolanic reaction of fly ash cement paste activated by an injection of alkali solution

2015 ◽  
Vol 94 ◽  
pp. 28-34 ◽  
Author(s):  
Phuong Trinh Bui ◽  
Yuko Ogawa ◽  
Kenichiro Nakarai ◽  
Kenji Kawai
2015 ◽  
Vol 49 (8) ◽  
pp. 3039-3053 ◽  
Author(s):  
Phuong Trinh Bui ◽  
Yuko Ogawa ◽  
Kenichiro Nakarai ◽  
Kenji Kawai

2016 ◽  
Vol 711 ◽  
pp. 95-102 ◽  
Author(s):  
Kazuki Ootaishi ◽  
Phuong Trinh Bui ◽  
Yuko Ogawa ◽  
Kenji Kawai

The utilization of fly ash not only reduces the environmental impact but also improves some mechanical properties and durability of concrete. However, the early-age strength of fly ash concrete is sometimes lower than that of normal concrete due to the slow pozzolanic reaction of fly ash. In recent years, some researchers have suggested alkali or sulfate activation to accelerate the pozzolanic reaction. Some studies have used sodium hydroxide (NaOH) solution, while others have applied potassium sulfate (K2SO4) or sodium sulfate (Na2SO4) as activators which are effective in accelerating the pozzolanic reaction and increasing the strength at early age. On the other hand, the early-age strength of fly ash concrete is also improved by using porous ceramic aggregate (PCA) as an internal curing agent. Therefore, the present study aims at investigating the effect of an internal activating agent using PCA on hardness and pore structure of fly ash cement paste. In the experimental program, PCA immersed in two kinds of solution (K2SO4 and Na2SO4) was placed in the center of specimen with dimension of 21x21x20 mm. In addition, normal aggregate (NS) was used for reference. As a result, internal sulfate activation using PCA improved the hardness of interfacial transition zone (ITZ) between paste and PCA, and reduced the Ca(OH)2 content in cement paste with 40% replacement with fly ash significantly at the age of 1 day, but negligibly at the ages of 7 and 28 days when compared with reference specimen. K2SO4 was more effective in improving hardness of ITZ as an internal activating agent than Na2SO4. Although the total pore volumes of the fly ash cement pastes using PCA imbibing sulfate activators were not reduced at the age of 28 days, their pore volumes with diameters less than 0.05 µm were increased.


2001 ◽  
Vol 31 (1) ◽  
pp. 31-39 ◽  
Author(s):  
Shunsuke Hanehara ◽  
Fuminori Tomosawa ◽  
Makoto Kobayakawa ◽  
KwangRyul Hwang

J ◽  
2021 ◽  
Vol 4 (3) ◽  
pp. 223-232
Author(s):  
Esperanza Menéndez ◽  
Cristina Argiz ◽  
Miguel Ángel Sanjuán

Ground coal bottom ash is considered a novel material when used in common cement production as a blended cement. This new application must be evaluated by means of the study of its pozzolanic properties. Coal bottom ash, in some countries, is being used as a replacement for natural sand, but in some others, it is disposed of in a landfill, leading thus to environmental problems. The pozzolanic properties of ground coal bottom ash and coal fly ash cements were investigated in order to assess their pozzolanic performance. Proportions of coal fly ash and ground coal bottom ash in the mixes were 100:0, 90:10, 80:20, 50:50, 0:100. Next, multicomponent cements were formulated using 10%, 25% or 35% of ashes. In general, the pozzolanic performance of the ground coal bottom ash is quite similar to that of the coal fly ash. As expected, the pozzolanic reaction of both of them proceeds slowly at early ages, but the reaction rate increases over time. Ground coal bottom ash is a promising novel material with pozzolanic properties which are comparable to that of coal fly ashes. Then, coal bottom ash subjected to an adequate mechanical grinding is suitable to be used to produce common coal-ash cements.


2016 ◽  
Vol 70 (1) ◽  
pp. 141-147
Author(s):  
Yuko OGAWA ◽  
P. Trinh BUI ◽  
Kenji KAWAI ◽  
Kazuki OTAISHI

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