Development of swelling pressure for pellet mixture and compacted block of GMZ bentonite

2021 ◽  
Vol 301 ◽  
pp. 124080
Author(s):  
Zhang-Rong Liu ◽  
Wei-Min Ye ◽  
Yu-Jun Cui ◽  
He-Hua Zhu ◽  
Qiong Wang ◽  
...  
2021 ◽  
Vol 13 (4) ◽  
pp. 1622
Author(s):  
Yu-Ping Wang ◽  
Zhe Wang ◽  
Yu Zhao ◽  
Fa-Cheng Yi ◽  
Bao-Long Zhu

In China, Gaomiaozi (GMZ) bentonite is recognized as a barrier material for isolating nuclear waste. Different chemical solutions may change the hydraulic conductivity and swelling capacity of bentonite. Consequently, a series of swelling pressure and permeability experiments was carried out on bentonite-sand mixtures with various dry densities and infiltrating solutions. X-ray diffraction (XRD) and the field emission scanning electron microscope (FESEM) were carried out on the samples experiencing the tests to identify the influence of chemistry pore solutions upon the mineralogical and microstructure changes. The results show that the swelling pressure experienced rapid swelling, slow expansion, and the stable expansion stage for the specimens of infiltrating solutions except for NaOH. For the specimens infiltrated with NaOH solutions, the swelling pressure experienced rapid increases, slow decreases, and a stable development stage. With hyper-alkaline and hyper-salinity infiltration, the swelling pressure decreased, and the permeability increased. In addition, swelling pressure attained stability more quickly on contact with hyper-alkaline and hyper-salinity solutions. Comparing the test results, the results indicate that the influence of NaOH on the expansion and permeability was higher than NaCl-Na2SO4 at the same concentration.


2021 ◽  
Vol 80 (15) ◽  
Author(s):  
Yu-Ping Wang ◽  
Zhe Wang ◽  
Yu Zhao ◽  
Bao-Long Zhu ◽  
Zhen-Yu Wang ◽  
...  

2018 ◽  
Vol 166 ◽  
pp. 318-326 ◽  
Author(s):  
Yong-Gui Chen ◽  
Xin-Xin Dong ◽  
Xu-Dong Zhang ◽  
Wei-Min Ye ◽  
Yu-Jun Cui

2018 ◽  
Vol 244 ◽  
pp. 66-74 ◽  
Author(s):  
Zhao Sun ◽  
Yong-gui Chen ◽  
Yu-jun Cui ◽  
Hao-dong Xu ◽  
Wei-min Ye ◽  
...  

2017 ◽  
Vol 54 (8) ◽  
pp. 1139-1149 ◽  
Author(s):  
L. Xu ◽  
W.M. Ye ◽  
B. Ye

In a geological repository for disposal of high-level radioactive waste, gas breakthrough is an important phenomenon during a gas migration process in the saturated engineered barrier. In this paper, gas injection, swelling pressure, water permeability, and water retention tests were conducted on saturated compacted GaoMiaoZi (GMZ) bentonite to investigate the gas breakthrough mechanism. Results show that, for saturated GMZ bentonite tested under rigid boundary conditions, the gas breakthrough pressure is significantly larger than the swelling pressure and slightly lower than the gas entry pressure obtained from the water retention characteristic and the van Genuchten model. Gas breakthrough pressure deviates from the swelling pressure and approaches the calculated gas entry pressure as the dry density increases. Mechanical and capillary effects are both important to the gas migration process for specimens with lower dry densities, and the capillary effect becomes more important with the increase of dry density. The desaturation and shrinkage of the specimen will result in unexpectedly high and disordered interfacial gas flux. For specimens with higher dry densities, gas will only flow through interconnected larger pores, then result in minor desaturation–shrinkage of the specimen. Finally, a new model with consideration of both mechanical and capillary effects is proposed, which can accurately predict gas breakthrough pressure for a GMZ bentonite specimen.


2019 ◽  
Vol 229 ◽  
pp. 116872 ◽  
Author(s):  
Yong-gui Chen ◽  
Zhao Sun ◽  
Yu-jun Cui ◽  
Wei-min Ye ◽  
Qi-hua Liu

2018 ◽  
Vol 161 ◽  
pp. 334-342 ◽  
Author(s):  
Li-Na Liu ◽  
Yong-Gui Chen ◽  
Wei-Min Ye ◽  
Yu-Jun Cui ◽  
Dong-Bei Wu

2019 ◽  
Vol 248 ◽  
pp. 155-163 ◽  
Author(s):  
Ling-Yan Jia ◽  
Yong-Gui Chen ◽  
Wei-Min Ye ◽  
Yu-Jun Cui

Clay Minerals ◽  
2016 ◽  
Vol 51 (2) ◽  
pp. 237-247 ◽  
Author(s):  
Chen Bao ◽  
Guo Jiaxing ◽  
Zhang Huixin

AbstractConcepts for geological disposal of high-level radioactive waste usually include bentonite buffer materials. Numerous studies have been performed with most usingWyoming bentonite. Gaomiaozi (GMZ) bentonite has been selected as a potential buffer/backfill material for the deep geological repository of high-level radioactive waste in China. In this context, the highly alkaline environment induced by cementitious materials in the repository is likely to alter montmorillonite, the main clay mineral in GMZ bentonite. This alteration may result in deterioration of the physical and/or chemical properties of the buffer material. To acquire quantitative data which would allow us to assess the dissolution of montmorillonite and changes in the diffusivity of hydroxide ions as well as their effects on the swelling pressure and permeability of the compacted GMZ bentonite, an experimental study was conducted under highly alkaline (NaOH solutions with various pH values were used), simulated groundwater conditions. The GMZ bentonite also contains cristobalite which may also have been dissolved. The microstructure of the compacted bentonite samples after the experiments was determined by mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). Energy dispersive spectroscopy (EDX) was carried out to identify mineralogical changes. At pH >13, the permeability of specimens increased significantly; the swelling potential decreased with increasing pH. Furthermore, the pore volume and pore size of GMZ bentonite changed when exposed to alkaline solution, resulting in an increase in porosity and permeability. The main alteration mechanisms of compacted GMZ bentonite undergoing infiltration by highly alkaline solution are likely to be dissolution and modifications in terms of the microstructure and mineralogy.


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