scholarly journals Effect of the photoinitiator system on the polymerization of secondary methacrylamides of systematically varied structure for dental adhesive applications

2020 ◽  
Vol 36 (3) ◽  
pp. 468-477 ◽  
Author(s):  
L.M. Barcelos ◽  
M.G. Borges ◽  
C.J. Soares ◽  
M.S. Menezes ◽  
V. Huynh ◽  
...  
Author(s):  
B. Van Meerbeek ◽  
L. J. Conn ◽  
E. S. Duke

Restoration of decayed teeth with tooth-colored materials that can be bonded to tooth tissue has been a highly desirable property in restorative dentistry for many years. Advantages of such an adhesive restorative technique over conventional techniques using non-adhesive metal-based restoratives include improved restoration retention with minimal sacrifice of sound tooth tissue for retention purposes, superior adaptation and sealing of the restoration margins in prevention of caries recurrence, improved stress distribution across the tooth-restoration interface throughout the whole tooth, and even reinforcement of weakened tooth structures. The dental adhesive technology is rapidly changing. An efficient resin bond to enamel has already long been achieved. Its bonding mechanism has been fully elucidated and has proven to be a durable and reliable clinical treatment. However, bonding to dentin represents a greater challenge. After the failures of a dentin acid-etch technique in imitation of the enamel phosphoric-acid-etch technique and a bonding procedure based on chemical adhesion, modern dentin adhesives are currently believed to bond to dentin by a micromechanical hybridization process. This process is developed by an initial demineralization of the dentin surface layer with acid etchants exposing a collagen fibril arrangement with interfibrillar microporosities that subsequently become impregnated by low-viscosity monomers. Although the development of such a hybridization process has well been documented in the literature, questions remain with respect to parameters of-primary importance to adhesive efficacy.


Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1813
Author(s):  
László Kollár ◽  
Ádám Erdélyi ◽  
Haroon Rasheed ◽  
Attila Takács

The aminocarbonylation of various alkenyl and (hetero)aryl iodides was carried out using tropane-based amines of biological importance, such as 8-azabicyclo[3.2.1]octan-3-one (nortropinone) and 3α-hydroxy-8-azabicyclo[3.2.1]octane (nortropine) as N-nucleophile. Using iodoalkenes, the two nucleophiles were selectively converted to the corresponding amide in the presence of Pd(OAc)2/2 PPh3 catalysts. In the presence of several iodo(hetero)arenes, the application of the bidentate Xantphos was necessary to produce the target compounds selectively. The new carboxamides of varied structure, formed in palladium-catalyzed aminocarbonylation reactions, were isolated and fully characterized. In this way, a novel synthetic method has been developed for the producing of N-acylnortropane derivatives of biological importance.


2006 ◽  
Vol 34 (7) ◽  
pp. 472-477 ◽  
Author(s):  
Fabrício Aulo Ogliari ◽  
Marli Luiza Tebaldi de Sordi ◽  
Marco Antônio Ceschi ◽  
Cesar Liberato Petzhold ◽  
Flávio Fernando Demarco ◽  
...  
Keyword(s):  

2014 ◽  
Vol 71 (4) ◽  
pp. 875-886 ◽  
Author(s):  
Hyun-Jin Kim ◽  
Tae-Yub Kwon ◽  
Kyo-Han Kim ◽  
Soon-Taek Kwon ◽  
Dae-Hyun Cho ◽  
...  

Author(s):  
Taíse Alessandra Hanzen ◽  
Mario Felipe Gutiérrez ◽  
Thalita de Paris Matos ◽  
Alexandra Mara de Paula ◽  
Fabiana Suelen Figueredo de Siqueira ◽  
...  

Odontology ◽  
2021 ◽  
Author(s):  
Nayara de Oliveira Souza ◽  
Diana Araújo Cunha ◽  
Nara Sousa Rodrigues ◽  
Thayllan Teixeira Bezerra ◽  
Diego Lomonaco ◽  
...  

2018 ◽  
Author(s):  
Agnieszka Łagoda ◽  
Adam Niesłony

Sign in / Sign up

Export Citation Format

Share Document