Jiaozuo is a typical resource-based city, and its economic transformation has been an example of success in China. However, quantitative evaluation of the city’s development has scarcely been performed, and future development is not clear. Because of this, using the relevant data from 1999 to 2013, this paper uses the data envelopment analysis (DEA) model to evaluate development after the transformation of Jiaozuo with the aim of providing a basis for its future developing plan. The results show that DEA was effective in 2000, 2004, 2006, 2010, and 2012, was weakly effective in 1999, 2001, 2002, 2003, and 2013, and was ineffective in 2005, 2007, 2008, 2009, and 2011. By evaluating the development of Jiaozuo, this paper provides policy implications for Jiaozuo’s sustainable development, and it may serve as a reference for the sustainable development of China’s other resources-based cities.