scholarly journals The Effect of Injection Speed on Morphology and Mechanical Properties of Polyoxymethylene/Poly(Lactic Acid) Blends

2014 ◽  
Vol 56 ◽  
pp. 57-64 ◽  
Author(s):  
Suchalinee Mathurosemontri ◽  
Putinun Auwongsuwan ◽  
Satoshi Nagai ◽  
Hiroyuki Hamada
2017 ◽  
Vol 737 ◽  
pp. 269-274
Author(s):  
Sirirat Wacharawichanant ◽  
Chaninthon Ounyai ◽  
Ployvaree Rassamee

The effects of four types of organoclay on morphology and mechanical properties of poly(lactic acid) (PLA)/propylene-ethylene copolymer (PEC) blends were investigated. The ratio of PLA and PEC was 80/20 by weight and the organoclay content was 5 phr. The morphology analysis showed that the addition of all oganocaly types could improve the miscibility of PLA and PEC blends due to the decreased of the domain sizes of PEC dispersed phase in the polymer matrix. The tensile properties showed Young’s modulus of the PLA/PEC blends was improved after adding clay treated surface with 25-30 wt% trimethyl stearyl ammonium.


2018 ◽  
Vol 916 ◽  
pp. 19-23 ◽  
Author(s):  
Sirirat Wacharawichanant ◽  
Nisarat Wimonsupakit ◽  
Sasithorn Kuhaudomlap

The objective of this study is to fabricate the polyoxymethylene (POM)/microcrystalline cellulose (MCC) and poly(lactic acid) (PLA)/MCC composites, and to compare the effect of MCC on the morphology and mechanical properties of POM and PLA. The polymer composites were prepared by melt mixing in an internal mixer and molded by compression molding. The MCC concentrations were 1, 3, 5, 7, 10, 15 and 10% by weight. From scanning electron microscopy study observes the fracture surface of POM and PLA composites is much rough and the roughness increases with increasing MCC content. This observation indicates MCC induces the ductile fracture characteristic of POM and PLA. The addition of MCC can improve the impact strength of PLA composite and improve Young’s modulus of both POM and PLA composites. While the tensile strength and strain at break decrease after adding MCC. In summary, MCC can enhance the morphology and mechanical properties of PLA composites is better than POM composites.


2016 ◽  
Vol 835 ◽  
pp. 284-288 ◽  
Author(s):  
Sirirat Wacharawichanant ◽  
Chawisa Wisuttrakarn ◽  
Kasana Chomphunoi

The effects of the montmorillonite clay surface modified with 25-30 wt% of methyl dihydroxyethyl hydrogenated tallow ammonium (Clay-MHA) on morphology and mechanical properties of poly(lactic acid) (PLA)/acrylonitrile-butadiene rubber copolymer (NBR)/Clay-MHA composites were investigated. The composites of blends of PLA/NBR with Clay-MHA were prepared by melt mixing in an internal mixer and molded by compression molding. The ratio of PLA and NBR was 80/20 by weight and the Clay-MHA content was 1, 3, 5 and 7 phr. The results showed Young’s modulus and stress at break of the composites increased with increasing Clay-MHA content. While the tensile strength and strain at break of the composites decreased with increasing Clay-MHA content. Scanning electron microscopy analysis showed that the addition of Clay-MHA could improve the miscibility of PLA and NBR to be homogeneous blends and the pore in polymer blends was disappeared.


Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2688
Author(s):  
F.A.M.M. Gonçalves ◽  
Sandra M. A. Cruz ◽  
Jorge F. J. Coelho ◽  
Arménio C. Serra

Poly (lactic acid) (PLA), due to its biodegradability, biocompatibility, and renewability, is one of the most promising biobased polymers for replacing some of the petrol-based materials. Low flexibility of PLA is overcome, by blending it with olefin-based polymers, such as polypropylene (PP). However, the use of compatibilizing agents is required to attain final materials with suitable mechanical properties. Such agents, although essential, can affect PLA structure and, consequently, the mechanical properties of the PLA. To the best of our knowledge, this issue was never studied, and the results can contribute to achieving the best formulations of PLA-based blends according to their final applications. The thermal and mechanical properties of the extruded PLA, with three different commercial compatibilizing agents, were evaluated with the purpose of demonstrating how the compatibilizers can introduce structural differences into the PLA chain during the extrusion process. The combination of crystallinity, molecular weight, and the morphology of the samples after extrusion determines the final mechanical properties of PLA. Despite being a fundamental study, it is our aim to contribute to the sustainability of PLA-based industries. The addition of a 2.5% concentration of C1 compatibilizer seems to have less influence on the final morphology and mechanical properties of the blends.


Author(s):  
Jipeng Guo ◽  
Chi-Hui Tsou ◽  
Yongqi Yu ◽  
Chin-San Wu ◽  
Xuemei Zhang ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 776
Author(s):  
Sixiang Zhai ◽  
Qingying Liu ◽  
Yuelong Zhao ◽  
Hui Sun ◽  
Biao Yang ◽  
...  

With the depletion of petroleum energy, the possibility of prices of petroleum-based materials increasing, and increased environmental awareness, biodegradable materials as a kind of green alternative have attracted more and more research attention. In this context, poly (lactic acid) has shown a unique combination of properties such as nontoxicity, biodegradability, biocompatibility, and good workability. However, examples of its known drawbacks include poor tensile strength, low elongation at break, poor thermal properties, and low crystallization rate. Lignocellulosic materials such as lignin and cellulose have excellent biodegradability and mechanical properties. Compounding such biomass components with poly (lactic acid) is expected to prepare green composite materials with improved properties of poly (lactic acid). This paper is aimed at summarizing the research progress of modification of poly (lactic acid) with lignin and cellulose made in in recent years, with emphasis on effects of lignin and cellulose on mechanical properties, thermal stability and crystallinity on poly (lactic acid) composite materials. Development of poly (lactic acid) composite materials in this respect is forecasted.


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