Time resolved study of electrode reactions using Fourier transform impedance spectroscopy: mutually correlated adsorption kinetics of Cu2+ and ClO4− on gold

2004 ◽  
Vol 49 (20) ◽  
pp. 3293-3304 ◽  
Author(s):  
C.M. Pettit ◽  
J.E. Garland ◽  
M.J. Walters ◽  
D. Roy
Keyword(s):  
Fourier Transform ◽  
Impedance Spectroscopy ◽  
Adsorption Kinetics ◽  
Time Resolved ◽  
Electrode Reactions ◽  
Kinetics Of

Time-Resolved Kinetics of Electrode Reactions

2019 ◽  
Vol 1 (6) ◽  
pp. 3-15
Author(s):  
Eliezer Gileadi
Keyword(s):  
Time Resolved ◽  
Electrode Reactions ◽  
Kinetics Of

Adsorption Kinetics of EGDN on ZnO by Diffuse Reflectance Infrared Fourier Transform Spectroscopy

1993 ◽  
Vol 47 (4) ◽  
pp. 528-532 ◽  
Author(s):  
D. O. Henderson ◽  
E. Silberman ◽  
N. Chen ◽  
F. W. Snyder
Keyword(s):  
Zinc Oxide ◽  
Fourier Transform ◽  
Adsorption Kinetics ◽  
Diffuse Reflectance ◽  
Fourier Transform Spectroscopy ◽  
Nonlinear Curve Fitting ◽  
Stretching Vibration ◽  
Diffuse Reflectance Infrared ◽  
Kinetics Of ◽  
Dose Dependent

Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was used to follow the adsorption kinetics of ethyleneglycol dinitrate (EGDN) on zinc oxide as a function of dosing time. Inhomogeneous broadening of the NO2 antisymmetric stretching vibration was found to be dose dependent. Through nonlinear curve-fitting techniques, the sum of three component bands was found to reproduce the inhomogeneously broadened envelope and was attributed to two different types of adsorbed EGDN corresponding to on-end and bridged sites on a zinc rich surface of zinc oxide. The adsorbed EGDN species were characterized by their line-shape parameters and adsorption kinetics.

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