A facile electrosynthesis approach of amorphous Mn-Co-Fe ternary hydroxides as binder-free active electrode materials for high-performance supercapacitors

2019 ◽  
Vol 296 ◽  
pp. 59-68 ◽  
Author(s):  
Ayman E. Elkholy ◽  
Fakiha El-Taib Heakal ◽  
Nageh K. Allam
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
Active Electrode ◽  
Binder Free

scholarly journals Ce-Doped PANI/Fe3O4 Nanocomposites: Electrode Materials for Supercapattery

2021 ◽  
Vol 3 ◽  
Author(s):  
Subash Pandey ◽  
Shova Neupane ◽  
Dipak Kumar Gupta ◽  
Anju Kumari Das ◽  
Nabin Karki ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Electrode Material ◽  
High Performance ◽  
Electrode Materials ◽  
Specific Capacity ◽  
Maximum Energy ◽  
Potential Range ◽  
X Ray Diffraction ◽  
Active Electrode ◽  
Transmission Electron

In this study, we report on a combined approach to preparing an active electrode material for supercapattery application by making nanocomposites of Polyaniline/Cerium (PANI/Ce) with different weight percentages of magnetite (Fe3O4). Fourier-transform infrared spectroscopy (FTIR) and x-ray diffraction (XRD) analyses supported the interaction of PANI with Ce and the formation of the successful nanocomposite with magnetite nanoparticles. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses showed the uniform and porous morphology of the composites. Cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) were used to test the supercapattery behavior of the nanocomposite electrodes in 1.0 M H2SO4. It was found that the supercapattery electrode of PANI/Ce+7 wt.% Fe3O4 exhibited a specific capacity of 171 mAhg−1 in the potential range of −0.2 to 1.0 V at the current density of 2.5 Ag−1. Moreover, PANI/Ce+7 wt.% Fe3O4 revealed a power density of 376.6 Wkg−1 along with a maximum energy density of 25.4 Whkg−1 at 2.5 Ag−1. Further, the cyclic stability of PANI/Ce+7 wt.% Fe3O4 was found to be 96.0% after 5,000 cycles. The obtained results suggested that the PANI/Ce+Fe3O4 nanocomposite could be a promising electrode material candidate for high-performance supercapattery applications.

Design and synthesis of hierarchical mesoporous WO3-MnO2 composite nanostructures on carbon cloth for high-performance supercapacitors

2017 ◽  
Vol 3 (1) ◽  
Author(s):  
Pragati A. Shinde ◽  
Vaibhav C. Lokhande ◽  
Amar M. Patil ◽  
Taeksoo Ji ◽  
Chandrakant D. Lokhande
Keyword(s):  
Energy Density ◽  
High Performance ◽  
Rational Design ◽  
Electrode Materials ◽  
Mesoporous Structure ◽  
Carbon Cloth ◽  
Power Performance ◽  
Active Electrode ◽  
Composite Nanostructures ◽  
Design And Synthesis

AbstractTo enhance the energy density and power performance of supercapacitors, the rational design and synthesis of active electrode materials with hierarchical mesoporous structure is highly desired. In the present work, fabrication of high-performance hierarchical mesoporous WO

scholarly journals Hierarchical Core/Shell Structured Ag@Ni(OH)2 Nanospheres as Binder-Free Electrodes for High Performance Supercapacitors

Crystals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 118
Author(s):  
Sa Lv ◽  
Xuefeng Chu ◽  
Fan Yang ◽  
Huan Wang ◽  
Jia Yang ◽  
...  
Keyword(s):  
High Performance ◽  
Copper Substrate ◽  
High Specific Capacitance ◽  
Electrochemical Reactions ◽  
Galvanic Replacement ◽  
Active Electrode ◽  
Step Process ◽  
Copper Foam ◽  
Binder Free ◽  
Enhanced Electrochemical Performance

Hierarchical Ag@Ni(OH)2 nanospheres were achieved directly on copper foam substrate through a convenient two-step process. Ag nanoflowers were formed on copper substrate by galvanic replacement technology between AgNO3 and copper foam followed by electrodeposition of a layer of Ni(OH)2. Ag nanostructures as cores not only dominated the final morphology of the composites, but also improved the electrical conductivity, increased the specific surface area of the active electrode material, and even directly participated in the electrochemical reactions. The resulted Ag@Ni(OH)2 nanospheres could be directly used as high-performance binder-free electrodes and exhibited enhanced electrochemical performance with a high specific capacitance of 1.864 F cm−2 and long cycling lifespans of 90.43% capacity retaining after 3000 cycles.

Bioinspired tailoring of nanoarchitectured nickel sulfide@nickel permeated carbon composite as highly durable and redox chemistry enabled battery-type electrode for hybrid supercapacitors

2021 ◽  
Author(s):  
Mohan Reddy Pallavolu ◽  
Ramesh Reddy N ◽  
Hemachandra Rao Goli ◽  
Arghya Narayan Banerjee ◽  
G. Rajasekhara Reddy ◽  
...  
Keyword(s):  
High Performance ◽  
Rational Design ◽  
Electrode Materials ◽  
Cost Effective ◽  
Carbon Composite ◽  
Metal Chalcogenides ◽  
Energy Storage Devices ◽  
Active Electrode ◽  
Storage Devices ◽  
Hybrid Supercapacitors

Rational design of highly conductive and redox-active electrode materials composed of metal chalcogenides and carbon composites has attracted promising attention for the development of high-performance energy storage devices. Herein, cost-effective...

A one-step, cost-effective green method to in situ fabricate Ni(OH)2 hexagonal platelets on Ni foam as binder-free supercapacitor electrode materials

2015 ◽  
Vol 3 (5) ◽  
pp. 1953-1960 ◽  
Author(s):  
Lingjie Li ◽  
Jing Xu ◽  
Jinglei Lei ◽  
Jie Zhang ◽  
Frank McLarnon ◽  
...  
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
Three Dimensional ◽  
Cost Effective ◽  
Ni Foam ◽  
Supercapacitor Electrode ◽  
One Step ◽  
Binder Free ◽  
Supercapacitor Electrode Materials

The Ni(OH)2 hexagonal platelets were in situ fabricated on Ni foam as a binder-free supercapacitor electrode material with high performance and excellent cycling stability by a one-step, cost-effective, green hydrothermal treatment of three-dimensional (3D) Ni foam in a 15 wt% H2O2 aqueous solution.

scholarly journals ZnO Nano-Flowers Assembled on Carbon Fiber Textile for High-Performance Supercapacitor’s Electrode

Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1337
Author(s):  
Qasim Abbas ◽  
Muhammad Sufyan Javed ◽  
Awais Ahmad ◽  
Sajid Hussain Siyal ◽  
Idress Asim ◽  
...  
Keyword(s):  
Carbon Fiber ◽  
High Performance ◽  
Electrode Materials ◽  
Low Cost ◽  
Hydrothermal Process ◽  
Effective Surface Area ◽  
Effective Surface ◽  
Efficient Diffusion ◽  
Binder Free ◽  
Simple Hydrothermal Process

Herein, a crystalline nano-flowers structured zinc oxide (ZnO) was directly grown on carbon fiber textile (CFT) substrate via a simple hydrothermal process and fabricated with a binder-free electrode (denoted as ZnO@CFT) for supercapacitor (SC) utilization. The ZnO@CFT electrode revealed a 201 F·g−1 specific capacitance at 1 A·g−1 with admirable stability of >90% maintained after 3000 cycles at 10 A·g−1. These impressive findings are responsible for the exceedingly open channels for well-organized and efficient diffusion of effective electrolytic conduction via ZnO and CFT. Consequently, accurate and consistent structural and morphological manufacturing engineering is well regarded when increasing electrode materials’ effective surface area and intrinsic electrical conduction capability. The crystalline structure of ZnO nano-flowers could pave the way for low-cost supercapacitors.

scholarly journals Flexible, Transparent and Highly Conductive Polymer Film Electrodes for All-Solid-State Transparent Supercapacitor Applications

Membranes ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 788
Author(s):  
Xin Guan ◽  
Lujun Pan ◽  
Zeng Fan
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Electrochemical Properties ◽  
Polymer Film ◽  
High Performance ◽  
Electrode Materials ◽  
Wearable Electronics ◽  
Energy Storage Devices ◽  
Active Electrode ◽  
Supercapacitor Applications

Lightweight energy storage devices with high mechanical flexibility, superior electrochemical properties and good optical transparency are highly desired for next-generation smart wearable electronics. The development of high-performance flexible and transparent electrodes for supercapacitor applications is thus attracting great attention. In this work, we successfully developed flexible, transparent and highly conductive film electrodes based on a conducting polymer, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). The PEDOT:PSS film electrodes were prepared via a simple spin-coating approach followed by a post-treatment with a salt solution. After treatment, the film electrodes achieved a high areal specific capacitance (3.92 mF/cm2 at 1 mA/cm2) and long cycling lifetime (capacitance retention >90% after 3000 cycles) with high transmittance (>60% at 550 nm). Owing to their good optoelectronic and electrochemical properties, the as-assembled all-solid-state device for which the PEDOT:PSS film electrodes were utilized as both the active electrode materials and current collectors also exhibited superior energy storage performance over other PEDOT-based flexible and transparent symmetric supercapacitors in the literature. This work provides an effective approach for producing high-performance, flexible and transparent polymer electrodes for supercapacitor applications. The as-obtained polymer film electrodes can also be highly promising for future flexible transparent portable electronics.

A novel electrochemical procedure for grown of bimetallic metal–organic framework (Ni/Zn-MOF) and its derived hydroxide@C onto Ni foam as binder-free high performance battery-type electrodes for supercapacitors

2021 ◽  
Author(s):  
Qichao Song ◽  
Chunguang Yang
Keyword(s):  
Energy Storage ◽  
High Performance ◽  
Electrode Materials ◽  
Metal Organic Framework ◽  
Ni Foam ◽  
Energy Storage Devices ◽  
Cathodic Electrodeposition ◽  
Storage Devices ◽  
Metal Organic ◽  
Binder Free

Abstract Todays, metal-organic frameworks (MOFs) and their derived structures have been extensively investigated as the novel electrode materials in energy storage area due to their stable porous architectures and exceptionally large specific surface area. In this study, bimetallic Ni,Zn-MOF is synthesized onto Ni foam via a novel indirect cathodic electrodeposition method for the first time. After that, the fabricated Ni,Zn-MOFs onto Ni foam was converted to corresponding bi-metal hydroxide@C/Ni foam through direct chemical treating with 6M KOH solution. The obtained Ni,Zn-MOFs/NF and Ni2 − xZnx (OH)2@C/NF electrodes are characterized through XRD, FT-IR, FE-SEM and EDS analyses. These analyses results confirmed deposition of well-defined crystalline porous sheet-like structures of Ni3 − xZnx(BTC)2 deposited onto Ni foam, where the hydroxide@C electrode was also exhibited similar morphology. As the binder-free electrode, the as-prepared Ni,Zn-MOF@Ni foam exhibited the superior storage capacities of 356.1 mAh g− 1 and 255.5 mAh g− 1 as well as good cycling stabilities of 94.2 % and 84.5 % after 6000 consecutive charge/discharge cycles at the current densities of 5 and 15 A g− 1, respectively. On the other hand, Ni,Zn-MOF derived hydroide@C/Ni foam presented the superior capacities of 545 mAh g− 1 and 406 mAh g− 1 as well as proper cycle lifes of 91.8 % and 78.3 % after 6000 cycling at the applied loads of 5 and 15 A g− 1, respectively. Based on these findings, both of these fabricated battery-type electrodes are introduced as the promising candidates for use in energy storage devices.

Sign in / Sign up

Export Citation Format

Share Document