scholarly journals Preparation of high surface area Cu-Au bimetallic nanostructured materials by co-electrodeposition in a deep eutectic solvent

2021 ◽  
pp. 139309
Author(s):  
Elena Plaza-Mayoral ◽  
Paula Sebastián-Pascual ◽  
Kim Nicole Dalby ◽  
Kim Degn Jensen ◽  
Ib Chorkendorff ◽  
...  
2021 ◽  
Author(s):  
Elena Plaza Mayoral ◽  
Paula Sebastián Pascual ◽  
Kim Nicole Dalby ◽  
Kim Degn Jensen ◽  
Ib Chorkendorff ◽  
...  

In this work we present an electrodeposition method in a deep eutectic solvent (DES) to prepare bimetallic high surface area nanostructures of Cu and Au with tunable structure and composition. The metal electrodeposition performed in green choline chloride within a urea deep eutectic solvent allows us to tailor the size, morphology and elemental composition of the deposits. We combine electrochemical methods with scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDS) to characterize the electrodeposited nanostructured materials. We assess the increase of the electroactive surface area through the analysis of the lead underpotential deposition (UPD) on the prepared films. We observe a 5 to 15-fold increase of the active surface area compared to flat surfaces of polycrystalline Cu or Au. Our work reports, for the first time, a green route for the electrodeposition of Cu-Au bimetallic nanostructures in a deep eutectic solvent.


2021 ◽  
Author(s):  
Elena Plaza Mayoral ◽  
Paula Sebastián Pascual ◽  
Kim Nicole Dalby ◽  
Kim Degn Jensen ◽  
Ib Chorkendorff ◽  
...  

In this work we present an electrodeposition method in a deep eutectic solvent (DES) to prepare bimetallic high surface area nanostructures of Cu and Au with tunable structure and composition. The metal electrodeposition performed in green choline chloride within a urea deep eutectic solvent allows us to tailor the size, morphology and elemental composition of the deposits. We combine electrochemical methods with scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and energy dispersive X-ray spectroscopy (EDS) to characterize the electrodeposited nanostructured materials. We assess the increase of the electroactive surface area through the analysis of the lead underpotential deposition (UPD) on the prepared films. We observe a 5 to 15-fold increase of the active surface area compared to flat surfaces of polycrystalline Cu or Au. Our work reports, for the first time, a green route for the electrodeposition of Cu-Au bimetallic nanostructures in a deep eutectic solvent.


2017 ◽  
Vol 266 ◽  
pp. 84-89 ◽  
Author(s):  
Mohd Hasmizam Razali ◽  
Nur Arifah Ismail ◽  
Khairul Anuar Mat Amin

Nanostructured materials are a new class of materials which provide one of the greatest potentials for improving performance and extended capabilities of products in a number of applications. In particular nanostructured TiO2 was used as photocatalysts, gas sensor, solar cells and nanocomposite biomaterials. For each of these applications, aspects such as surface morphology, crystallinity and chemistry of the titania-based materials are the key parameters to be settled for the process optimization. A series of nanostructured TiO2 materials (TiO2 nanotubes, TiO2 nanorods, TiO2 nanoparticles) was synthesized using simple hydrothermal methods. X-Ray Diffraction (XRD), Field Emission Scanning Electron microscope (FESEM) and Brunauer–Emmett–Teller (BET) surface area characterization was carried out to study the properties of synthesized nanostructured TiO2 materials. The performance of synthesized nanostructured TiO2 was evaluated for various applications such as photocatalyst for methyl orange (MO) degradation and anti-bacterial thin film for biomedical and food packaging. Among the nanostructured TiO2 materials, TiO2 nanotubes shows the highest activity regardless of their applications. This is probably due to their nanotubular morphology in which provided high surface area materials. The surface area of TiO2 nanotubes was found to be 226.52 m2/g. The outer and inner diameters of nanotubes are 4 nm and 10 nm, respectively with several hundred nanometers in length. Anatase TiO2 phase structure and crystallinity of TiO2 nanotubes supports the good performances of the nanostructured materials.


Author(s):  
Alexandru SIRGHIE ◽  
◽  
Mihai OPROESCU ◽  
Gabriel Vasile IANA ◽  
Adriana Gabriela PLAIASU

Nanomaterials are gaining significance in technological applications due to their chemical, physical, and mechanical properties and enhanced performance when compared with their bulkier counterparts. The synthesis of nanostructured materials has led to a significant increase in properties (thermal, optical, electrical, magnetic, mechanical) as well as the discovery of materials with new properties due the fact that at the nanoscale the materials have a high surface area Most applications of nanomaterials in sensors are related to their synthesis. In this paper we report recent trends in applications of various nanomaterials such as nanoparticles, carbon nanotubes, nanowires andgraphene to detect CBRN agents.


Author(s):  
Kailun Yang ◽  
Recep Kas ◽  
Wilson A. Smith

<p>This study evaluated the performance of the commonly used strong buffer electrolytes, i.e. phosphate buffers, during CO<sub>2</sub> electroreduction in neutral pH conditions by using in-situ surface enhanced infrared absorption spectroscopy (SEIRAS). Unfortunately, the buffers break down a lot faster than anticipated which has serious implications on many studies in the literature such as selectivity and kinetic analysis of the electrocatalysts. Increasing electrolyte concentration, surprisingly, did not extend the potential window of the phosphate buffers due to dramatic increase in hydrogen evolution reaction. Even high concentration phosphate buffers (1 M) break down within the potentials (-1 V vs RHE) where hydrocarbons are formed on copper electrodes. We have extended the discussion to high surface area electrodes by evaluating electrodes composed of copper nanowires. We would like highlight that it is not possible to cope with high local current densities on these high surface area electrodes by using high buffer capacity solutions and the CO<sub>2</sub> electrocatalysts are needed to be evaluated by casting thin nanoparticle films onto inert substrates as commonly employed in fuel cell reactions and up to now scarcely employed in CO<sub>2</sub> electroreduction. In addition, we underscore that normalization of the electrocatalytic activity to the electrochemical active surface area is not the ultimate solution due to concentration gradient along the catalyst layer.This will “underestimate” the activity of high surface electrocatalyst and the degree of underestimation will depend on the thickness, porosity and morphology of the catalyst layer. </p> <p> </p>


Nanoscale ◽  
2015 ◽  
Vol 7 (25) ◽  
pp. 10974-10981 ◽  
Author(s):  
Xiulin Yang ◽  
Ang-Yu Lu ◽  
Yihan Zhu ◽  
Shixiong Min ◽  
Mohamed Nejib Hedhili ◽  
...  

High surface area FeP nanosheets on a carbon cloth were prepared by gas phase phosphidation of electroplated FeOOH, which exhibit exceptionally high catalytic efficiency and stability for hydrogen generation.


Author(s):  
Sisir Maity ◽  
Dheeraj Kumar Singh ◽  
Divya Bhutani ◽  
Suchitra Prasad ◽  
Umesh V. Waghmare ◽  
...  

MethodsX ◽  
2021 ◽  
pp. 101464
Author(s):  
Yichen Wu ◽  
Nan Zhang ◽  
Charles-François de Lannoy

2021 ◽  
Author(s):  
Gurwinder Singh ◽  
Rohan Bahadur ◽  
Ajanya Maria Ruban ◽  
Jefrin Marykala Davidraj ◽  
Dawei Su ◽  
...  

Nanoporous biocarbons derived from waste biomass have created significant attention owing to their great potential for energy storage and conversion and water purification. However, the fabrication technology for these materials...


Sign in / Sign up

Export Citation Format

Share Document