Experimental study on gas diffusion dynamics in fractured coal: A better understanding of gas migration in in-situ coal seam

Energy ◽  
2020 ◽  
Vol 195 ◽  
pp. 117005 ◽  
Author(s):  
Ting Liu ◽  
Baiquan Lin ◽  
Xuehai Fu ◽  
Yabin Gao ◽  
Jia Kong ◽  
...  

We present the results of a theoretical investigation of the trapping and migration of the fission gas atoms, Kr and Xe in UO 2 . Our models differ from those previously presented in discussions of rare gas diffusion in ionic crystals. We propose that trapping occurs at vacancy aggregates, and that detrapping into interstitial sites is unimportant; gas migration is effected by the intrinsic mobility of the gas-trap complexes. We suggest that the trapping and diffusion of the two gas atoms occur by different mechanisms, owing to their different sizes. Our results explain many of the observations of the experimental study of Felix & Miekeley and emphasize the importance of the chemical composition of the fuel on gas diffusion coefficients. The contradictions between this work and the earlier studies summarized by Matzke is, we suggest, possibly due to the higher levels of radiation damage which may have been present in the crystals used in the latter work.


Water ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1525
Author(s):  
Christian Ferrarin ◽  
Pierluigi Penna ◽  
Antonella Penna ◽  
Vedrana Spada ◽  
Fabio Ricci ◽  
...  

The aim of this study is to develop a relocatable modelling system able to describe the microbial contamination that affects the quality of coastal bathing waters. Pollution events are mainly triggered by urban sewer outflows during massive rainy events, with relevant negative consequences on the marine environment and tourism and related activities of coastal towns. A finite element hydrodynamic model was applied to five study areas in the Adriatic Sea, which differ for urban, oceanographic and morphological conditions. With the help of transport-diffusion and microbial decay modules, the distribution of Escherichia coli was investigated during significant events. The numerical investigation was supported by detailed in situ observational datasets. The model results were evaluated against water level, sea temperature, salinity and E. coli concentrations acquired in situ, demonstrating the capacity of the modelling suite in simulating the circulation in the coastal areas of the Adriatic Sea, as well as several main transport and diffusion dynamics, such as riverine and polluted waters dispersion. Moreover, the results of the simulations were used to perform a comparative analysis among the different study sites, demonstrating that dilution and mixing, mostly induced by the tidal action, had a stronger effect on bacteria reduction with respect to microbial decay. Stratification and estuarine dynamics also play an important role in governing microbial concentration. The modelling suite can be used as a beach management tool for improving protection of public health, as required by the EU Bathing Water Directive.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jing Li ◽  
Xiaoxia Chang ◽  
Haochen Zhang ◽  
Arnav S. Malkani ◽  
Mu-jeng Cheng ◽  
...  

AbstractRigorous electrokinetic results are key to understanding the reaction mechanisms in the electrochemical CO reduction reaction (CORR), however, most reported results are compromised by the CO mass transport limitation. In this work, we determined mass transport-free CORR kinetics by employing a gas-diffusion type electrode and identified dependence of catalyst surface speciation on the electrolyte pH using in-situ surface enhanced vibrational spectroscopies. Based on the measured Tafel slopes and reaction orders, we demonstrate that the formation rates of C2+ products are most likely limited by the dimerization of CO adsorbate. CH4 production is limited by the CO hydrogenation step via a proton coupled electron transfer and a chemical hydrogenation step of CO by adsorbed hydrogen atom in weakly (7 < pH < 11) and strongly (pH > 11) alkaline electrolytes, respectively. Further, CH4 and C2+ products are likely formed on distinct types of active sites.


Author(s):  
Xiaojie Fang ◽  
Caifang Wu ◽  
Xiuming Jiang ◽  
Ningning Liu ◽  
Dan Zhou ◽  
...  

2021 ◽  
Vol 113 (1-2) ◽  
pp. 321-335
Author(s):  
Zhenyu Zuo ◽  
Jie Chen ◽  
Weiwei Yu ◽  
Yugang Li ◽  
Dong Chen ◽  
...  

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