High concentrations and dry deposition of reactive nitrogen species at two sites in the North China Plain

2009 ◽  
Vol 157 (11) ◽  
pp. 3106-3113 ◽  
Author(s):  
J.L. Shen ◽  
A.H. Tang ◽  
X.J. Liu ◽  
A. Fangmeier ◽  
K.T.W. Goulding ◽  
...  
2019 ◽  
Vol 651 ◽  
pp. 2312-2322 ◽  
Author(s):  
Jiao Du ◽  
Xiaodong Zhang ◽  
Tao Huang ◽  
Hong Gao ◽  
Jingyue Mo ◽  
...  

2020 ◽  
Author(s):  
Tao Ma ◽  
Hiroshi Furutani ◽  
Fengkui Duan ◽  
Takashi Kimoto ◽  
Jingkun Jiang ◽  
...  

Abstract. Severe winter hazes accompanied by high concentrations of fine particulate matter (PM2.5) occur frequently in the North China Plain and threaten public health. Organic matter (OM) and sulfate are recognized as major components of PM2.5, while atmospheric models often fail to predict their high concentrations during severe winter hazes due to incomplete understanding of secondary aerosol formation mechanisms. By using a novel combination of single particle mass spectrometer and optimized ion chromatography measurement, here we show that hydroxymethanesulfonate (HMS), formed by the reaction between formaldehyde (HCHO) and dissolved SO2 in aerosol water, is ubiquitous in Beijing winter. The HMS concentration and the molar ratio of HMS to sulfate increased with the deterioration of winter haze. High concentrations of precursors (SO2 and HCHO) coupled with low oxidant levels, low temperature, high relative humidity, and moderately acid pH facilitate the heterogeneous formation of HMS, which could account for up to 15 % of OM in winter haze and lead to 36 % overestimates of sulfate when using traditional ion chromatography measurements. Despite the clean air actions have substantially reduced SO2 emissions, HMS concentration and molar ratio of HMS to sulfate during severe winter hazes increased from 2015 to 2016 with the growth of HCHO concentration. Our findings illustrate the significant contribution of heterogeneous HMS chemistry to severe winter hazes in Beijing, which help to improve the prediction of OM and sulfate, and suggest that the reduction in HCHO can help to mitigate haze pollution.


2020 ◽  
Vol 20 (10) ◽  
pp. 5887-5897 ◽  
Author(s):  
Tao Ma ◽  
Hiroshi Furutani ◽  
Fengkui Duan ◽  
Takashi Kimoto ◽  
Jingkun Jiang ◽  
...  

Abstract. Severe winter haze accompanied by high concentrations of fine particulate matter (PM2.5) occurs frequently in the North China Plain and threatens public health. Organic matter (OM) and sulfate are recognized as major components of PM2.5, while atmospheric models often fail to predict their high concentrations during severe winter haze due to incomplete understanding of secondary aerosol formation mechanisms. By using a novel combination of single-particle mass spectrometry and an optimized ion chromatography method, here we show that hydroxymethanesulfonate (HMS), formed by the reaction between formaldehyde (HCHO) and dissolved SO2 in aerosol water, is ubiquitous in Beijing during winter. The HMS concentration and the molar ratio of HMS to sulfate increased with the deterioration of winter haze. High concentrations of precursors (SO2 and HCHO) coupled with low oxidant levels, low temperature, high relative humidity, and moderately acidic pH facilitate the heterogeneous formation of HMS, which could account for up to 15 % of OM in winter haze and lead to up to 36 % overestimates of sulfate when using traditional ion chromatography. Despite the clean air actions having substantially reduced SO2 emissions, the HMS concentration and molar ratio of HMS to sulfate during severe winter haze increased from 2015 to 2016 with the growth in HCHO concentration. Our findings illustrate the significant contribution of heterogeneous HMS chemistry to severe winter haze in Beijing, which helps to improve the prediction of OM and sulfate and suggests that the reduction in HCHO can help to mitigate haze pollution.


Author(s):  
Min Xue ◽  
Jianzhong Ma ◽  
Guiqian Tang ◽  
Shengrui Tong ◽  
Bo Hu ◽  
...  

Sensors ◽  
2020 ◽  
Vol 21 (1) ◽  
pp. 46
Author(s):  
Gangqiang Zhang ◽  
Wei Zheng ◽  
Wenjie Yin ◽  
Weiwei Lei

The launch of GRACE satellites has provided a new avenue for studying the terrestrial water storage anomalies (TWSA) with unprecedented accuracy. However, the coarse spatial resolution greatly limits its application in hydrology researches on local scales. To overcome this limitation, this study develops a machine learning-based fusion model to obtain high-resolution (0.25°) groundwater level anomalies (GWLA) by integrating GRACE observations in the North China Plain. Specifically, the fusion model consists of three modules, namely the downscaling module, the data fusion module, and the prediction module, respectively. In terms of the downscaling module, the GRACE-Noah model outperforms traditional data-driven models (multiple linear regression and gradient boosting decision tree (GBDT)) with the correlation coefficient (CC) values from 0.24 to 0.78. With respect to the data fusion module, the groundwater level from 12 monitoring wells is incorporated with climate variables (precipitation, runoff, and evapotranspiration) using the GBDT algorithm, achieving satisfactory performance (mean values: CC: 0.97, RMSE: 1.10 m, and MAE: 0.87 m). By merging the downscaled TWSA and fused groundwater level based on the GBDT algorithm, the prediction module can predict the water level in specified pixels. The predicted groundwater level is validated against 6 in-situ groundwater level data sets in the study area. Compare to the downscaling module, there is a significant improvement in terms of CC metrics, on average, from 0.43 to 0.71. This study provides a feasible and accurate fusion model for downscaling GRACE observations and predicting groundwater level with improved accuracy.


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