scholarly journals In-situ borehole temperature measurements confirm dynamics of the gas hydrate stability zone at the upper Danube deep sea fan, Black Sea

2021 ◽  
Vol 563 ◽  
pp. 116869
Author(s):  
Michael Riedel ◽  
Tim Freudenthal ◽  
Jörg Bialas ◽  
Cord Papenberg ◽  
Matthias Haeckel ◽  
...  
Geosciences ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 193 ◽  
Author(s):  
Marcelo Ketzer ◽  
Daniel Praeg ◽  
Maria A.G. Pivel ◽  
Adolpho H. Augustin ◽  
Luiz F. Rodrigues ◽  
...  

Gas hydrate provinces occur in two sedimentary basins along Brazil’s continental margin: (1) The Rio Grande Cone in the southeast, and (2) the Amazon deep-sea fan in the equatorial region. The occurrence of gas hydrates in these depocenters was first detected geophysically and has recently been proven by seafloor sampling of gas vents, detected as water column acoustic anomalies rising from seafloor depressions (pockmarks) and/or mounds, many associated with seafloor faults formed by the gravitational collapse of both depocenters. The gas vents include typical features of cold seep systems, including shallow sulphate reduction depths (<4 m), authigenic carbonate pavements, and chemosynthetic ecosystems. In both areas, gas sampled in hydrate and in sediments is dominantly formed by biogenic methane. Calculation of the methane hydrate stability zone for water temperatures in the two areas shows that gas vents occur along its feather edge (water depths between 510 and 760 m in the Rio Grande Cone and between 500 and 670 m in the Amazon deep-sea fan), but also in deeper waters within the stability zone. Gas venting along the feather edge of the stability zone could reflect gas hydrate dissociation and release to the oceans, as inferred on other continental margins, or upward fluid flow through the stability zone facilitated by tectonic structures recording the gravitational collapse of both depocenters. The potential quantity of venting gas on the Brazilian margin under different scenarios of natural or anthropogenic change requires further investigation. The studied areas provide natural laboratories where these critical processes can be analyzed and quantified.


Author(s):  
Marcelo Ketzer ◽  
Daniel Praeg ◽  
Maria A.G. Pivel ◽  
Adolpho H. Augustin ◽  
Luiz F. Rodrigues ◽  
...  

Gas hydrate provinces are present in at least in two areas along Brazil&rsquo;s continental margin: (1) the Rio Grande Cone in the southeast, and (2) the Amazon deep-sea fan in the equatorial region. The occurrence of gas hydrates in these depocentres was first detected geophysically and has recently been proven by seafloor sampling of gas vents, detected as water column acoustic anomalies rising from seafloor depressions (pockmarks) and/or mounds, many associated with seafloor faults. The gas vents include typical features of cold seep systems, including shallow sulphate reduction depths (&lt;4 m), authigenic carbonate pavements and chemosynthetic ecosystems. In both areas, gas sampled in hydrate and in sediments is dominantly formed by biogenic methane. Calculation of the methane hydrate stability zone for water temperatures in the two areas shows that gas vents occur along its feather edge (water depths between 510-760 m in the Rio Grande Cone and 500-670 m in the Amazon deep-sea fan) but also in deeper waters within the stability zone. Gas venting along the feather edge of the stability zone could reflect gas hydrate dissociation and release to the oceans, as inferred on other continental margins, or upward fluid flow through the stability zone facilitated by tectonic structures recording the gravitational collapse of both depocentres. The potential quantity of venting gas on the Brazilian margin under different scenarios of natural or anthropogenic change require further investigation. The studied areas provide a natural laboratory where these critical processes can be analysed and quantified.


Energies ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 3403 ◽  
Author(s):  
Burwicz ◽  
Rüpke

Marine sediments of the Blake Ridge province exhibit clearly defined geophysical indications for the presence of gas hydrates and a free gas phase. Despite being one of the world’s best-studied gas hydrate provinces and having been drilled during Ocean Drilling Program (ODP) Leg 164, discrepancies between previous model predictions and reported chemical profiles as well as hydrate concentrations result in uncertainty regarding methane sources and a possible co-existence between hydrates and free gas near the base of the gas hydrate stability zone (GHSZ). Here, by using a new multi-phase finite element (FE) numerical model, we investigate different scenarios of gas hydrate formation from both single and mixed methane sources (in-situ biogenic formation and a deep methane flux). Moreover, we explore the evolution of the GHSZ base for the past 10 Myr using reconstructed sedimentation rates and non-steady-state P-T solutions. We conclude that (1) the present-day base of the GHSZ predicted by our model is located at the depth of ~450 mbsf, thereby resolving a previously reported inconsistency between the location of the BSR at ODP Site 997 and the theoretical base of the GHSZ in the Blake Ridge region, (2) a single in-situ methane source results in a good fit between the simulated and measured geochemical profiles including the anaerobic oxidation of methane (AOM) zone, and (3) previously suggested 4 vol.%–7 vol.% gas hydrate concentrations would require a deep methane flux of ~170 mM (corresponds to the mass of methane flux of 1.6 × 10−11 kg s−1 m−2) in addition to methane generated in-situ by organic carbon (POC) degradation at the cost of deteriorating the fit between observed and modelled geochemical profiles.


Geosciences ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 240
Author(s):  
Michael Riedel ◽  
Jörg Bialas ◽  
Heinrich Villinger ◽  
Thomas Pape ◽  
Matthias Haeckel ◽  
...  

Seafloor heat flow measurements are utilized to determine the geothermal regime of the Danube deep-sea fan in the western Black Sea and are presented in the larger context of regional gas hydrate occurrences. Heat flow data were collected across paleo-channels in water depths of 550–1460 m. Heat flow across levees ranges from 25 to 30 mW m−2 but is up to 65 mW m−2 on channel floors. Gravity coring reveals sediment layers typical of the western Black Sea, consisting of three late Pleistocene to Holocene units, notably red clay within the lowermost unit cored. Heat flow derived from the bottom-simulating reflector (BSR), assumed to represent the base of the gas hydrate stability zone (GHSZ), deviates from seafloor measurements. These discrepancies are linked either to fast sedimentation or slumping and associated variations in sediment physical properties. Topographic effects account of up to 50% of heat flow deviations from average values. Combined with climate-induced variations in seafloor temperature and sea-level since the last glacial maximum large uncertainties in the prediction of the base of the GHSZ remain. A regional representative heat flow value is ~30 mW m−2 for the study region but deviations from this value may be up to 100%.


2020 ◽  
Vol 81 (3) ◽  
pp. 184-186
Author(s):  
Atanas Vasilev ◽  
Nikola Botoucharov ◽  
Petar Petsinski ◽  
Rositsa Pehlivanova

The aim of this work is to reconstruct the variations of the total gas hydrate (GH) masses of the Danube deep-sea fan after 0.265 Ma BP. The PetroMod™ model developed in GEOMAR, Germany is for basin analysis of the Western Black Sea for 98 Ma. Geological structure is from 2D seismic of the Black Sea consortium “Geology without limits”. Results show a trend for total GH masses decrease after Middle Pleistocene and the role of the GHs as sink and source of methane.


2018 ◽  
Vol 92 ◽  
pp. 1056-1068 ◽  
Author(s):  
Timo Zander ◽  
Jung Chan Choi ◽  
Maarten Vanneste ◽  
Christian Berndt ◽  
Anke Dannowski ◽  
...  

2021 ◽  
Author(s):  
Hariharan Ramachandran ◽  
Andreia Plaza-Faverola ◽  
Hugh Daigle ◽  
Stefan Buenz

&lt;p&gt;Evidences of subsurface fluid flow-driven fractures (from seismic interpretation) are quite common at Vestnesa Ridge (around 79&amp;#186;N in the Arctic Ocean), W-Svalbard margin. Ultimately, the fractured systems have led to the formation of pockmarks on the seafloor. At present day, the eastern segment of the ridge has active pockmarks with continuous methane seep observations in sonar data. The pockmarks in the western segment are considered inactive or to seep at a rate that is harder to identify. The ridge is at ~1200m water depth with the base of the gas hydrate stability zone (GHSZ) at ~200m below the seafloor. Considerable free gas zone is present below the hydrates. Besides the obvious concern of amount and rates of historic methane seeping into the ocean biosphere and its associated effects, significant gaps exist in the ability to model the processes of flow of methane through this faulted and fractured region. Our aim is to highlight the interactions between physical flow, geomechanics and geological control processes that govern the rates and timing of methane seepage.&lt;/p&gt;&lt;p&gt;For this purpose, we performed numerical fluid flow simulations. We integrate fundamental mass and component conservation equations with a phase equilibrium approach accounting for hydrate phase boundary effects to simulate the transport of gas from the base of the GHSZ through rock matrix and interconnected fractures until the seafloor. The relation between effective stress and fluid pressure is considered and fractures are activated once the effective stress exceeds the tensile limit. We use field data (seismic, oedometer tests on calypso cores, pore fluid pressure and temperature) to constrain the range of validity of various flow and geomechanical parameters in the simulation (such as vertical stress, porosity, permeability, saturations).&lt;/p&gt;&lt;p&gt;Preliminary results indicate fluid overpressure greater than 1.5 MPa is required to initiate fractures at the base of the gas hydrate stability zone for the investigated system. Focused fluid flow occurs through the narrow fracture networks and the gas reaches the seafloor within 1 day. The surrounding regions near the fracture network exhibit slower seepage towards the seafloor, but over a wider area. Advective flux through the less fractured surrounding regions, reaches the seafloor within 15 years and a diffusive flux reaches within 1200 years. These times are controlled by the permeability of the sediments and are retarded further due to considerable hydrate/carbonate formation during vertical migration. Next course of action includes constraining the methane availability at the base of the GHSZ and estimating its impact on seepage behavior.&lt;/p&gt;


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