Supplemental Material: Magmatic evolution and architecture of an arc-related, rhyolitic caldera complex: The late Pleistocene to Holocene Cerro Blanco volcanic complex, southern Puna, Argentina

Methodology, calculations, and data analysis.

Supplemental Material: Magmatic evolution and architecture of an arc-related, rhyolitic caldera complex: The late Pleistocene to Holocene Cerro Blanco volcanic complex, southern Puna, Argentina

Methodology, calculations, and data analysis.

Gothic-Arch Calcite from Speleothems of the Bohemian Karst (Czech Republic): Its Occurrence, Microscopic Ultrastructure and Possible Mechanism of Growth

Gothic arch calcite, a specific crystallographic variety of calcite known from some hot springs and tufa streams, has been newly recognized in the Koněprusy Caves. The gothic-arch calcite occurs on the exteriors of exotic coralloid speleothems where it coexists with scalenohedral (dogtooth) spar crystals. The crystals exhibit microscopic ultrastructural features including deeply eroded topography, etch pits, and spiky and ribbon calcite crystallites, pointing to its extensive natural etching. Many gothic-arch calcites originated as late-stage, secondary overgrowths on older, etched dogtooth calcite crystals. Its characteristic outward curvature resulted from the recrystallization of etching-liberated fine carbonate grains and newly formed needle-fiber calcite laths, which were accumulated and bound on the faces and at the bases of corroded crystals. These intimately coexisting destructive and constructive processes of carbonate crystal corrosion and growth were probably mediated by bacteria, fungi, or other microorganisms. Fluid inclusions embedded in calcite crystals point to a vadose setting and temperatures below ~50 °C. This, combined with the wider geological context, indicates that the gothic arch calcite crystals originated only during the late Pleistocene to Holocene epochs, when the cave, initially eroded by hypogene fluids in the deeper subsurface, was uplifted to the subaerial setting and exposed to the meteoric waters seeping from the topographic surface. The radiocarbon analysis shows that gothic-arch calcite crystals are generally older than ~55,000 years, but the surface layers of some crystals still reveal a weak 14C activity, suggesting that microbiologically mediated alterations of the speleothems may have been occurring locally until now.

Heat Flow Measurements at the Danube Deep-Sea Fan, Western Black Sea

Seafloor heat flow measurements are utilized to determine the geothermal regime of the Danube deep-sea fan in the western Black Sea and are presented in the larger context of regional gas hydrate occurrences. Heat flow data were collected across paleo-channels in water depths of 550–1460 m. Heat flow across levees ranges from 25 to 30 mW m−2 but is up to 65 mW m−2 on channel floors. Gravity coring reveals sediment layers typical of the western Black Sea, consisting of three late Pleistocene to Holocene units, notably red clay within the lowermost unit cored. Heat flow derived from the bottom-simulating reflector (BSR), assumed to represent the base of the gas hydrate stability zone (GHSZ), deviates from seafloor measurements. These discrepancies are linked either to fast sedimentation or slumping and associated variations in sediment physical properties. Topographic effects account of up to 50% of heat flow deviations from average values. Combined with climate-induced variations in seafloor temperature and sea-level since the last glacial maximum large uncertainties in the prediction of the base of the GHSZ remain. A regional representative heat flow value is ~30 mW m−2 for the study region but deviations from this value may be up to 100%.

Ghost-dune hollows of the eastern Snake River Plain, Idaho: Their genesis, evolution, and relevance to Martian ghost-dune pits

Ghost-dune hollows on the eastern Snake River Plain (ESRP), Idaho, USA, are topographically inverted, crescent-shaped depressions that record the partial encasement of sand dunes by ca. 61 ka basalt lava flows. Deflation of these “ghost” sand dunes produced approximately two dozen, 5–10-m-deep ghost-dune hollows now incompletely filled with pedogenically altered eolian and colluvial sediment. Optically stimulated luminescence (OSL) and 40Ar/39Ar ages constrain a ghost-dune hollow model that illuminates the late Pleistocene to Holocene environmental and climate history of the ESRP. Detrital zircon analyses indicate sand-dune supply routes changed following the burial of Pleistocene Henrys Fork (tributary of the Snake River) alluvium by ca. 70 ka basalt flows. Removal of Henrys Fork alluvium from the eolian supply system made Lake Terreton sediment the primary source for later ESRP sand dunes. Such sediment supply changes highlight the potential impacts of effusive volcanism on sand-dune histories and landscapes. Our results support stratigraphic and sedimentary modeling of comparable ghost-dune “pit” deposits older than ca. 2 Ga on Mars that may have served as refugia for early life on that planet. Analogous ancient ghost-dune hollow deposits on Earth may also have served as early life refugia.

Mirror fault formation and coseismic slip at surface conditions: an example of faulting in unconsolidated deposits in the Central Apennines (Italy)

<p>Faulting in seismically active regions commonly involves the deformation of unconsolidated to poorly lithified sediments at shallow to near-surface depths. When compared to classic crustal strength profiles that predict a velocity-strengthening behaviour for the first few km of depth, the propagation of seismic rupture to the surface appears counterintuitive. Rock deformation experiments have shown an inverse relationship between normal stress and displacement needed to the onset of dynamic weakening during seismic slip, meaning that for a seismic rupture to be able to propagate towards the surface, displacements should be large enough to counter the progressive decrease of normal and confining stresses.</p><p>In this contribution, we document the occurrence of mirror-like faults that formed within 20-30 m-thick, unconsolidated colluvium fan deposits at the hanging wall of the active Vado di Corno Fault Zone (VCFZ) in the Central Apennines, Italy. The deposits lie in direct contact with the master normal-fault surface, are Late Pleistocene to Holocene in age, and consist of angular carbonate clasts with grain size ranging ~0.1-10 mm derived from the dismantling of the adjacent VCFZ footwall. Field observations of cross cutting relationships and marker layer displacements suggest a maximum formation depth of the faults of c. 20-30 m and slip accommodated along single faults on the order of few cm. Faults are organised in three sets: subvertical, N-S and NE-SW trending faults, and WNW-ESE striking faults, synthetic and antithetic to the VCFZ master fault surface (N195/55°). Faults are commonly lineated with a dip-slip to slightly oblique kinematic.</p><p>Detailed microstructural analysis of the mirror faults shows extreme strain localization on a 2-5 µm thick principal slip zone composed of calcite nanograins ranging 10s-100s nm in size with amorphous material and phyllosilicates occurring along grain boundaries and within intragranular porosity. Locally, aggregates of nanograins coalesce and transition to µm-sized polygonal, larger grains. Calcite nanograins are mostly equant, with straight grain boundaries, 120° dihedral angles, and negligible porosity. These microstructures strongly resemble high temperature recrystallization structures documented along seismic faults exhumed from >5 km of depth, where stresses are significantly larger. In our case, field constraints show that deformation occurred in very confining stress conditions and with limited displacement.</p><p>Collectively, our observations provide new documentation on the conditions for the formation of mirror faults and new insights into the mechanics of faulting and strain accommodation in the shallowest part of the crust (< 1 km).</p>