Potassium hydroxide activated carbon derived from albumen as an efficient sulfur host for room temperature sodium-sulfur batteries

2022 ◽  
Vol 45 ◽  
pp. 103666
Author(s):  
B.S. Reddy ◽  
N.S. Reddy ◽  
Sang-Yong Nam ◽  
Hyo-Jun Ahn ◽  
Jou-Hyeon Ahn ◽  
...  
Nano Letters ◽  
2021 ◽  
Author(s):  
Alex Yong Sheng Eng ◽  
Yong Wang ◽  
Dan-Thien Nguyen ◽  
Si Yin Tee ◽  
Carina Yi Jing Lim ◽  
...  

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Zichao Yan ◽  
Jin Xiao ◽  
Weihong Lai ◽  
Li Wang ◽  
Florian Gebert ◽  
...  

Abstract Polysulfide dissolution and slow electrochemical kinetics of conversion reactions lead to low utilization of sulfur cathodes that inhibits further development of room-temperature sodium-sulfur batteries. Here we report a multifunctional sulfur host, NiS2 nanocrystals implanted in nitrogen-doped porous carbon nanotubes, which is rationally designed to achieve high polysulfide immobilization and conversion. Attributable to the synergetic effect of physical confinement and chemical bonding, the high electronic conductivity of the matrix, closed porous structure, and polarized additives of the multifunctional sulfur host effectively immobilize polysulfides. Significantly, the electrocatalytic behaviors of the Lewis base matrix and the NiS2 component are clearly evidenced by operando synchrotron X-ray diffraction and density functional theory with strong adsorption of polysulfides and high conversion of soluble polysulfides into insoluble Na2S2/Na2S. Thus, the as-obtained sulfur cathodes exhibit excellent performance in room-temperature Na/S batteries.


2021 ◽  
pp. 160910
Author(s):  
B.S. Reddy ◽  
Gyu-Bong Cho ◽  
N.S. Reddy ◽  
Hyo-Jun Ahn ◽  
Jou-Hyeon Ahn ◽  
...  

2018 ◽  
Vol 10 (24) ◽  
pp. 20422-20428 ◽  
Author(s):  
Lei Zhang ◽  
Binwei Zhang ◽  
Yuhai Dou ◽  
Yunxiao Wang ◽  
Mohammad Al-Mamun ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1535
Author(s):  
Yanjie Wang ◽  
Yingjie Zhang ◽  
Hongyu Cheng ◽  
Zhicong Ni ◽  
Ying Wang ◽  
...  

Lithium metal batteries have achieved large-scale application, but still have limitations such as poor safety performance and high cost, and limited lithium resources limit the production of lithium batteries. The construction of these devices is also hampered by limited lithium supplies. Therefore, it is particularly important to find alternative metals for lithium replacement. Sodium has the properties of rich in content, low cost and ability to provide high voltage, which makes it an ideal substitute for lithium. Sulfur-based materials have attributes of high energy density, high theoretical specific capacity and are easily oxidized. They may be used as cathodes matched with sodium anodes to form a sodium-sulfur battery. Traditional sodium-sulfur batteries are used at a temperature of about 300 °C. In order to solve problems associated with flammability, explosiveness and energy loss caused by high-temperature use conditions, most research is now focused on the development of room temperature sodium-sulfur batteries. Regardless of safety performance or energy storage performance, room temperature sodium-sulfur batteries have great potential as next-generation secondary batteries. This article summarizes the working principle and existing problems for room temperature sodium-sulfur battery, and summarizes the methods necessary to solve key scientific problems to improve the comprehensive energy storage performance of sodium-sulfur battery from four aspects: cathode, anode, electrolyte and separator.


2020 ◽  
Vol 35 (6) ◽  
pp. 630-645
Author(s):  
Jia-ying Yang ◽  
Hao-jie Han ◽  
Hlib Repich ◽  
Ri-cheng Zhi ◽  
Chang-zhen Qu ◽  
...  

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