Effect of ionic liquid on dielectric, mechanical and dynamic mechanical properties of multi-walled carbon nanotubes/polychloroprene rubber composites

2011 ◽  
Vol 47 (12) ◽  
pp. 2234-2243 ◽  
Author(s):  
Kalaivani Subramaniam ◽  
Amit Das ◽  
Dagmar Steinhauser ◽  
Manfred Klüppel ◽  
Gert Heinrich
2019 ◽  
pp. 089270571988601 ◽  
Author(s):  
Sahil Kapoor ◽  
Meenakshi Goyal ◽  
Prashant Jindal

Nanocomposites of acrylonitrile butadiene styrene (ABS) with multi-walled carbon nanotubes (MWCNTs) have been fabricated using a facile solution blending technique with the variable weight of MWCNTs in ABS within a range of 1–5 wt% in the ABS/MWCNTs nanocomposites. Morphological characterization using field emission scanning electron microscope has shown uniform dispersion of MWCNTs in the nanocomposites. Thermal gravimetric analysis has shown improved thermal degradation stability for 5 wt% ABS/MWCNTs nanocomposites in comparison to pure ABS. Thermal expansion analysis of ABS/MWCNTs nanocomposites also showed a significant reduction in thermal strain and coefficient of thermal expansion (CTE) in comparison to pure ABS, with the 5 wt% sample showing a maximum reduction in thermal expansion properties. Mechanical characterization for 5 wt% ABS/MWCNTs nanocomposite, using nanoindentation, showed significant improvement in elastic modulus (90%) and hardness (99%) in comparison to pure ABS. The dynamic mechanical properties of 5 wt% ABS/MWCNTs nanocomposites also showed significant improvement with storage modulus and hardness improving by 153% and 342%, respectively, in comparison to pure ABS. These enhanced thermal and mechanical properties of ABS/MWCNTs nanocomposites enable their applications for a wider scope in various areas of engineering-based application, especially in the automobile industry.


2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Mahdi Najjar Disfani ◽  
Seyed-Hassan Jafari ◽  
Hossin Ali Khonakdar

Abstract Nanocomposites of phenoxy resin with various functionalized multi-walled carbon nanotubes (CNTs) were investigated to assess and compare the effect of functionalization on dynamic mechanical properties. Non-functionalized and various functionalized CNTs containing -COOH, -OH, and -NH2 groups were utilized for preparing phenoxy/CNT nanocomposites through a melt mixing process. Dynamic mechanical properties of nanocomposites, storage modulus (E′), and loss tangent (tanδ) data in temperature range of 20–120°C were collected. Transmission electron microscopy and optical microscopy were also used to gain an insight into the CNTs dispersion state within phenoxy matrix. The functionalized CNTs had no adverse effect on storage modulus of phenoxy. The morphological investigation revealed the highest degree of agglomeration and the shortest tube lengths for the CNT-COOH within phenoxy matrix.


2009 ◽  
Vol 87-88 ◽  
pp. 110-115 ◽  
Author(s):  
Ze Peng Wang

The basic and dynamic mechanical properties and thrermal conductivity of rubber composites filled with carbon nanotubes (CNTs) and various particle-sized carbon blacks (CB) were investigated. Results indicated that tear strength and modulus at a definite elongation of rubber composites filled with CNTs were enhanced compared to the conventional CB filler. However, tensile strength and elongation at break became lower. Thermal conductivity of rubber composites partly filled with CNTs is higher than those filled with CB. Rubber filled with the combination of CNTs and the bigger CB particles was beneficial to improve wet-resistant performance and roll resistance of elastomer such as tire.


2010 ◽  
Vol 150-151 ◽  
pp. 1413-1416 ◽  
Author(s):  
Hong Yan Chen ◽  
Zhen Xing Kong ◽  
Ji Hui Wang

The cure kinetics of Derakane 411-350, a kind of vinyl ester resin, and its suspensions containing multi-walled carbon nanotubes( MWCNTs) were investigated via non-isothermal dynamic scanning calorimetry (DSC) measurements. The results showed that incorporation of MWCNTs into vinyl ester resin excessively reduces polymerization degree and crosslinking density of vinyl ester resin. For suppressing the negative effect caused by nanotubes, the higher temperature initiator combined with the initiator MEKP was used. Dynamic-mechanical Behavior testing was then carried out on the cured sample in order to relate the curing behavior of MWCNTs modified resin suspensions to mechanical response of their resulting nanocomposites. It was revealed that nanocomposites containing MWCNTs possessed larger storage modulus values as well as higher glass transition temperatures (Tg) as compared to those without MWCNTs after using mixed intiators system to improve the degree of cure.


2021 ◽  
Vol 3 (6) ◽  
Author(s):  
Seyed Ali Mirsalehi ◽  
Amir Ali Youzbashi ◽  
Amjad Sazgar

AbstractIn this study, epoxy hybrid nanocomposites reinforced by carbon fibers (CFs) were fabricated by a filament winding. To improve out-of-plane (transverse) mechanical properties, 0.5 and 1.0 Wt.% multi-walled carbon nanotubes (MWCNTs) were embedded into epoxy/CF composites. The MWCNTs were well dispersed into the epoxy resin without using any additives. The transverse mechanical properties of epoxy/MWCNT/CF hybrid nanocomposites were evaluated by the tensile test in the vertical direction to the CFs (90º tensile) and flexural tests. The fracture surfaces of composites were studied by scanning electron microscopy (SEM). The SEM observations showed that the bridging of the MWCNTs is one of the mechanisms of transverse mechanical properties enhancement in the epoxy/MWCNT/CF composites. The results of the 90º tensile test proved that the tensile strength and elongation at break of nanocomposite with 1.0 Wt.% MWCNTs improved up to 53% and 50% in comparison with epoxy/CF laminate composite, respectively. Furthermore, the flexural strength, secant modulus, and elongation of epoxy/1.0 Wt.% MWCNT/CF hybrid nanocomposite increased 15%, 7%, and 9% compared to epoxy/CF laminate composite, respectively.


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