Heavy oil catalytic upgrading under methane environment: A small pilot plant evaluation

Fuel ◽  
2019 ◽  
Vol 258 ◽  
pp. 116161 ◽  
Author(s):  
Peng He ◽  
Shijun Meng ◽  
Yang Song ◽  
Bei Liu ◽  
Hua Song
2020 ◽  
Vol 60 (3) ◽  
pp. 384-391
Author(s):  
N. N. Sviridenko ◽  
A. V. Vosmerikov ◽  
M. R. Agliullin ◽  
B. I. Kutepov

Catalysts ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 497 ◽  
Author(s):  
Abarasi Hart ◽  
Mohamed Adam ◽  
John P. Robinson ◽  
Sean P. Rigby ◽  
Joseph Wood

This paper reports the hydrogenation and dehydrogenation of tetralin and naphthalene as model reactions that mimic polyaromatic compounds found in heavy oil. The focus is to explore complex heavy oil upgrading using NiMo/Al2O3 and CoMo/Al2O3 catalysts heated inductively with 3 mm steel balls. The application is to augment and create uniform temperature in the vicinity of the CAtalytic upgrading PRocess In-situ (CAPRI) combined with the Toe-to-Heel Air Injection (THAI) process. The effect of temperature in the range of 210–380 °C and flowrate of 1–3 mL/min were studied at catalyst/steel balls 70% (v/v), pressure 18 bar, and gas flowrate 200 mL/min (H2 or N2). The fixed bed kinetics data were described with a first-order rate equation and an assumed plug flow model. It was found that Ni metal showed higher hydrogenation/dehydrogenation functionality than Co. As the reaction temperature increased from 210 to 300 °C, naphthalene hydrogenation increased, while further temperature increases to 380 °C caused a decrease. The apparent activation energy achieved for naphthalene hydrogenation was 16.3 kJ/mol. The rate of naphthalene hydrogenation was faster than tetralin with the rate constant in the ratio of 1:2.5 (tetralin/naphthalene). It was demonstrated that an inductively heated mixed catalytic bed had a smaller temperature gradient between the catalyst and the surrounding fluid than the conventional heated one. This favored endothermic tetralin dehydrogenation rather than exothermic naphthalene hydrogenation. It was also found that tetralin dehydrogenation produced six times more coke and caused more catalyst pore plugging than naphthalene hydrogenation. Hence, hydrogen addition enhanced the desorption of products from the catalyst surface and reduced coke formation.


2019 ◽  
Vol 143 ◽  
pp. 104684
Author(s):  
Xiao-Dong Tang ◽  
Tian-Da Zhou ◽  
Jing-Jing Li ◽  
Chang-Lian Deng ◽  
Guang-Fu Qin

2017 ◽  
Vol 17 (6) ◽  
pp. 1793-1800
Author(s):  
Y. Yan ◽  
M. Carter ◽  
A. Mercer

Abstract Pilot plant testing is invaluable for ascertaining the robustness of water treatment processes against raw water quality events such as turbidity and colour spikes, whether it be for stress testing of an existing process or designing of a new process. Unfortunately, the natural occurrence of such events (particularly colour) can be difficult to predict and commercial humic materials generally fail to closely match the indigenous natural organic matter (NOM) present in the raw water. Therefore, it is highly desirable to be able to simulate NOM event conditions. This paper describes a simple brewing method that we developed and used in our recent pilot plant evaluation of a proposed DAF/Ozone/BAC process for drinking water treatment. Using this method we successfully prepared, by using fallen leaves etc. collected from the local catchment area, large quantities of a concentrated NOM stock solution with its specific ultraviolet absorbance (SUVA), when diluted, very close to the median SUVA of historical NOM events. The brewed solution showed broadly similar NOM characteristics to those of the raw water encountered during the pilot investigation period in terms of molecular weight distribution and fractionation. The coagulation behaviour was also examined for the spiked and non-spiked raw water.


1999 ◽  
Vol 38 (13) ◽  
Author(s):  
R.G. Moore ◽  
C.J. Laureshen ◽  
S.A. Mehta ◽  
M.G. Ursenbach ◽  
J.D.M. Belgrave ◽  
...  

Author(s):  
A. Veses ◽  
O. Sanahuja-Parejo ◽  
M.V. Navarro ◽  
J.M. López ◽  
R. Murillo ◽  
...  

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