Effects of nano-pore and macromolecule structure of coal samples on energy parameters variation during methane adsorption under different temperature and pressure

Fuel ◽  
2021 ◽  
Vol 289 ◽  
pp. 119804
Author(s):  
Junjian Zhang ◽  
Chongtao Wei ◽  
Chengjin Zhao ◽  
Tao Zhang ◽  
Guanwen Lu ◽  
...  
Fuel ◽  
2019 ◽  
Vol 254 ◽  
pp. 115686 ◽  
Author(s):  
Chuan-jie Zhu ◽  
Jie Ren ◽  
Jiamin Wan ◽  
Bai-quan Lin ◽  
Kai Yang ◽  
...  

2013 ◽  
Vol 27 (6) ◽  
pp. 3099-3109 ◽  
Author(s):  
Thomas F. T. Rexer ◽  
Michael J. Benham ◽  
Andrew C. Aplin ◽  
K. Mark Thomas

2020 ◽  
Vol 60 (2) ◽  
pp. 748
Author(s):  
Syed Shabbar Raza ◽  
Julie Pearce ◽  
Pradeep Shukla ◽  
Phil Hayes ◽  
Victor Rudolph

The Surat Basin in Queensland is one of the world’s premier producers of natural gas from coal seams. We investigate the potential for clay-rich Walloon Coal interburden and the overlying Springbok Sandstone to hold or produce gas. Seventeen core samples were analysed from two wells from intervals within the Walloon Upper Juandah Coal Measures interburden and the Springbok Sandstone. Samples were characterised using high-pressure methane adsorption isotherms, canister gas desorption tests, moisture contents, ash contents, carbon contents, scanning electron microscopy/energy dispersive X-ray spectrometry, X-ray quantitative clay analysis, permeability, helium pycnometry and mercury intrusion porosimetry. Methane adsorption was conducted at 30°C with up to 8 MPa pressure on dried crushed samples. The adsorption capacity of methane at 8 MPa varied from 3 cc/g (calcite-cemented) up to 25 cc/g (standard temperature and pressure equivalent) (coal). Clay-rich interburden samples adsorbed ~5–14 cc/g (dry). The measured isotherms and methane content from canister desorption tests show that appreciable volumes of gas are contained within some portions of interburden and in the overlying Springbok Sandstone. Gas within the interburden likely represents a large volumetric resource, albeit in low permeability rock that restricts direct productivity. The gas adsorption and gas content results for the Springbok Sandstone help to explain field observations of high gas content in some landholder water wells.


Author(s):  
Ronald S. Weinstein ◽  
N. Scott McNutt

The Type I simple cold block device was described by Bullivant and Ames in 1966 and represented the product of the first successful effort to simplify the equipment required to do sophisticated freeze-cleave techniques. Bullivant, Weinstein and Someda described the Type II device which is a modification of the Type I device and was developed as a collaborative effort at the Massachusetts General Hospital and the University of Auckland, New Zealand. The modifications reduced specimen contamination and provided controlled specimen warming for heat-etching of fracture faces. We have now tested the Mass. General Hospital version of the Type II device (called the “Type II-MGH device”) on a wide variety of biological specimens and have established temperature and pressure curves for routine heat-etching with the device.


Author(s):  
G.D. Danilatos

Over recent years a new type of electron microscope - the environmental scanning electron microscope (ESEM) - has been developed for the examination of specimen surfaces in the presence of gases. A detailed series of reports on the system has appeared elsewhere. A review summary of the current state and potential of the system is presented here.The gas composition, temperature and pressure can be varied in the specimen chamber of the ESEM. With air, the pressure can be up to one atmosphere (about 1000 mbar). Environments with fully saturated water vapor only at room temperature (20-30 mbar) can be easily maintained whilst liquid water or other solutions, together with uncoated specimens, can be imaged routinely during various applications.


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