Laccase-mediated system pretreatment to enhance the effect of hydrogen peroxide bleaching of cotton fabric

2012 ◽  
Vol 50 (3) ◽  
pp. 782-787 ◽  
Author(s):  
Liqiang Tian ◽  
C. Branford-White ◽  
Wen Wang ◽  
Huali Nie ◽  
Limin Zhu
Keyword(s):  
Hydrogen Peroxide ◽  
Cotton Fabric ◽  
Peroxide Bleaching

Hydrogen Peroxide Bleaching of Cationized Cotton Fabric

2019 ◽  
Vol 6 (5) ◽  
pp. 21-29
Author(s):  
Sha Fu ◽  
Matthew J. Farrell ◽  
Mary A. Ankeny ◽  
Edwin T. Turner ◽  
Victoria Rizk
Keyword(s):  
Hydrogen Peroxide ◽  
Statistical Model ◽  
Magnesium Sulfate ◽  
Cotton Fabric ◽  
Significant Loss ◽  
Bleaching Agent ◽  
Color Strength ◽  
Whiteness Index ◽  
Peroxide Bleaching ◽  
Screening Experiment

Hydrogen peroxide (H2O2) is the most commonly used bleaching agent for cotton fabric. However, the conventional H2O2 bleaching formula is not applicable for cationized cotton due to the low whiteness index after bleaching, fabric weakening, and a significant loss of cationic sites. In this work, magnesium sulfate (MgSO4) was added in the H2O2 bleaching formula to stabilize the bleaching system for cationized cotton. Additionally, a screening experiment with temperature and time, and sodium hydroxide (NaOH), H2O2, and MgSO4 concentrations as the factors, and whiteness index, bursting strength, and color strength from dyeing as the responses, was formulated. A statistical model was created using JMP software, which demonstrated how the bleaching conditions influenced the fabric properties. This procedure can be useful for bleaching cationized cotton in production settings.

scholarly journals A new method: the usage of natural zeolite as a killer chemical for hydrogen peroxide during the hydrogen peroxide bleaching

2019 ◽  
Vol 70 (06) ◽  
pp. 519-522
Author(s):  
CANDAN CANDAN
Keyword(s):  
Hydrogen Peroxide ◽  
Particle Size ◽  
Quantitative Analysis ◽  
Cotton Fabric ◽  
Elemental Analysis ◽  
Natural Zeolite ◽  
The Other ◽  
New Method ◽  
Peroxide Bleaching ◽  
Icp Ms

In the study, the usage possibility of natural zeolite as hydrogen peroxide killer during the hydrogen peroxide bleaching was investigated. Natural zeolite from Gördes region with 30 µm particle size was used during the hydrogen peroxide bleaching of the cotton fabric as a hydrogen peroxide killer agent. ICP-MS elemental analysis of the natural zeolite was performed. Hydrogen peroxide concentration of the bleaching liquor was performed by quantitative analysis. It was seen that natural zeolite is so efficient to decrease in hydrogen peroxide concentration in the bleaching bath. It is thought that natural zeolite can be an alternative to antiperoxide enzymes and the other hydrogen peroxide killers which are commonly used in the industry.

The role of copper ions in hydrogen peroxide bleaching: Their origin, removal, and effect on pulp quality

TAPPI Journal ◽  
2012 ◽  
Vol 11 (7) ◽  
pp. 37-46 ◽  
Author(s):  
PEDRO E.G. LOUREIRO ◽  
SANDRINE DUARTE ◽  
DMITRY V. EVTUGUIN ◽  
M. GRAÇA V.S. CARVALHO
Keyword(s):  
Hydrogen Peroxide ◽  
Copper Ions ◽  
Peroxide Bleaching ◽  
Metals Removal ◽  
Peroxide Decomposition ◽  
Equipment Corrosion ◽  
And Performance ◽  
And Control ◽  
Main Effects

This study puts particular emphasis on the role of copper ions in the performance of hydrogen peroxide bleaching (P-stage). Owing to their variable levels across the bleaching line due to washing filtrates, bleaching reagents, and equipment corrosion, these ions can play a major role in hydrogen peroxide decomposition and be detrimental to polysaccharide integrity. In this study, a Cu-contaminated D0(EOP)D1 prebleached pulp was subjected to an acidic washing (A-stage) or chelation (Q-stage) before the alkaline P-stage. The objective was to understand the isolated and combined role of copper ions in peroxide bleaching performance. By applying an experimental design, it was possible to identify the main effects of the pretreatment variables on the extent of metals removal and performance of the P-stage. The acid treatment was unsuccessful in terms of complete copper removal, magnesium preservation, and control of hydrogen peroxide consumption in the following P-stage. Increasing reaction temperature and time of the acidic A-stage improved the brightness stability of the D0(EOP)D1AP bleached pulp. The optimum conditions for chelation pretreatment to maximize the brightness gains obtained in the subsequent P-stage with the lowest peroxide consumption were 0.4% diethylenetriaminepentaacetic acid (DTPA), 80ºC, and 4.5 pH.

The Effect of Microwave Treatment on the Hydrogen Peroxide Bleaching of Soda-AQ Wheat Straw Pulp

2011 ◽  
Vol 236-238 ◽  
pp. 1307-1312
Author(s):  
Chao Jun Wu ◽  
Chuan Shan Zhao ◽  
Jun Li ◽  
Ke FU Chen
Keyword(s):  
Hydrogen Peroxide ◽  
Wheat Straw ◽  
Fiber Length ◽  
Weighted Average ◽  
Microwave Treatment ◽  
Arithmetic Average ◽  
Peroxide Bleaching ◽  
Bleached Pulp ◽  
Infra Red ◽  
Wheat Straw Pulp

In this paper, the effect of microwave treatment on the hydrogen peroxide bleaching of Soda-AQ wheat-straw pulp was investigated. The results showed that microwave treatment could increase the brightness of the hydrogen peroxide bleached pulp. The fiber coarseness of microwave enhancing peroxide bleached pulp was higher than that of the peroxide bleached pulp. However, the arithmetic average fiber length, the length weighted average fiber length and weight weighted average fiber length of the former was lower than that of the latter. Fourier transform infra-red spectroscopy (FTIR) and X-ray diffraction (XRD) spectra showed that CrI(%) crystallinity of microwave enhancing peroxide bleached pulp was similar as that of the peroxide bleached pulp but all higher than that of the Soda-AQ wheat-straw pulp. N·O′KI infra-red crystalline index of microwave enhancing peroxide bleached pulp were lower than that of the peroxide bleached pulp. The FTIR spectra of lignin showed that the microwave treatment had some influences on the methoxyl and phenolic group in lignin.

Influence of Hydrogen Peroxide Bleaching Gels on Color, Opacity, and Fluorescence of Composite Resins

2012 ◽  
Vol 37 (5) ◽  
pp. 526-531 ◽  
Author(s):  
CRG Torres ◽  
CF Ribeiro ◽  
E Bresciani ◽  
AB Borges
Keyword(s):  
Hydrogen Peroxide ◽  
Composite Resin ◽  
Color Change ◽  
Composite Resins ◽  
Control Group ◽  
Peroxide Bleaching ◽  
Color Changes ◽  
Tukey Test ◽  
Bleaching Gels ◽  
Bleaching Treatment

SUMMARY The aim of the present study was to evaluate the effect of 20% and 35% hydrogen peroxide bleaching gels on the color, opacity, and fluorescence of composite resins. Seven composite resin brands were tested and 30 specimens, 3-mm in diameter and 2-mm thick, of each material were fabricated, for a total of 210 specimens. The specimens of each tested material were divided into three subgroups (n=10) according to the bleaching therapy tested: 20% hydrogen peroxide gel, 35% hydroxide peroxide gel, and the control group. The baseline color, opacity, and fluorescence were assessed by spectrophotometry. Four 30-minute bleaching gel applications, two hours in total, were performed. The control group did not receive bleaching treatment and was stored in deionized water. Final assessments were performed, and data were analyzed by two-way analysis of variance and Tukey tests (p<0.05). Color changes were significant for different tested bleaching therapies (p<0.0001), with the greatest color change observed for 35% hydrogen peroxide gel. No difference in opacity was detected for all analyzed parameters. Fluorescence changes were influenced by composite resin brand (p<0.0001) and bleaching therapy (p=0.0016) used. No significant differences in fluorescence between different bleaching gel concentrations were detected by Tukey test. The greatest fluorescence alteration was detected on the brand Z350. It was concluded that 35% hydrogen peroxide bleaching gel generated the greatest color change among all evaluated materials. No statistical opacity changes were detected for all tested variables, and significant fluorescence changes were dependent on the material and bleaching therapy, regardless of the gel concentration.

scholarly journals Influence of the fluorescent brightener Periblanc BA on the degree of whiteness of the knitted cotton fabric

2011 ◽  
Vol 65 (1) ◽  
pp. 61-66 ◽  
Author(s):  
Milena Miljkovic ◽  
Milovan Purenovic ◽  
Mile Novakovic ◽  
Sonja Randjelovic
Keyword(s):  
Hydrogen Peroxide ◽  
Cotton Fabric ◽  
Whiteness Index ◽  
Fluorescent Brightener ◽  
Single Bath ◽  
Optical Bleaching ◽  
The One ◽  
Experimental Runs ◽  
Exhaustion Method

In this study the influence of the different fluorescent brightener Periblanc BA concentrations on the degree of knitted cotton fabric whiteness was investigated. Two consecutive experimental runs were performed. The first was the bleaching of the knitted cotton fabric with hydrogen peroxide using the methods of two and single bath exhaustion while the second was the optical bleaching with fluorescent brightener Periblanc BA using the exhaustion method. CIE Whiteness Index and Tint value were measured on the Color-Eye 3000 spectrophotometer at the standard illuminant D65 (Ice-Texicon, d/8, D65/10?) while K/S values were determined using the Kubelka Munk equation. The results show that cotton fabric bleached with fluorescent brightener Periblanc BA after bleaching with hydrogen peroxide using two bath exhaustion method has higher degree of whiteness (118.8) with a reddish tint in comparison to the one bleached with hydrogen peroxide using single bath method (106.1).

Hydrogen peroxide bleaching of Arundo donax L. kraft-anthraquinone pulp—Effect of a chelating stage

2007 ◽  
Vol 25 (3) ◽  
pp. 288-293 ◽  
Author(s):  
Sandra Abrantes ◽  
Emília Amaral ◽  
Ana Paula Costa ◽  
Anatoly A. Shatalov ◽  
Ana Paula Duarte
Keyword(s):  
Hydrogen Peroxide ◽  
Arundo Donax ◽  
Peroxide Bleaching ◽  
Arundo Donax L

Hydrogen Peroxide Bleaching of Amaranth Catalysed by Nickel(II) Nitrilotriacetic Acid

1999 ◽  
Vol 23 (5) ◽  
pp. 340-341
Author(s):  
Paul M. Paradis
Keyword(s):  
Hydrogen Peroxide ◽  
Nitrilotriacetic Acid ◽  
Peroxide Bleaching

The complex of NiII with nitrilotriacetic acid (NTA) (but not other aminocarboxylate complexes) autocatalyses the hydrogen peroxide bleaching of amaranth, although the reaction is inhibited by the absence of light or presence of alcohol, suggesting a radical-based mechanism.

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