Hydrogen isotopes separation using frontal displacement chromatography: The influences of column temperature and gas flow rate

2019 ◽  
Vol 44 (31) ◽  
pp. 16675-16683 ◽  
Author(s):  
Xiaojun Deng ◽  
Deli Luo ◽  
Cheng Qin ◽  
Daqiao Meng ◽  
Tao Tang ◽  
...  
Keyword(s):  
Flow Rate ◽  
Gas Flow ◽  
Hydrogen Isotopes ◽  
Gas Flow Rate ◽  
Displacement Chromatography ◽  
Column Temperature ◽  
Isotopes Separation ◽  
Frontal Displacement

Application of Response Surface Methodology to Investigate CO2 Absorption Column Temperature Rise

2014 ◽  
Vol 917 ◽  
pp. 257-266 ◽  
Author(s):  
Lian See Tan ◽  
Mohd Shariff Azmi ◽  
Lau Kok Keong ◽  
Mohammad Azmi Bustam
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Flow Rate ◽  
Temperature Rise ◽  
Gas Flow ◽  
Liquid Temperature ◽  
Inlet Concentration ◽  
Gas Flow Rate ◽  
Column Temperature ◽  
Column Pressure

This study aims to investigate the impact of process parameters to the column temperature rise during the absorption process using response surface methodology (RSM). The parameters studied were liquid temperature, column pressure, CO2 inlet concentration and gas flow rate. While all the factors studied had significant impact to the quadratic model for the temperature rise, the magnitude of temperature rise was more obvious with the variation of column pressure and CO2 inlet concentration. The column temperature rise was found to be high when the liquid temperature, column pressure and CO2 inlet concentration were high. Similar behavior of high column temperature rise was also observed when the gas flow rate was low.

scholarly journals EFFECT OF CARRIER GAS FLOW RATE AND COLUMN TEMPERATURE ON THE SUITABILITY PARAMETERS OF GC-ECD FOR SF6 MEASUREMENT

2017 ◽  
Vol 14 (28) ◽  
pp. 120-129
Author(s):  
Oman ZUAS
Keyword(s):  
Flow Rate ◽  
Gas Flow ◽  
Theoretical Plate ◽  
Gas Flow Rate ◽  
Column Temperature ◽  
Carrier Gas ◽  
System Suitability ◽  
Carrier Gas Flow ◽  
Asymmetric Factor ◽  
Good Agreement

System suitability testing of a GC is essential to verify its suitability for intended application. The GC always uses a carrier gas and column temperature, which may impact on its suitability parameters. This study is aimed to evaluate the effects of carrier gas flow rate (FLRT) and column temperature (CLTP) on the system suitability parameters (SSP) of GC-ECD for SF6 measurement such as retention time/tR, response factor/RF, theoretical plate numbers/N, and asymmetric factor/As. The evaluation was conducted by carefully profiling the SF6 chromatogram and the data obtained were used to calculate the tR, RF, N, and As values. It was found that the tR increases linearly (R2 = 0.9978) by increasing the FLRT, but decreases linearly (R2 = 0.9991) by increasing the CLTP. The RF decreases linearly (R2 = 0.9939) by increasing the FLRT. Interestingly, the RF was affected by the CLTP with 2nd polynomial order trend (R2 = 0.9949). The N increases linearly (R2 = 0.9404) by increasing the FLRT but the N was affected b the CLTP with 2nd polynomial order trend (R2 = 0.9769). The As was found to increase slightly with FLRT (R2 = 0.1288), while the As was affected by the CT with 2nd polynomial order trend (R2 = 0.9778). These results are in a good agreement with previous SSP studies.

Establishment of Gas Chromatography Analytical Method for 4-Amino-2-Methylpentane

2017 ◽  
Vol 865 ◽  
pp. 624-629
Author(s):  
Shu Chun Zhao ◽  
Yan Yan Yan ◽  
Yue Zhang ◽  
Xin Rui Dong ◽  
Hua Zhao ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Flow Rate ◽  
Gas Flow ◽  
Gas Flow Rate ◽  
Pure Nitrogen ◽  
Column Temperature ◽  
Carrier Gas ◽  
Flame Ionization ◽  
Split Ratio ◽  
Accuracy And Precision

The aim of this paper was to establish a gas chromatography (GC) method for the determination of 4-amino-2-methylpentane and validate the methodology. The gas chromatography conditions such as column temperature, carrier gas flow rate, split ratio and the make-up gas flow rate were investigated in detail. The chromatographic column used in this method was capillary column of DA-1. The oven temperature was initially held at 40 °C for 15 min and was then programmed temperature to 140 °C at the rate of 75 °C/min and held for 10 min. The injection temperature was 180 °C and the flame ionization detector temperature was 200 °C. The carrier gas was high pure nitrogen with a flow rate of 0.8 mL/min. The split ratio was 130:1 and the make-up gas flow rate was 30 mL/min. Good linearity of 4-amino-2-methylpentane was obtained within the concentration range of 25.44 mg/mL to 84.81 mg/mL and the correlation coefficient was 0.9990. Good accuracy and precision were obtained and the average recovery was 101.76%. The quantification limit of 4-amino-2-methylpentane was 7.21 μg/mL and the detection limit of that was 3.72 μg/mL. The method was well-validated and proved to be used for quality test of 4-amino-2-methylpentane.

SCIENTIFIC AND ENGINEERING PRINCIPLES OF EFFICIENT FUEL USE AND ENVIRONMENTALLY FRIENDLY GAS COMBUSTION IN STOVE PLATES. PART 1. MODERN STATE-OF-THE-ART AND DIRECTIONS FOR IMPROVEMENT THE GAS BURNING IN DOMESTIC GAS COOKERS

2017 ◽  
pp. 3-18 ◽  
Author(s):  
B.S. Soroka ◽  
V.V. Horupa
Keyword(s):  
Natural Gas ◽  
Flow Rate ◽  
Gas Flow ◽  
Renewable Energy Sources ◽  
Combustion Process ◽  
Orifice Diameter ◽  
Firing Process ◽  
Gas Flow Rate ◽  
Gas Combustion ◽  
Gas Stoves

Natural gas NG consumption in industry and energy of Ukraine, in recent years falls down as a result of the crisis in the country’s economy, to a certain extent due to the introduction of renewable energy sources along with alternative technologies, while in the utility sector the consumption of fuel gas flow rate enhancing because of an increase the number of consumers. The natural gas is mostly using by domestic purpose for heating of premises and for cooking. These items of the gas utilization in Ukraine are already exceeding the NG consumption in industry. Cooking is proceeding directly in the living quarters, those usually do not meet the requirements of the Ukrainian norms DBN for the ventilation procedures. NG use in household gas stoves is of great importance from the standpoint of controlling the emissions of harmful components of combustion products along with maintenance the satisfactory energy efficiency characteristics of NG using. The main environment pollutants when burning the natural gas in gas stoves are including the nitrogen oxides NOx (to a greater extent — highly toxic NO2 component), carbon oxide CO, formaldehyde CH2O as well as hydrocarbons (unburned UHC and polyaromatic PAH). An overview of environmental documents to control CO and NOx emissions in comparison with the proper norms by USA, EU, Russian Federation, Australia and China, has been completed. The modern designs of the burners for gas stoves are considered along with defining the main characteristics: heat power, the natural gas flow rate, diameter of gas orifice, diameter and spacing the firing openings and other parameters. The modern physical and chemical principles of gas combustion by means of atmospheric ejection burners of gas cookers have been analyzed from the standpoints of combustion process stabilization and of ensuring the stability of flares. Among the factors of the firing process destabilization within the framework of analysis above mentioned, the following forms of unstable combustion/flame unstabilities have been considered: flashback, blow out or flame lifting, and the appearance of flame yellow tips. Bibl. 37, Fig. 11, Tab. 7.

On the Influence of Fluctuating Flow Rate Upon the Performance and Behaviour of Isothermal Reacting Systems

1998 ◽  
Vol 63 (6) ◽  
pp. 881-898
Author(s):  
Otakar Trnka ◽  
Miloslav Hartman
Keyword(s):  
Flow Rate ◽  
Gas Flow ◽  
Fluidized Bed Reactor ◽  
Computational Techniques ◽  
Continuous Stirred Tank Reactor ◽  
Gas Flow Rate ◽  
Solid Reaction ◽  
Continuous Stirred Tank ◽  
And Performance ◽  
Reacting Systems

Three simple computational techniques are proposed and employed to demonstrate the effect of fluctuating flow rate of feed on the behaviour and performance of an isothermal, continuous stirred tank reactor (CSTR). A fluidized bed reactor (FBR), in which a non-catalytic gas-solid reaction occurs, is also considered. The influence of amplitude and frequency of gas flow rate fluctuations on reactant concentrations at the exit of the CSTR is shown in four different situations.

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