Rate equation theory for the hydrogenation kinetics of Mg-based materials

2021 ◽  
Author(s):  
Jinzhi Cai ◽  
Lei Liu ◽  
Zhenshan Li
Keyword(s):  
Rate Equation ◽  
Hydrogenation Kinetics ◽  
Kinetics Of

Kinetics of catalytic reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst

1983 ◽  
Vol 48 (11) ◽  
pp. 3202-3208 ◽  
Author(s):  
Zdeněk Musil ◽  
Vladimír Pour
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Oxide ◽  
Rate Equation ◽  
Catalytic Reduction ◽  
Zero Order ◽  
Spectroscopic Measurements ◽  
First Order ◽  
Ir Spectroscopic ◽  
Kinetics Of ◽  
Al2o3 Catalyst

The kinetics of the reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst (8.36 mass % CuO) were determined at temperatures between 413 and 473 K. The reaction was found to be first order in NO and zero order in CO. The observed kinetics are consistent with a rate equation derived from a mechanism proposed on the basis of IR spectroscopic measurements.

The kinetics of the decarboxylation of β-resorcylic acid in catechol

1976 ◽  
Vol 29 (2) ◽  
pp. 443 ◽  
Author(s):  
MA Haleem ◽  
MA Hakeem
Keyword(s):  
Rate Equation ◽  
Kinetic Data ◽  
Reaction Rate ◽  
Complex Mechanism ◽  
First Order ◽  
Absolute Reaction Rate ◽  
First Time ◽  
Kinetics Of ◽  
Absolute Reaction ◽  
Reaction Rate Equation

Kinetic data are reported for the decarboxylation of β-resorcylic acid in resorcinol and catechol for the first time. The reaction is first order. The observation supports the view that the decomposition proceeds through an intermediate complex mechanism. The parameters of the absolute reaction rate equation are calculated.

Hydrogenation kinetics of toluene on Pt/ZSM-22

2002 ◽  
Vol 90 (1-2) ◽  
pp. 117-129 ◽  
Author(s):  
Joris W. Thybaut ◽  
Mark Saeys ◽  
Guy B. Marin
Keyword(s):  
Hydrogenation Kinetics ◽  
Kinetics Of

Studies on metal hydroxy compounds. X. Thermal analyses, decomposition kinetics, and infrared spectra of lead halide (Cl, Br, I) derivatives

1970 ◽  
Vol 48 (16) ◽  
pp. 2617-2622 ◽  
Author(s):  
P. Ramamurthy ◽  
E. A. Secco ◽  
M. Badri
Keyword(s):  
Infrared Spectra ◽  
Rate Equation ◽  
Thermal Analyses ◽  
Decomposition Reaction ◽  
Diffusion Type ◽  
Type Rate ◽  
Hydroxy Compounds ◽  
Kinetics Of ◽  
Lead Halide ◽  
Order Rate Equation

The thermal analyses, thermogravimetry (TG), and differential thermal analysis (DTA) of PbOHCl, PbOHBr, and PbOHI reveal that the initial mode of decomposition is via dehydroxylation. Calorimetric measurements along with related enthalpy values for the decomposition reaction are given.The infrared spectra of these compounds are interpreted in terms of folded bands of (PbOH+)n tied together by halide ions consistent with their crystal structures.The kinetics of thermal decomposition of lead hydroxyhalides follow a diffusion-type rate equation which is in contrast to the simple first-order rate equation observed for most Cd, Zn, and Cu compounds. These two distinct rates are interpreted in terms of mobile OH or H species in the dehydroxylation step.

THE REDUCTION OF CYTOCHROMEcBY HYDROQUINONE

1963 ◽  
Vol 41 (1) ◽  
pp. 231-237 ◽  
Author(s):  
G. R. Williams
Keyword(s):  
Reaction Mechanism ◽  
Ionic Strength ◽  
Rate Equation ◽  
Second Order ◽  
Order Rate ◽  
Ferricytochrome C ◽  
Kinetics Of ◽  
Kinetics Of Reduction ◽  
Order Rate Equation

The kinetics of reduction of ferricytochrome c by hydroquinone have been studied. The reaction does not conform to a simple second-order rate equation and it is demonstrated that the deviations are brought about by the presence of p-quinone, one of the products of the reaction. The accelerating effect of p-quinone is explained tentatively on the basis of an involvement of the semi-quinone. The effects on the reaction of pH, ionic strength, and temperature are reported and used to suggest features of the reaction mechanism.

Enhanced dehydrogenation/hydrogenation kinetics of the Mg(NH2)2–2LiH system with NaOH additive

2011 ◽  
Vol 36 (3) ◽  
pp. 2137-2144 ◽  
Author(s):  
Chu Liang ◽  
Yongfeng Liu ◽  
Zhijun Wei ◽  
Ying Jiang ◽  
Fan Wu ◽  
...  
Keyword(s):  
Hydrogenation Kinetics ◽  
Kinetics Of

Kinetics of ο-Chloronitrobenzene Hydrogenation on Palladium/Carbon Catalyst

2011 ◽  
Vol 239-242 ◽  
pp. 161-167
Author(s):  
Xiao Zhen Wang ◽  
Yi Feng Zhu ◽  
Xiao Nian Li
Keyword(s):  
High Selectivity ◽  
Total Yield ◽  
Hydrogenation Reaction ◽  
Commercial Application ◽  
Reaction Conditions ◽  
Solvent Free Conditions ◽  
Hydrogenation Kinetics ◽  
Favorable Reaction ◽  
Kinetics Of ◽  
Very High

A 2 wt % Pd/C catalyst has been prepared by chemical impregnation and used to catalyze the hydrogenation of o-chloronitrobenzene (o-CNB) to o-chloroaniline (o-CAN) in solvent-free conditions. The effects of reaction temperature, H2 pressure, and stirring intensity on the hydrogenation kinetics have been investigated. The hydrogenation reaction showed very high selectivity with dehalogenation side products as low as 0.3% of total yield. The favorable reaction conditions were found to be temperature T = 383 K, stirring speed = 900 rpm, and feeding ratio CNB/catalyst = 200/1 (m/m). The recycled Pd/C still retained more than 98% of its original selectivity after 12 repeat used, indicating the catalyst had strong potentials for commercial application at industrial scale.

Hydrogenation Kinetics of N -Ethylindole on a Supported Ru Catalyst

2018 ◽  
Vol 6 (3) ◽  
pp. 558-562 ◽  
Author(s):  
Yuan Dong ◽  
Ming Yang ◽  
Ting Zhu ◽  
Xuedi Chen ◽  
Chenguang Li ◽  
...  
Keyword(s):  
Ru Catalyst ◽  
Hydrogenation Kinetics ◽  
Kinetics Of
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