absolute reaction
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2020 ◽  
Vol 861 ◽  
pp. 107-112
Author(s):  
Vladimir S. Tsepelev ◽  
Yuri N. Starodubtsev ◽  
Kai Ming Wu ◽  
Yekaterina A. Kochetkova

The size of the nanoparticles participating in the viscous flow and the diffusion coefficient were calculated using statistical mechanical theory of absolute reaction rates and the Arrhenius equation. As experimental data, temperature dependence of the kinematic viscosity and density of Fe73.5Cu1Mo3Si13.5B9 melt was used. At a temperature of 1600 K, after the melt is overheated above the critical temperature Tk = 1770 K, the nanoparticles size decreases from 0.92 to 0.47 nm, and the diffusion coefficient increases from 2.4·10-10 to 4.5·10-10 m2·s-1.



2017 ◽  
Vol 2017 ◽  
pp. 1-13
Author(s):  
Huayan Chen ◽  
Xiangguo Zeng ◽  
Yang Guo ◽  
Fang Wang

In this work, the viscoplasticity and creep behavior for modified 9Cr-1Mo and 316 stainless steels were investigated. Based on the absolute reaction rate theory, a unified constitutive model incorporating internal state variables was proposed to characterize the evolution of the back stress. Also, the model was implemented by the ABAQUS system with the semi-implicit stress integration. Compared to the experimental data, the results demonstrated that the proposed approach could effectively simulate the cyclic softening and hardening behavior for such structural steels.





2008 ◽  
Vol 385-387 ◽  
pp. 853-856
Author(s):  
Xiang Guo Zeng ◽  
Hua Yan Chen ◽  
Zhan Hua Gao

Founded on the energy storing characteristics of microstructure during irreversible deformation, a viscoplastic constitutive model with no yielding surface introduced was developed for single crystals by adopting a spring-dashpot mechanical system. Both plastic dashpots reflecting the material time-independent responses and Newtonian dashpots mirroring the material time-dependent viscous responses were introduced to describe the viscoplasticity of slip systems. The single crystal constitutive model was established based on the thermodynamics of internal variables and the theory of absolute reaction rate. By implementing the KBW self-consistent theory, a polycrystal viscoplastic constitutive model was formed. The numerical analysis in corresponding algorithm was significantly simplified as no searching process for the activation of the slip systems and slip directions was required. The numerical simulation of creep-plasticity behaviors demonstrated excellent agreement with the corresponding experimental data.



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