Enhanced hydrogen production through alkaline electrolysis using laser-nanostructured nickel electrodes

Author(s):  
Ioannis A. Poimenidis ◽  
Michael D. Tsanakas ◽  
Nikandra Papakosta ◽  
Argyro Klini ◽  
Maria Farsari ◽  
...  
2020 ◽  
Vol 1012 ◽  
pp. 158-163
Author(s):  
Oliveira Marilei de Fátima ◽  
Mazur Viviane Teleginski ◽  
Virtuozo Fernanda ◽  
Junior Valter Anzolin de Souza

Nowadays, humanity has become aware of the consequences that the use of fossil fuels entails, and the latest developments in the energy sector are leading to a diversification of energy resources. In this context, researching on alternative forms of producing electric energy is being conducted. At the transportation level, a possible solution for this matter may lie in hydrogen fuel cells. The electrolysis of water is one of the possible processes for hydrogen production, but the reaction to break the water molecule requires a great amount of energy and this is precisely the biggest issue involving this process. In this work, low cost electrodes of 254 stainless steel and electrolytic graphite were used for hydrogen production, allowing high efficiency and reduced oxidation during the process. The selection of these materials allows to obtain a high corrosion resistance electrolytic pair, by replacing the high cost platinum electrode usually employed in the alkaline electrolysis process. The formic acid of biomass origin was used as an electrolyte. It was observed that the developed reactor have no energy losses through heat and it was possible to obtain approximately 82% conversion efficiency in the gas production process.


2017 ◽  
Vol 42 (17) ◽  
pp. 12094-12103 ◽  
Author(s):  
K.C. Sandeep ◽  
Sachin Kamath ◽  
Krunal Mistry ◽  
Ashok Kumar M ◽  
S.K. Bhattacharya ◽  
...  

Fuel ◽  
2020 ◽  
Vol 276 ◽  
pp. 117910
Author(s):  
J. Barco-Burgos ◽  
U. Eicker ◽  
N. Saldaña-Robles ◽  
A.L. Saldaña-Robles ◽  
V. Alcántar-Camarena

2020 ◽  
Vol 45 (7) ◽  
pp. 3916-3929 ◽  
Author(s):  
Mónica Sánchez ◽  
Ernesto Amores ◽  
David Abad ◽  
Lourdes Rodríguez ◽  
Carmen Clemente-Jul

2012 ◽  
pp. 141-148
Author(s):  
Valentin Pérez-Herranz ◽  
Isaac Herrãiz-Cardona ◽  
Emma Ortega ◽  
José Garcia-Anton

Hydrogen ◽  
2020 ◽  
Vol 2 (1) ◽  
pp. 1-17
Author(s):  
William J. F. Gannon ◽  
Charles W. Dunnill

Low-cost, high-performance coatings for hydrogen production via electrolytic water-splitting are of great importance for de-carbonising energy. In this study the Raney2.0 coating was analysed using various electrochemical techniques to assess its absolute performance, and it was confirmed to have an extremely low overpotential for hydrogen evolution of just 28 mV at 10 mA/cm2. It was also confirmed to be an acceptable catalyst for oxygen evolution, making it the highest performing simple bifunctional electrocatalyst known. The coating exhibits an extremely high capacitance of up to 1.7 F/cm2, as well as being able to store 0.61 J/cm2 in the form of temporary hydride deposits. A new technique is presented that performs a best-fit of a transient simulation of an equivalent circuit containing a constant phase element to cyclic voltammetry measurements. From this the roughness factor of the coating was calculated to be approximately 40,000, which is the highest figure ever reported for this type of material. The coating is therefore an extremely useful improved bifunctional coating for the continued roll-out of alkaline electrolysis for large-scale renewable energy capture via hydrogen production.


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