Catalyst-free self-healing fully bio-based vitrimers derived from tung oil: Strong mechanical properties, shape memory, and recyclability

2021 ◽  
Vol 171 ◽  
pp. 113978
Author(s):  
Ya-zhou Xu ◽  
Pan Fu ◽  
Song-lin Dai ◽  
Hai-bo Zhang ◽  
Liang-wu Bi ◽  
...  
2018 ◽  
Vol 29 (20) ◽  
pp. 3972-3982 ◽  
Author(s):  
Mohammad Amin Poormir ◽  
Seyed Mohammad Reza Khalili ◽  
Reza Eslami-Farsani

Utilizing smart materials such as shape memory alloys as reinforcement in metal matrix composites is a novel method to bio-mimic self-healing. This study aims to investigate the influence of design factors of a self-healing metal matrix composite by employing the Taguchi method for designing of the experimental procedure. Three design factors, each in three levels, were studied simultaneously according to L-9 standard Taguchi orthogonal array to determine the optimal level of each factor in mechanical properties enhancement with a reduced number of experiments. Composite specimens were fabricated from Sn-13 wt.% Bi alloy as matrix and nickel–titanium shape memory alloy strips as reinforcement with gravity casting process. Matrix alloy was melted and casted in a preheated metallic mold in which SMA strips were installed in various quantities (one, two, or three strips) and different pre-strains (0%, 2%, or 6%). After fabrication of the specimens, a tensile test was conducted until fracture to specify mechanical properties. Then, specimens were placed in a furnace in three different temperatures (170°C, 180°C, and 190°C) to activate the shape memory effect of strips and achieve crack closure and healing. Specimens were tensile tested again after healing to calculate the amount of healed properties and healing efficiency. Results show that using three strips with 6% of pre-strain and applying 190°C healing temperature can maximize the ultimate tensile strength efficiency. Also, the existence of one strip, 0% pre-strain, and 190°C healing temperature creates the best circumstances for healing ductility.


Author(s):  
Shishan Xue ◽  
Yuanpeng Wu ◽  
Guanfei Liu ◽  
Meiling Guo ◽  
Yuhan Liu ◽  
...  

A hierarchically reversible crosslinked hydrogel has been designed with excellent mechanical properties, efficient self-healability and double-driven shape memory effect (pH, Ca2+). A soft catcher actuator was constructed, which could catch a plastic fish in Ca2+ solution.


2020 ◽  
Vol 8 (32) ◽  
pp. 16203-16211 ◽  
Author(s):  
Chaoxian Chen ◽  
Siwen Chen ◽  
Zhihao Guo ◽  
Wanruo Hu ◽  
Zhangpei Chen ◽  
...  

Novel dual-physical cross-linked elastomers with unprecedented mechanical, highly efficient self-healing, and excellent shape memory properties are designed, which will offer new guild for future body-sensors, stimulating reactive and wound healing.


2021 ◽  
Author(s):  
Jinshuai Zhang ◽  
Jia Huang ◽  
Guoqiang Zhu ◽  
Xixi Yu ◽  
Jianwen Cheng ◽  
...  

This study reports the development of super “green” smart coatings by integrating renewable resources, microwave-assisted synthesis, and dynamic covalent chemistry into UV-curable coatings. First, a novel UV-curable oligomer (TMG) was...


Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1679
Author(s):  
Yanning Zeng ◽  
Weiming Yang ◽  
Shuxin Liu ◽  
Xiahui Shi ◽  
Aoqian Xi ◽  
...  

Thermoset polymers show favorable material properties, while bringing about environmental pollution due to non-reprocessing and unrecyclable. Diels–Alder (DA) chemistry or reversible exchange boronic ester bonds have been employed to fabricate recycled polymers with covalent adaptable networks (CANs). Herein, a novel type of CANs with multiple dynamic linkers (DA chemistry and boronic ester bonds) was firstly constructed based on a linear copolymer of styrene and furfuryl methacrylate and boronic ester crosslinker. Thermoplastic polyurethane is introduced into the CANs to give a semi Interpenetrating Polymer Networks (semi IPNs) to enhance the properties of the CANs. We describe the synthesis and dynamic properties of semi IPNs. Because of the DA reaction and transesterification of boronic ester bonds, the topologies of semi IPNs can be altered, contributing to the reprocessing, self-healing, welding, and shape memory behaviors of the produced polymer. Through a microinjection technique, the cut samples of the semi IPNs can be reshaped and mechanical properties of the recycled samples can be well-restored after being remolded at 190 °C for 5 min.


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