Self-healing, recyclable, and shape memory UV-curable coatings derived from tung oil and malic acid

2021 ◽  
Author(s):  
Jinshuai Zhang ◽  
Jia Huang ◽  
Guoqiang Zhu ◽  
Xixi Yu ◽  
Jianwen Cheng ◽  
...  
Keyword(s):  
Shape Memory ◽  
Malic Acid ◽  
Renewable Resources ◽  
Microwave Assisted Synthesis ◽  
Self Healing ◽  
Uv Curable ◽  
Dynamic Covalent Chemistry ◽  
Tung Oil ◽  
Microwave Assisted ◽  
Smart Coatings

This study reports the development of super “green” smart coatings by integrating renewable resources, microwave-assisted synthesis, and dynamic covalent chemistry into UV-curable coatings. First, a novel UV-curable oligomer (TMG) was...

High-biobased-content UV-curable oligomers derived from tung oil and citric acid: Microwave-assisted synthesis and properties

2020 ◽  
Vol 140 ◽  
pp. 109997
Author(s):  
Jinshuai Zhang ◽  
Qianqian Shang ◽  
Yun Hu ◽  
Fei Zhang ◽  
Jia Huang ◽  
...  
Keyword(s):  
Citric Acid ◽  
Microwave Assisted Synthesis ◽  
Uv Curable ◽  
Tung Oil ◽  
Microwave Assisted ◽  
Biobased Content

Catalyst-free self-healing fully bio-based vitrimers derived from tung oil: Strong mechanical properties, shape memory, and recyclability

2021 ◽  
Vol 171 ◽  
pp. 113978
Author(s):  
Ya-zhou Xu ◽  
Pan Fu ◽  
Song-lin Dai ◽  
Hai-bo Zhang ◽  
Liang-wu Bi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Shape Memory ◽  
Self Healing ◽  
Tung Oil ◽  
Catalyst Free

Microwave-assisted synthesis of malic acid involving hydrochloric acid as catalyst

2017 ◽  
Vol 122 (2) ◽  
pp. 793-802 ◽  
Author(s):  
Ronald Wbeimar Pacheco Ortiz ◽  
Brendha Gonçalves de Jesús ◽  
Elton Franceschi ◽  
Cláudio Dariva ◽  
Lúcio Cardozo-Filho ◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
Malic Acid ◽  
Microwave Assisted Synthesis ◽  
Microwave Assisted

scholarly journals Self-Healing Performance of Smart Polymeric Coatings Modified with Tung Oil and Linalyl Acetate

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1609
Author(s):  
Norhan Ashraf Ismail ◽  
Adnan Khan ◽  
Eman Fayyad ◽  
Ramazan Kahraman ◽  
Aboubakr M. Abdullah ◽  
...  
Keyword(s):  
Electrochemical Impedance ◽  
In Situ Polymerization ◽  
Urea Formaldehyde ◽  
Average Particle Size ◽  
Average Particle ◽  
Self Healing ◽  
Polymeric Coatings ◽  
Linalyl Acetate ◽  
Tung Oil ◽  
Smart Coatings

This work focuses on the synthesis and characterization of polymeric smart self-healing coatings. A comparison of structural, thermal, and self-healing properties of two different polymeric coatings comprising distinct self-healing agents (tung oil and linalyl acetate) is studied to elucidate the role of self-healing agents in corrosion protection. Towards this direction, urea-formaldehyde microcapsules (UFMCs) loaded with tung oil (TMMCs) and linalyl acetate (LMMCs) were synthesized using the in-situ polymerization method. The synthesis of both LMMCs and TMMCs under identical experimental conditions (900 rpm, 55 °C) has resulted in a similar average particle size range (63–125 µm). The polymeric smart self-healing coatings were developed by reinforcing a polymeric matrix separately with a fixed amount of LMMCs (3 wt.% and 5 wt.%), and TMMCs (3 wt.% and 5 wt.%) referred to as LMCOATs and TMCOATs, respectively. The development of smart coatings (LMCOATs and TMCOATs) contributes to achieving decent thermal stability up to 450 °C. Electrochemical impedance spectroscopy (EIS) analysis indicates that the corrosion resistance of smart coatings increases with increasing concentration of the microcapsules (TMMCs, LMMCs) in the epoxy matrix reaching ~1 GΩ. As a comparison, LMCOATs containing 5 wt.% LMMCs demonstrate the best stability in the barrier properties than other developed coatings and can be considered for many potential applications.

Dual-action smart coatings with a self-healing superhydrophobic surface and anti-corrosion properties

2017 ◽  
Vol 5 (5) ◽  
pp. 2355-2364 ◽  
Author(s):  
Hongchang Qian ◽  
Dake Xu ◽  
Cuiwei Du ◽  
Dawei Zhang ◽  
Xiaogang Li ◽  
...  
Keyword(s):  
Shape Memory ◽  
Corrosion Inhibitor ◽  
Superhydrophobic Surface ◽  
Shape Memory Polymer ◽  
Self Healing ◽  
Superhydrophobic Coating ◽  
Corrosion Properties ◽  
Smart Coatings ◽  
Dual Action

This work introduces a new self-healing superhydrophobic coating based on dual actions by the corrosion inhibitor benzotriazole (BTA) and an epoxy-based shape memory polymer (SMP).

scholarly journals Tailor‐Made Functional Polymethacrylates with Dual Characteristics of Self‐Healing and Shape‐Memory Based on Dynamic Covalent Chemistry

2020 ◽  
Vol 305 (6) ◽  
pp. 2000142 ◽  
Author(s):  
Prantik Mondal ◽  
Prasanta K. Behera ◽  
Brigitte Voit ◽  
Frank Böhme ◽  
Nikhil K. Singha
Keyword(s):  
Shape Memory ◽  
Self Healing ◽  
Dynamic Covalent Chemistry
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