The main feature of this article is the investigation on the influence of temperature, relative humidity, film thickness on permeability of PET packaging film, the analysis of perm-selectivity of the packaging films for oxygen gas and carbon dioxide gas, and the evaluation on experimental formulas of water vapor, O2 and CO2 gas permeating rates on the basis of gas molecular osmotic reaction kinetics and regression analysis. The comparison between experimental studies and calculation indicates that: (1) with increment of ambient temperature water vapor, O2 and CO2 permeating rate of PET films and PET/Al film also rise, and the logarithm of water vapor, O2 and CO2 gas permeating rates has linear relation with the reciprocal of thermodynamic temperature, and (2) the influence of relative humidity on water vapor permeating rate of PET film with thickness 12µm is the least, and that of PET film with thickness 20µm and PET/Al film with thickness 18µm is a little obvious. (3) The PET films hold remarkable perm-selectivity for O2 and CO2 gas, and CO2 gas permeating rate is about two times of O2 gas, yet O2 and CO2 gas permeating rates of PET/Al film are both very low and have small difference, so the PET/Al film has better barrier performance than the PET film.
