Synthesis, characterization and high temperature CO2 capture capacity of nanoscale Ca-based layered double hydroxides via reverse microemulsion

2014 ◽  
Vol 586 ◽  
pp. S498-S505 ◽  
Author(s):  
Po-Hsueh Chang ◽  
Yen-Po Chang ◽  
Yen-Ho Lai ◽  
San-Yuan Chen ◽  
Ching-Tsung Yu ◽  
...  
2021 ◽  
Author(s):  
Manohara Gudiyor Veerabhadrappa ◽  
David Norris ◽  
Mercedes Maroto-Valer ◽  
Susana García

Layered double hydroxides (LDHs) based mixed metal oxides (MMOs) are promising high temperature CO2 capture sorbents. In order to improve their CO2 capture capacity, it is crucial to bring in...


ChemSusChem ◽  
2011 ◽  
Vol 4 (12) ◽  
pp. 1844-1851 ◽  
Author(s):  
Po-Hsueh Chang ◽  
Yen-Po Chang ◽  
San-Yuan Chen ◽  
Ching-Tsung Yu ◽  
Yau-Pin Chyou

2017 ◽  
Vol 22 (3) ◽  
pp. 215 ◽  
Author(s):  
Oscar H Ojeda-Niño ◽  
Carolina Blanco ◽  
Carlos E Daza

Hydroxyapatite (HAp) was obtained from tilapia scales by two extraction<br />methods: direct calcination and acid-base treatment. The physicochemical<br />characteristics of the obtained HAps were evaluated by thermogravimetric<br />analysis, X-ray fluorescence, X-ray diffraction, scanning electron microscopy, surface area, infrared spectroscopy, and basicity measurement at 298 K by CO2-pulse titration. Furthermore, the CO2 capture capacity of the solids at high temperature was also determined. Both methods showed the presence of a HAp phase although significant differences in the properties of the solids were found. The HAp obtained by direct calcination, exhibited a lower crystallinity and a greater surface area and basicity than the HAp obtained by the acid-base treatment. These features were correlated with the solid’s CO2 capture capacity. In this work, CO2 capture capacity values for HAp yielded by calcination ranged from 2.5 to 3.2 mg CO2 /g captured at 973 K, and for the acid-base treatment-derived HAp, CO2 capture capacity values between 1.2 to 2.5 mg CO2 /g were recorded. These results reveal the potential of HAps extracted from tilapia scales as solids with high CO2 capture capacity, thermal stability, and capture/release cycles reversibility.


ChemSusChem ◽  
2010 ◽  
Vol 3 (8) ◽  
pp. 965-973 ◽  
Author(s):  
Qiang Wang ◽  
Hui Huang Tay ◽  
Desmond Jia Wei Ng ◽  
Luwei Chen ◽  
Yan Liu ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3188
Author(s):  
Ren-Wei Chang ◽  
Chin-Jung Lin ◽  
Ya-Hsuan Liou

Calcium oxide (CaO) is a promising adsorbent to separate CO2 from flue gas. However, with cycling of carbonation/decarbonation at high temperature, the serious sintering problem causes its capture capacity to decrease dramatically. A CaTiO3-decorated CaO-based CO2 adsorbent was prepared by a continuous and simple aerosol-assisted self-assembly process in this work. Results indicated that CaTiO3 and CaO formed in the adsorbent, whereas CaO gradually showed a good crystalline structure with increased calcium loading. Owing to the high thermal stability of CaTiO3, it played a role in suppressing the sintering effect and maintaining repeated high-temperature carbonation and decarbonation processes. When the calcium and titanium ratio was 3, the CO2 capture capacity was as large as 7 mmol/g with fast kinetics. After 20 cycles under mild regeneration conditions (700 °C, N2), the performance of CO2 capture of CaTiO3-decorated CaO-based adsorbent nearly unchanged. Even after 10 cycles under severe regeneration conditions (920 °C, CO2), the performance of CO2 capture still remained nearly 70% compared to the first cycle. The addition of CaTiO3 induced good and firm CaO dispersion on its surface. Excellent kinetics and stability were evident.


2016 ◽  
Vol 4 (3) ◽  
pp. 1439-1445 ◽  
Author(s):  
Jie Chen ◽  
Jie Yang ◽  
Gengshen Hu ◽  
Xin Hu ◽  
Zhiming Li ◽  
...  

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