Sphere-like MoS2 and porous TiO2 composite film on Ti foil as lithium-ion battery anode synthesized by plasma electrolytic oxidation and magnetron sputtering

2022 ◽  
Vol 892 ◽  
pp. 162075
Author(s):  
Menglu Sun ◽  
Jie Wu ◽  
Ping Lu ◽  
Zhonghua Zhang ◽  
Yifan Zhang ◽  
...  
Keyword(s):  
Magnetron Sputtering ◽  
Composite Film ◽  
Lithium Ion Battery ◽  
Plasma Electrolytic Oxidation ◽  
Lithium Ion ◽  
Porous Tio2 ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic ◽  
Battery Anode

Rapid construction of TiO2/SiO2 composite film on Ti foil as lithium-ion battery anode by plasma discharge in solution

2019 ◽  
Vol 114 (4) ◽  
pp. 043903 ◽  
Author(s):  
Jie Wu ◽  
Xiaodong He ◽  
Guozheng Li ◽  
Jianhua Deng ◽  
Lin Chen ◽  
...  
Keyword(s):  
Composite Film ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Plasma Discharge ◽  
Rapid Construction ◽  
Battery Anode

Structure and Photocatalytic Properties of Fixed Porous TiO2 Composite Film on Steel Prepared by Plasma Electrolytic Oxidation

2012 ◽  
Vol 217-219 ◽  
pp. 1073-1076
Author(s):  
Yun Long Wang ◽  
Miao Wang ◽  
Mao Sun Xu ◽  
Yue Mei Qin
Keyword(s):  
Composite Film ◽  
Photocatalytic Degradation ◽  
Ultraviolet Light ◽  
Rhodamine B ◽  
Plasma Electrolytic Oxidation ◽  
Film Surface ◽  
Photocatalytic Properties ◽  
Ceramic Film ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic

TiO2 composite photocatalytic film was fixed on steel by by plasma electrolytic oxidation. The microstructure of the composite film were investigated by XRD, EDS and SEM. The photocatalytic properties of the film were studied by testing the photocatalytic degradation of Rhodamine B. The results showed that the ceramic film was composed of A-TiO2 and R-TiO2. The EDS revealed that the film consisted Ti, O, Si and Fe elements. The SEM pictures showed that the film surface was rough and porous. The photocatalytic experiment results showed that the the TiO2 composite film fixed on steel by plasma electrolytic oxidation exhibited relatively high photocatalytic photodegradation of Rhodamine B, whose removal ratio reached 90% in 2 hours, irradiation of ultraviolet light.

scholarly journals Fabrication of a Novel Ta(Zn)O Thin Film on Titanium by Magnetron Sputtering and Plasma Electrolytic Oxidation for Cell Biocompatibilities and Antibacterial Applications

Metals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 649
Author(s):  
Heng-Li Huang ◽  
Ming-Tzu Tsai ◽  
Yin-Yu Chang ◽  
Yi-Jyun Lin ◽  
Jui-Ting Hsu
Keyword(s):  
Thin Films ◽  
Magnetron Sputtering ◽  
Cell Viability ◽  
Plasma Electrolytic Oxidation ◽  
Tantalum Oxide ◽  
Antibacterial Properties ◽  
Pure Titanium ◽  
Antibacterial Performance ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic

Pure titanium (Ti) and titanium alloys are widely used as artificial implant materials for biomedical applications. The excellent biocompatibility of Ti has been attributed to the presence of a natural or artificial surface layer of titanium dioxide. Zinc oxide and tantalum oxide thin films are recognized due to their outstanding antibacterial properties. In this study, high power impulse magnetron sputtering (HiPIMS) was used for the deposition of tantalum oxide and zinc-doped Ta(Zn)O thin films on Ti with rough and porous surface, which was pretreated by plasma electrolytic oxidation (PEO). Surface morphology, antibacterial property as well as cell biocompatibility were analyzed. The antibacterial effect was studied individually for the Gram-positive and Gram-negative bacteria Staphylococcus aureus (S. aureus) and Actinobacillus actinomycetemcomitans (A. actinomycetemcomitans). The deposited Ta (Zn)O coating was composed of amorphous tantalum oxide and crystalline ZnO. The antibacterial results on the tantalum oxide and Ta(Zn)O coated Ti indicated a significant inhibition of both S. aureus and A. actinomycetemcomitans bacteria when compared with the uncoated Ti samples. The deposited Ta(Zn)O showed the best antibacterial performance. The Ta(Zn)O coated Ti showed lower level of the cell viability in MG-63 cells compared to other groups, indicating that Zn-doped Ta(Zn)O coatings may restrict the cell viability of hard tissue-derived MG-63 cells. However, the biocompatibility tests demonstrated that the tantalum oxide and Ta(Zn)O coatings improved cell attachment and cell growth in human skin fibroblasts. The cytotoxicity was found similar between the Ta2O5 and Ta(Zn)O coated Ti. By adopting a first PEO surface modification and a subsequent HiPIMS coating deposition, we synthetized amorphous tantalum oxide and Ta(Zn)O coatings that improved titanium surface properties and morphologies, making them a good surface treatment for titanium-based implants.

scholarly journals Characterization of Sn4P3–Carbon Composite Films for Lithium-Ion Battery Anode Fabricated by Aerosol Deposition

Nanomaterials ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 1032 ◽  
Author(s):  
Toki Moritaka ◽  
Yuh Yamashita ◽  
Tomohiro Tojo ◽  
Ryoji Inada ◽  
Yoji Sakurai
Keyword(s):  
Electrochemical Performance ◽  
Composite Film ◽  
Lithium Ion Battery ◽  
Active Material ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Aerosol Deposition ◽  
Raw Material ◽  
Composite Powders ◽  
Battery Anode

We fabricated tin phosphide–carbon (Sn4P3/C) composite film by aerosol deposition (AD) and investigated its electrochemical performance for a lithium-ion battery anode. Sn4P3/C composite powders prepared by a ball milling was used as raw material and deposited onto a stainless steel substrate to form the composite film via impact consolidation. The Sn4P3/C composite film fabricated by AD showed much better electrochemical performance than the Sn4P3 film without complexing carbon. Although both films showed initial discharge (Li+ extraction) capacities of approximately 1000 mAh g−1, Sn4P3/C films retained higher reversible capacity above 700 mAh g−1 after 100 cycles of charge and discharge processes while the capacity of Sn4P3 film rapidly degraded with cycling. In addition, by controlling the potential window in galvanostatic testing, Sn4P3/C composite film retained the reversible capacity of 380 mAh g−1 even after 400 cycles. The complexed carbon works not only as a buffer to suppress the collapse of electrodes by large volume change of Sn4P3 in charge and discharge reactions but also as an electronic conduction path among the atomized active material particles in the film.

scholarly journals Porous CaP Coatings Formed by Combination of Plasma Electrolytic Oxidation and RF-Magnetron Sputtering

Coatings ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1113
Author(s):  
Anna Kozelskaya ◽  
Gleb Dubinenko ◽  
Alexandr Vorobyev ◽  
Alexander Fedotkin ◽  
Natalia Korotchenko ◽  
...  
Keyword(s):  
Magnetron Sputtering ◽  
Young’S Modulus ◽  
Tricalcium Phosphate ◽  
Plasma Electrolytic Oxidation ◽  
Young's Modulus ◽  
Rf Magnetron Sputtering ◽  
Nanoindentation Test ◽  
X Ray ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic

The porous CaP subcoating was formed on the Ti6Al4V titanium alloy substrate by plasma electrolytic oxidation (PEO). Then, upper coatings were formed by radio frequency magnetron sputtering (RFMS) over the PEO subcoating by the sputtering of various CaP powder targets: β-tricalcium phosphate (β-TCP), hydroxyapatite (HA), Mg-substituted β-tricalcium phosphate (Mg-β-TCP) and Mg-substituted hydroxyapatite (Mg-HA), Sr-substituted β-tricalcium phosphate (Sr-β-TCP) and Sr-substituted hydroxyapatite (Sr-HA). The coating surface morphology was studied by scanning electron and atomic force microscopy. The chemical composition was determined by X-ray photoelectron spectroscopy. The phase composition of the coatings was studied by X-ray diffraction analysis. The Young’s modulus of the coatings was studied by nanoindentation test. RF-magnetron sputtering treatment of PEO subcoating resulted in multileveled roughness, increased Ca/P ratio and Young’s modulus and enrichment with Sr and Mg. Sputtering of the upper layer also helped to adjust the coating crystallinity.

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