Internal oxidation of cast iron artifacts from an 18th-century steel cementation furnace

2012 ◽  
Vol 39 (8) ◽  
pp. 2714-2721 ◽  
Author(s):  
Colin Thomas ◽  
Richard Hunter ◽  
Robert Gordon
Radiocarbon ◽  
2019 ◽  
Vol 61 (03) ◽  
pp. 831-843 ◽  
Author(s):  
J S Park ◽  
W Honeychurch ◽  
A Chunag

ABSTRACTCast iron objects recovered primarily in eastern Mongolia, spanning the Xiongnu through the Early Historic periods (ca. 3rd BC–AD 17th century), were examined for their radiocarbon (14C) concentration and microstructure. Most of the samples examined were found to have originated from charcoal-based smelting with a few exceptions that were made using a mineral coal-based technique. A comparison of 14C dates with dates derived from artifact typology allowed the charcoal-smelted objects to be classified into two groups, based on whether the radiometric and typological periodization are in agreement or not. In addition, those with differing 14C and typological dates can be divided into two subgroups with and without evidence for a melt treatment applied after original casting. These conflicting dating results are confusing and would seem to provoke skepticism about the use of 14C measurements for dating iron artifacts. We demonstrate however that 14C analysis, when combined with metallographic examination and other lines of chronological evidence, can clarify the history of a given iron object and its multiple users, often separated in time by more than a millennium.


Coatings ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 12 ◽  
Author(s):  
Paola Roncagliolo Barrera ◽  
Francisco Rodríguez Gómez ◽  
Esteban García Ochoa

Cast iron has stood for centuries of invention. It is a very versatile and durable material. Coating systems are a low-maintenance protection method. The purpose of this research is to increase the Paraloid coating’s resistance when applied to iron in high humidity atmospheres, with the addition of caffeine (1,3,7-dimethylxanthine) and nicotine (S)-3-(1-methylpyrrolidin-2-yl) pyridine as corrosion inhibitors; the resistance of protection versus exposure time will be evaluated by using electrochemical noise. A statistical analysis of the electrochemical noise signals was carried out. Recurrence plots were used as a powerful tool in the analysis to complement the data obtained and they predicted the evaluation of coatings behaviors performance versus time. The outcomes show that the addition of inhibitors increases and improves the performance as a temporary protection of Paraloid and that protection in high relative humidity was improved. Recurrence plots and parameter quantification show the variances in the surface corrosion dynamics.


2019 ◽  
Vol 120 (4) ◽  
pp. 387-393
Author(s):  
V. M. Schastlivtsev ◽  
B. A. Gizhevsky ◽  
Yu. V. Khlebnikova ◽  
S. V. Naumov ◽  
E. I. Patrakov
Keyword(s):  

1981 ◽  
Vol 1 (1) ◽  
pp. 203-206
Author(s):  
O.P. Nicholson ◽  
J.G. Mc Donnell
Keyword(s):  

2014 ◽  
Vol 887-888 ◽  
pp. 262-265
Author(s):  
Wei Zhen Ouyang

The components of corrosion products on rusted cast iron artifacts in a wet/dry atmospheric environment have been studied by micro-Raman spectroscopy. The observations show that microstructures of outer and inner interfaces are different; indicating that active corrosion occurred on the rusted specimen covered with many cracks and pores. The μRaman spectra of outer and inner layer results prove to be composed of three main iron oxyhydroxides. In addition, Fe3O4 only exists in the inner layer.


2013 ◽  
Vol 690-693 ◽  
pp. 97-100
Author(s):  
Wei Zhen Ouyang

The atmospheric corrosion behavior of cast iron after six months immersion was studies by means of optical stereomicroscope and X-ray diffraction techniques. The results showed that active corrosion occurred on the rusted specimen covered with many thin spherical shells of solid material. The XRD analysis indicated the formation of β-FeOOH tends to increase with increasing exposure.


2012 ◽  
Vol 229-231 ◽  
pp. 2506-2509
Author(s):  
Shao Wen Guo ◽  
Wei Zhen Ou Yang

Chloride ion migration and the choice of optimized current density during galvanostatic dechlorination of simulated cast iron artifacts in alkaline solution were studied by means of galvanostatic polarization. The results showed that the more treatment time and the more current density, the more was the extraction ratio of chloride ion and the less was the electrical efficiency. The current density was optimized with respect to the extraction ratio of chloride ion and the electrical efficiency, and the optional current density was presented.


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