A lead-isotope database of copper ores from the Southeastern Alps: A tool for the investigation of prehistoric copper metallurgy

2016 ◽  
Vol 75 ◽  
pp. 27-39 ◽  
Author(s):  
G. Artioli ◽  
I. Angelini ◽  
P. Nimis ◽  
I.M. Villa
2001 ◽  
Vol 4 (1) ◽  
pp. 43-85 ◽  
Author(s):  
Friedrich Begemann ◽  
Sigrid Schmitt-Strecker ◽  
Ernst Pernicka ◽  
Fulvia Lo Schiavo

We present data on the chemical and lead isotope composition of copper and bronze objects from Nuragic Sardinia. The sample suite comprises, inter alia, objects from the hoard finds at Arzachena (21 objects), Bonnanaro (10), Ittireddu (34), and Pattada (20), all in northern Sardinia. With one exception, all ingot fragments (49) consist of unalloyed copper; the exception comes from Ittireddu and contains 11 per cent tin. In contradistinction, all implements (21) are made from standard bronze with a mean tin content of 10.8 per cent. A dozen sword fragments from the Arzachena hoard, all of fairly uniform small size, are pieces of a large number of different swords. The low tin content of only about 1 per cent would have made for poor weapons, confirming the archaeological identification of the fragments as pieces of votive swords. Scrap metal from Arzachena is remarkable for its wide range of trace element contents and lead isotope abundance ratios. It is dissimilar to all other metal samples investigated, possibly representing metal from local smelting experiments using a variety of different copper ores. Lead isotope data and trace element patterns, alone or in conjunction, do not allow us to tell oxhide ingots from plano-convex (bun) ingots. Most ingot fragments have a lead isotope signature similar to those of Cypriot copper ores but there are also a number of ingots whose lead isotope fingerprints are fully compatible with them being local products. Of the bronzes, none has lead with an isotopic composition characteristic of copper ingots from Cyprus. All contain local lead, suggesting the bronze implements were manufactured locally. Isotopically-fitting lead is found in copper and lead ore deposits from the Iglesiente-Sulcis district in south-west Sardinia and from Funtana Raminosa in central Sardinia.


Metals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1252
Author(s):  
Xiaoting Wang ◽  
Wugan Luo ◽  
Yingdong Yang ◽  
Dian Chen ◽  
Jing Du ◽  
...  

The debate about the highly radiogenic lead in Chinese archaeology has never ceased. However, previous studies have mainly focused on high leaded bronzes and lead materials, and with little specific discussion on the unalloyed copper artifacts and the sources of copper materials in China. In this work, a trace of highly radiogenic lead was found in ten copper spearheads unearthed from Huili County, Sichuan Province, southwest China, which inspired our research on this issue. The pXRF results showed that their lead content is extremely low, so the lead isotope ratios can indicate the source of copper, and the data correspond to the local copper deposits. Combined with other relevant highly radiogenic lead isotope data of unalloyed copper artifacts, the results indicate that there were multiple sources of copper ores used in the Shang Dynasty, and copper mines were continuously used in Southwest China until the Eastern Zhou Dynasty.


2018 ◽  
Vol 19 ◽  
pp. 11-23 ◽  
Author(s):  
L. Chiarantini ◽  
M. Benvenuti ◽  
P. Costagliola ◽  
A. Dini ◽  
M. Firmati ◽  
...  

2021 ◽  
Vol 21 (1) ◽  
pp. 47-74

Abstract A series of excavations were conducted at the Xiwubi site during 2018–2019, yielding abundant copper metallurgy remains dating to the Erlitou and Erligang cultural periods. Archaeological features include remains of smelting furnaces, charcoal kilns, houses, and refuse pits. A variety of artifacts were retrieved, ranging from copper ores, fragments of smelting furnaces, crucibles, and slag to objects made of pottery, stone, and bone. It is the first copper metallurgy site found in the Zhongtiao Mountains in the vicinity of the heartland of the Xia and Shang dynasties. Characterized by early dates, large scale, and advanced specialization in copper metallurgy, the excavation of the Xiwubi site provides substantial materials for the study of mining and use of copper ore resources by the Xia and Shang dynasties, as well as interactions between copper metallurgy and the destiny of the royal courts.


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