Support effects in iridium-catalyzed aerobic oxidation of benzyl alcohol studied by modulation-excitation attenuated total reflection IR spectroscopy

2021 ◽  
Vol 393 ◽  
pp. 42-50
Author(s):  
Shizuka Ito ◽  
Xianwei Wang ◽  
Ammara Waheed ◽  
Gao Li ◽  
Nobutaka Maeda ◽  
...  
2014 ◽  
Vol 3 (1) ◽  
pp. 99-110 ◽  
Author(s):  
Hannes Alex ◽  
Norbert Steinfeldt ◽  
Klaus Jähnisch ◽  
Matthias Bauer ◽  
Sandra Hübner

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.


2009 ◽  
Vol 10 (13) ◽  
pp. 1752-1756 ◽  
Author(s):  
Hao Yu ◽  
Yan Zhang ◽  
Xiaobo Fu ◽  
Feng Peng ◽  
Hongjuan Wang ◽  
...  

2013 ◽  
Vol 378 ◽  
pp. 47-56 ◽  
Author(s):  
Sandip Mandal ◽  
Chiranjit Santra ◽  
Kyoko K. Bando ◽  
Olusola O. James ◽  
Sudip Maity ◽  
...  

2014 ◽  
Vol 240 ◽  
pp. 434-442 ◽  
Author(s):  
Jin Luo ◽  
Hao Yu ◽  
Hongjuan Wang ◽  
Haihui Wang ◽  
Feng Peng

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