An Efficient Chiral Porous Catalyst Support -Hypercrosslinked Amino Acid Polymer

Author(s):  
Yaodong Wang ◽  
Lijia Liu ◽  
Kexiao Sang ◽  
Yudan Wang ◽  
Chunhong Zhang ◽  
...  
1998 ◽  
Vol 102 (17) ◽  
pp. 3090-3098 ◽  
Author(s):  
Igor V. Koptyug ◽  
Vladimir B. Fenelonov ◽  
Ludmila Yu. Khitrina ◽  
Renad Z. Sagdeev ◽  
Valentin N. Parmon

2019 ◽  
Vol 63 (3-4) ◽  
pp. 319-327 ◽  
Author(s):  
Neil Robinson ◽  
Carmine D’Agostino

AbstractPulsed field gradient NMR diffusion measurements provide a non-invasive measure of the mass transport (self-diffusion) characteristics of liquids confined to porous catalyst materials. Here we explore the ability of this technique to probe the diffusive behaviour of a series of short-chain primary alcohols within a mesoporous catalyst support material; through the comparison of our results with highly surface-sensitive NMR relaxation data, we show that the evaluation of bulk-pore diffusion dynamics may provide a simple and indirect method to access and explore surface interaction phenomena occurring at the catalyst-liquid interface.


2021 ◽  
pp. 2007368
Author(s):  
Jun‐Xi Wu ◽  
Partha Pratim Bag ◽  
Yan‐Tong Xu ◽  
Li Gong ◽  
Chun‐Ting He ◽  
...  

2015 ◽  
Vol 670 ◽  
pp. 139-143 ◽  
Author(s):  
Tatiana Bugrova ◽  
Anastasia Tatarkina ◽  
Ilya Zhukov ◽  
Grigory Mamontov

The moulded Al2O3 materials prepared by mixing of thermochemically activated aluminum trihydroxide (TCA ATH) with wood flour were proposed to be used as promising porous catalyst support for various processes. A series of Al2O3 supports with different wood flour loading (0, 2 and 5 %wt.) were studied by SEM, low-temperature N2 sorption, XRD, granule strength and water-absorbing capacity. It was shown that supports were characterized by porous structure with mesopore sizes of 2-20 nm and specific surface area of 159-186 m2/g. The increase of the amount of wood flour leads to increase of the share of pore volume with wider than 10 nm and the decrease of the strength of alumina granules. Thus, optimization of preparation conditions allows obtaining alumina materials with desired porous structure.


2011 ◽  
Vol 284-286 ◽  
pp. 1358-1361
Author(s):  
Da Cheng Liu ◽  
Shi Zhe Liu ◽  
Bin Hao ◽  
Yue Li

Porous catalyst support was prepared using gangue of bauxite tailing which was a solid waste material. It was found that the mass ratio of gangue of bauxite and knar clay was 4: 1. The masses of cellulose and water were individually 1 wt% and 25 wt% of the total mass of gangue of bauxite tailing and knar clay. The pore forming agent M was optimum among the selected pore forming agents. The pore forming agent M didn’t residue in support after sintering so that the support wasn’t polluted. The appropriate addition of the pore forming agent M was 4%, and the catalyst support with the porosity of 41.3% was preparated. The appropriate sintering temperature and holding time were 1250 °C and 2.0 h, respectively. Mullite and quartz were the main mineral phase of the porous catalyst support and the catalyst support have good chemical stability and heat-resisting property.


Author(s):  
M.K. Lamvik ◽  
L.L. Klatt

Tropomyosin paracrystals have been used extensively as test specimens and magnification standards due to their clear periodic banding patterns. The paracrystal type discovered by Ohtsuki1 has been of particular interest as a test of unstained specimens because of alternating bands that differ by 50% in mass thickness. While producing specimens of this type, we came across a new paracrystal form. Since this new form displays aligned tropomyosin molecules without the overlaps that are characteristic of the Ohtsuki-type paracrystal, it presents a staining pattern that corresponds to the amino acid sequence of the molecule.


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