Establishing correlation between effective diffusivity coefficient and the mass transfer for Zn2+ column extraction by D2EHPA: An experimental and theoretical investigation

2018 ◽  
Vol 6 (5) ◽  
pp. 6322-6327
Author(s):  
Zahra Anari ◽  
Elmira Katoozi ◽  
Arijit Sengupta
2021 ◽  
Author(s):  
Ahmed Monofy ◽  
Fulvio Boano ◽  
Stanley B. Grant ◽  
Megan A. Rippy

<p>In-stream environments, many biogeochemical processes occur in the benthic biolayer, i.e., within sediments at a very shallow depth close to the sediment-water interface (SWI). These processes are important for stream ecology and the overall environment.</p><p>Here, a 1D diffusive model is used to analyze the vertical exchange of solutes through the SWI and in the benthic biolayer. The model is applied to an extensive set of previously published laboratory experiments of solute exchange with different bed morphologies: flatbeds, dunes, and alternate bars. Although these different bed features induce mixing that is controlled by different physical processes at the SWI, overall mixing within the sediment is well represented by a parsimonious diffusive model, provided that the diffusivity profile declines exponentially with sediment depth.</p><p>For all morphology types, mixing is better simulated by an exponential diffusivity model than a constant diffusivity approach. Two parameters define the exponential diffusivity model; the effective diffusivity at the SWI, and a depth scale over which the exponential profile decays. Using a combination of classification and regression trees (CART) and multiple linear regression approaches, we demonstrate that a single predictive model captures measured variability in the effective diffusivity coefficient at the SWI across all morphological types. The best predictive model for the decay depth scale, on the other hand, is tailored to each morphological type separately.</p><p>The predictive framework developed here contributes to our understanding of the physical processes responsible for mixing across the SWI,  and therefore the in-bed processes that contribute to the biogeochemical processing of nutrients and other contaminants in streams.</p>


2011 ◽  
Vol 312-315 ◽  
pp. 364-369 ◽  
Author(s):  
Seyed Amir Bahrani ◽  
Catherine Loisel ◽  
Jean Yves Monteau ◽  
Sid Ahmed Rezzoug ◽  
Zoulikha Maache-Rezzoug

Two hydrothermal treatment processes (DV-HMT and DIC treatment) were investigated on standard maize starch for three processing temperatures; 100, 110 and 120°C. The gravimetric change of starch powder during the treatment was analyzed by a simultaneous water diffusion and starch reaction model. The effective diffusivity coefficient (Deff) and reaction rate constant (k) were estimated by minimizing the error between experimental and analytical results. The values of Deff and k clearly increased with temperature. The degree of starch melting was evaluated for the two treatments using the first-order reaction model as a function of processing time. The results suggest that the absorption process is controlled by water–starch reactivity that induces melting phenomenon of starch crystallites, which progresses when temperature increases. The two hydrothermal treatments considerably differ: DIC being more prone to water absorption as demonstrated by the values of Deff and k.


2020 ◽  
Vol 23 (2) ◽  
pp. 92-98
Author(s):  
Amor Bouhdjar ◽  
Hakim Semai ◽  
Amal Boukadoum ◽  
Sofiane Elmokretar ◽  
Azzedine Mazari ◽  
...  

AbstractVegetable drying is an energy consuming procedure despite the fact that it is the most efficient way to preserve agricultural products. This study investigates a new way to dry good quality garlic at lower cost. Thin garlic layer was submitted to free convection airflow at air drying temperature of 40 °C, 50 °C, and 60 °C. Using the slope method, effective diffusivity coefficient was determined at each drying temperature during the first and second falling drying rate periods. Considering the former, it increased with increasing temperature. In relation to latter, it decreased with the temperature increase. However, at low drying temperatures, process keeps on going to very low moisture content; and it develops to an asymptotic value at high temperatures, indicating that shrinking at high temperature prevents evaporation of some residual moisture. Considered separately, these temperatures do not reflect the conditions met in solar drying, since in solar systems, air temperature increases during the day with increasing solar radiation. Therefore, characterization of garlic drying by means of step temperature varying – the first hour of drying at 40 °C; the second hour of drying at 50 °C, and the remaining time of drying at 60 °C – might better correspond with conditions under solar drying and result in better understanding of the process.


2020 ◽  
Vol 42 ◽  
pp. e40570
Author(s):  
Ibrahim Doymaz

Kiwifruit slices were dried at four different air drying temperatures of 50, 55, 60 and 70ºC and at 2 m s-1 air velocity by using a cabinet dryer in this study. The drying, rehydration and colour characteristics were significantly influenced by pretreatment and drying temperature. The drying time decreased with the increase in drying temperature. The drying rate curves showed that the entire drying process took place in the falling rate period. Five well-known thin-layer models were evaluated for moisture ratios using nonlinear regression analysis. The results of regression analysis indicated that the Midilli & Kucuk model the best to describe the drying behaviour with the lowest c2 and RMSE values, and highest R2 value. The effective moisture diffusivity of the dried kiwifruit slices was calculated with Fick’s diffusion model, in which their values varied from 4.19×10–10 to 6.99×10-10 m2 s-1 over the mentioned temperature range. The dependence of effective diffusivity coefficient on temperature was expressed by an Arrhenius type equation. The calculated values of the activation energy of moisture diffusion were 10.37 and 19.08 kJ mol-1 for citric acid and control samples, respectively


2003 ◽  
Vol 88 (1-2) ◽  
pp. 3-16 ◽  
Author(s):  
David H. West ◽  
Vemuri Balakotaiah ◽  
Zoran Jovanovic

Author(s):  
Jyh-Jian Chen ◽  
Yu-Cheng Luo ◽  
Shin-Hau Su ◽  
Nai-Yu Jheng

This theoretical investigation analyzed the three-dimensional momentum and mass transfer characteristics arising from the multiple inlets and single outlet in micro chamber which consists of a right square prism, an octagonal prism or a cylinder. The effects of various geometric parameters, inlet velocities, and the types of lamination on the mixing characteristics were investigated, and the results were presented in terms of flow fields, concentration profiles, and mixing index. Numerical results indicated that vortex flow and numbers of inlets dominate the mixing index. At larger Taylor number, more inertia caused the powerful vortex flow in the chamber, and the damping effect on diffusion was diminished, which then increased the mixing performance. Furthermore, passive micromixers utilizing hybrid laminations showed better mixing results than those with parallel laminations.


2012 ◽  
Vol 32 (2) ◽  
pp. 342-353 ◽  
Author(s):  
Cleide M. D. P. da S. e Silva ◽  
Wilton P. da Silva ◽  
Vera S. de O. Farias ◽  
Josivanda P. Gomes

In this article, a methodology is used for the simultaneous determination of the effective diffusivity and the convective mass transfer coefficient in porous solids, which can be considered as an infinite cylinder during drying. Two models are used for optimization and drying simulation: model 1 (constant volume and diffusivity, with equilibrium boundary condition), and model 2 (constant volume and diffusivity with convective boundary condition). Optimization algorithms based on the inverse method were coupled to the analytical solutions, and these solutions can be adjusted to experimental data of the drying kinetics. An application of optimization methodology was made to describe the drying kinetics of whole bananas, using experimental data available in the literature. The statistical indicators enable to affirm that the solution of diffusion equation with convective boundary condition generates results superior than those with the equilibrium boundary condition.


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