Crystalline oxyfluorinated open-framework compounds: Silicates, metal phosphates, metal fluorides and metal-organic frameworks (MOF)

2007 ◽  
Vol 128 (4) ◽  
pp. 413-422 ◽  
Author(s):  
Thierry Loiseau ◽  
Gérard Férey
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Phosphates ◽  
Open Framework ◽  
Metal Fluorides ◽  
Metal Organic ◽  
Framework Compounds

scholarly journals Isoreticular zirconium-based metal–organic frameworks: discovering mechanical trends and elastic anomalies controlling chemical structure stability

2016 ◽  
Vol 18 (13) ◽  
pp. 9079-9087 ◽  
Author(s):  
Matthew R. Ryder ◽  
Bartolomeo Civalleri ◽  
Jin-Chong Tan
Keyword(s):  
Mechanical Properties ◽  
Chemical Structure ◽  
Metal Organic Frameworks ◽  
Structure Stability ◽  
Practical Applications ◽  
Open Framework ◽  
Metal Organic ◽  
Fundamental Research ◽  
Elastic Anomalies ◽  
Framework Compounds

Understanding the mechanical properties of MOFs is crucial not only to yield robust practical applications, but also to advance fundamental research underpinning flexibility of a myriad of open-framework compounds.

Necklace-like NiCo2O4@carbon composite nanofibers derived from metal-organic framework compounds for high rate lithium storage

2021 ◽  
Author(s):  
zhiwen Long ◽  
Rongrong Li ◽  
Zixin Dai ◽  
Chu Shi ◽  
Caiqin Wu ◽  
...  
Keyword(s):  
Volume Expansion ◽  
Composite Nanofibers ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Lithium Ion ◽  
Carbon Composite ◽  
High Rate ◽  
Lithium Storage ◽  
Metal Organic ◽  
Framework Compounds

In this study, necklace-like NiCo2O4@carbon composite nanofibers (NCO@CNFs) anode hatched by metal-organic frameworks, featuring low volume expansion and superior high rate properties, are prepared for anode of lithium-ion batteries. By...

Potassium Mediated Co-Fe-based Prussian Blue Analogue Architectures for Aqueous Potassium-Ion Storage

2021 ◽  
Author(s):  
Xijun Wei ◽  
Yingze Song ◽  
Donghai Wu ◽  
Xu Dong Liu ◽  
Houyang Chen ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Metal Organic Frameworks ◽  
Potassium Ion ◽  
Framework Structure ◽  
Prussian Blue Analogue ◽  
Open Framework ◽  
Ion Storage ◽  
Metal Organic ◽  
Prussian Blue Analogs ◽  
Open Framework Structure

Prussian blue analogs (PBAs) as a type of emerging metal-organic frameworks (MOFs) show great potential in the realm of aqueous potassium-ion batteries (AKIBs) owing to their open-framework structure, 3D channels...

scholarly journals Mechanochemical Access to Elusive Metal Diphosphinate Coordination Polymer

Crystals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 283 ◽  
Author(s):  
Andrea Ienco ◽  
Giulia Tuci ◽  
Annalisa Guerri ◽  
Ferdinando Costantino
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystalline Form ◽  
Framework Structure ◽  
Open Framework ◽  
Metal Organic ◽  
Two Phases ◽  
Bridge Length ◽  
Open Framework Structure

Several binary metal diphosphinate compounds (ML) have been reported for diphosphinate bonded by a single methylene fragment. In case of longer bridges, binary products are difficult to isolate in crystalline form. Here, using a solvent assisted mechano-chemistry synthesis, we report two new ML crystalline phases, one hydrated and one anhydrous. The hydrated phase is a 2D coordination polymer with an open framework structure. Its network displays a new topology for coordination polymers and metal organic frameworks. The thermal behavior of the two phases has been studied. Finally, the importance of the bridge length is discussed in view of known metal diphosphinate compounds.

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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