Adsorption of chromium(VI) and Rhodamine B by surface modified tannery waste: Kinetic, mechanistic and thermodynamic studies

2011 ◽  
Vol 186 (2-3) ◽  
pp. 1088-1096 ◽  
Author(s):  
J. Anandkumar ◽  
B. Mandal
2020 ◽  
Vol 29 (4) ◽  
pp. 2721-2730 ◽  
Author(s):  
Yixin Lu ◽  
Jiao Chen ◽  
Li Zhao ◽  
Zheng Zhou ◽  
Cheng Qiu ◽  
...  

2013 ◽  
Vol 28 (1-2) ◽  
pp. 113-122
Author(s):  
Kedar Nath Ghimire ◽  
Deepak Wagle ◽  
Suman Lal Shrestha

An effective chemically modified adsorbent based on sugarcane waste has been prepared by treating with concentrated sulphuric acid in 2:1weight/volume ratio. Thus prepared adsorbent has been found to be effective in the adsorption of chromium from aqueous medium. The efficacy of the adsorbent in the removal of chromium was evaluated by batch adsorption method. The effect of initial concentration, contact time and pH of the solution was investigated. The maximum adsorption capacity onto this adsorbent was found to be 195 mg/g at their optimal pH 1 at which unmodified bagasse has only 58 mg/g. The characterization of adsorbent was done by determining surface area and Boehm’s titration method. Freundlich isotherm and pseudo-second order kinetic model gave better explanation of the adsorption process.


2011 ◽  
Vol 1352 ◽  
Author(s):  
Emilly A. Obuya ◽  
William Harrigan ◽  
Tim O’Brien ◽  
Dickson Andala ◽  
Eliud Mushibe ◽  
...  

ABSTRACTThe synthesis and application of environmentally benign, efficient and low cost heterogeneous catalysts is increasingly important for affordable and clean chemical technologies. Nanomaterials have been proposed to have new and exciting properties relative to their bulk counterparts due to the quantum level interactions that exist at nanoscale. These materials also offer enormous surface to volume ratios that would be invaluable in heterogeneous catalysis. Recent studies point at titanium dioxide nanomaterials as having strong potential to be applied in heterogeneous photocatalysis for environmental remediation and pollution control. This work reports the use of surface modified anatase TiO2 nanofibers with rhodium (Rh) nanoparticles in the photodegradation of rhodamine B (RH-B), an organic pollutant. The dimensions of TiO2 nanofibers were 150±50 nm in diameter and the size of the Rh nanoparticles was ~5 nm. The Rh-doped TiO2 catalyst exhibited an enhanced photocatalytic activity in photodegradation of rhodamine B under visible light irradiation, with 95 % degradation within 180 minutes reaction time. Undoped TiO2 did not show any notable phocatalytic activity under visible light.


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