Sulfidated nano-scale zerovalent iron is able to effectively reduce in situ hexavalent chromium in a contaminated aquifer

2021 ◽  
Vol 405 ◽  
pp. 124665
Author(s):  
Miroslav Brumovský ◽  
Jana Oborná ◽  
Petr Lacina ◽  
Michal Hegedüs ◽  
Ondra Sracek ◽  
...  
Keyword(s):  
Hexavalent Chromium ◽  
Zerovalent Iron ◽  
Contaminated Aquifer ◽  
Nano Scale

scholarly journals Biotic and Abiotic Biostimulation for the Reduction of Hexavalent Chromium in Contaminated Aquifers

Water ◽  
2022 ◽  
Vol 14 (1) ◽  
pp. 89
Author(s):  
Andriani Galani ◽  
Daniel Mamais ◽  
Constantinos Noutsopoulos ◽  
Petra Anastopoulou ◽  
Alexia Varouxaki
Keyword(s):  
Microbial Communities ◽  
Hexavalent Chromium ◽  
Soil Column ◽  
Carbon Sources ◽  
Anaerobic Respiration ◽  
Electron Donors ◽  
Natural Soil ◽  
Contaminated Aquifer ◽  
Reducing Bacteria

Hexavalent chromium is a carcinogenic heavy metal that needs to be removed effectively from polluted aquifers in order to protect public health and the environment. This work aims to evaluate the reduction of Cr(VI) to Cr(III) in a contaminated aquifer through the stimulation of indigenous microbial communities with the addition of reductive agents. Soil-column experiments were conducted in the absence of oxygen and at hexavalent chromium (Cr(VI)) groundwater concentrations in the 1000–2000 μg/L range. Two carbon sources (molasses and EVO) and one iron electron donor (FeSO4·7H2O) were used as ways to stimulate the metabolism and proliferation of Cr(VI) reducing bacteria in-situ. The obtained results indicate that microbial anaerobic respiration and electron transfer can be fundamental to alleviate polluted groundwater from hazardous Cr(VI). The addition of organic electron donors increased significantly Cr(VI) reduction rates in comparison to natural soil attenuation rates. Furthermore, a combination of organic carbon and iron electron donors led to a longer life span of the remediation process and thus increased total Cr(VI) removal. This is the first study to investigate biotic and abiotic Cr(VI) removal by conducting experiments with natural soil and by applying biostimulation to modify the natural existing microbial communities.

On-site and in situ bioremediation of wood-preservative contaminated groundwater

2000 ◽  
Vol 42 (5-6) ◽  
pp. 371-376 ◽  
Author(s):  
J.A. Puhakka ◽  
K.T. Järvinen ◽  
J.H. Langwaldt ◽  
E.S. Melin ◽  
M.K. Männistö ◽  
...  
Keyword(s):  
Iron Oxidation ◽  
Wood Preservative ◽  
Pilot Scale ◽  
High Rate ◽  
Contaminated Groundwater ◽  
Groundwater Temperature ◽  
In Situ Bioremediation ◽  
Contaminated Aquifer ◽  
Fluidized Bed Process

This paper reviews ten years of research on on-site and in situ bioremediation of chlorophenol contaminated groundwater. Laboratory experiments on the development of a high-rate, fluidized-bed process resulted in a full-scale, pump-and-treat application which has operated for several years. The system operates at ambient groundwater temperature of 7 to 9°C at 2.7 d hydraulic retention time and chlorophenol removal efficiencies of 98.5 to 99.9%. The microbial ecology studies of the contaminated aquifer revealed a diverse chlorophenol-degrading community. In situ biodegradation of chlorophenols is controlled by oxygen availability, only. Laboratory and pilot-scale experiments showed the potential for in situ aquifer bioremediation with iron oxidation and precipitation as a potential problem.

Remediation of PCE-contaminated aquifer by an in situ two-layer biobarrier: laboratory batch and column studies

2003 ◽  
Vol 37 (1) ◽  
pp. 27-38 ◽  
Author(s):  
C.M Kao ◽  
S.C Chen ◽  
J.Y Wang ◽  
Y.L Chen ◽  
S.Z Lee
Keyword(s):  
Column Studies ◽  
Contaminated Aquifer

scholarly journals Removal of hexavalent chromium from wastewater by Cu/Fe bimetallic nanoparticles

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jien Ye ◽  
Yi Wang ◽  
Qiao Xu ◽  
Hanxin Wu ◽  
Jianhao Tong ◽  
...  
Keyword(s):  
Hexavalent Chromium ◽  
Removal Efficiency ◽  
Photoelectron Spectroscopy ◽  
Bimetallic Nanoparticles ◽  
Chemical Reduction ◽  
Particle Surface ◽  
Zerovalent Iron ◽  
Order Model ◽  
X Ray ◽  
Nanoscale Zerovalent Iron

AbstractPassivation of nanoscale zerovalent iron hinders its efficiency in water treatment, and loading another catalytic metal has been found to improve the efficiency significantly. In this study, Cu/Fe bimetallic nanoparticles were prepared by liquid-phase chemical reduction for removal of hexavalent chromium (Cr(VI)) from wastewater. Synthesized bimetallic nanoparticles were characterized by transmission electron microscopy, Brunauer–Emmet–Teller isotherm, and X-ray diffraction. The results showed that Cu loading can significantly enhance the removal efficiency of Cr(VI) by 29.3% to 84.0%, and the optimal Cu loading rate was 3% (wt%). The removal efficiency decreased with increasing initial pH and Cr(VI) concentration. The removal of Cr(VI) was better fitted by pseudo-second-order model than pseudo-first-order model. Thermodynamic analysis revealed that the Cr(VI) removal was spontaneous and endothermic, and the increase of reaction temperature facilitated the process. X-ray photoelectron spectroscopy (XPS) analysis indicated that Cr(VI) was completely reduced to Cr(III) and precipitated on the particle surface as hydroxylated Cr(OH)3 and CrxFe1−x(OH)3 coprecipitation. Our work could be beneficial for the application of iron-based nanomaterials in remediation of wastewater.

Removal of heavy metal from soil and groundwater by in-situ electrokinetic remediation

2000 ◽  
Vol 42 (7-8) ◽  
pp. 335-343 ◽  
Author(s):  
S. Shiba ◽  
S. Hino ◽  
Y. Hirata ◽  
T. Seno
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Electric Potential ◽  
Potential Gradient ◽  
Electrokinetic Remediation ◽  
Contaminated Aquifer ◽  
Physico Chemical ◽  
Operational Variables ◽  
Mass Transport Process

The operational variables of electrokinetic remediation have not been cleared yet, because this method is relatively new and is an innovative technique in the aquifer remediation. In order to investigate the operational variables of the electrokinetic remediation, a mathematical model has been constructed based on the physico chemical mass transport process of heavy metals in pore water of contaminated aquifer. The transport of the heavy metals is driven not only by the hydraulic flow due to the injection of the purge water but also by the electromigration due to the application of the electric potential gradient. The electric potential between anode and cathode is the important operational variable for the electrokinetic remediation. From the numerical simulations with use of this model it is confirmed that the remediation starts from the up stream anode and gradually the heavy metal is transported to the down stream cathode and drawn out through the purge water.

Fabrication of Nanoscale Homogeneous Lead Azide@Carbon Fiber Film with Low Electrostatic Sensitivity by In-situ Synthesis

2021 ◽  
Author(s):  
Zhenzhan Yan ◽  
Li Yang ◽  
Ji-Min Han ◽  
Haojie Li ◽  
Junda Huo
Keyword(s):  
Carbon Fiber ◽  
Lead Acetate ◽  
In Situ Synthesis ◽  
Raw Material ◽  
Lead Azide ◽  
Nano Scale ◽  
Carbon Based

In this work, a nano-scale carbon-based lead azide initiating film was prepared by electrospinning, carbonization, azide, and other steps using cheap and easily available lead acetate as the raw material....

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