Effects of a carbon monoxide-dominant gas mixture on the explosion and flame propagation behaviors of methane in air

2019 ◽  
Vol 58 ◽  
pp. 8-16 ◽  
Author(s):  
Zhenmin Luo ◽  
Litao Liu ◽  
Fangming Cheng ◽  
Tao Wang ◽  
Bin Su ◽  
...  
1981 ◽  
Vol 50 (5) ◽  
pp. 1061-1064 ◽  
Author(s):  
D. Z. Rubin ◽  
D. Fujino ◽  
C. Mittman ◽  
S. M. Lewis

The existence of a saturable carbon monoxide (CO) carrier in the lung remains controversial. The carrier hypothesis was invoked to explain data that indicated that pulmonary diffusing capacity for CO (DLCO) decreases with increasing CO concentration. To test this hypothesis, we measured DLCO in 14 normal adult subjects at three alveolar CO concentrations (60, 660, and 2,060 ppm). Each mixture contained a constant amount of labeled C18O (60 ppm) and a balance of unlabeled C16O. If a saturable carrier exists at increasing CO concentrations, the unlabeled CO would compete for most of the sites on the carrier molecule, effectively inhibiting the uptake of the labeled C18O. C18O diffusing capacities (mean +/- SD) for the three levels of CO were 34.9 +/- 5.6, 33.0 +/- 6.0, and 34.7 +/- 7.8. There were no significant differences (P greater than 0.2) among the three levels. In another group of subjects we repeated the study using a gas mixture containing 130 ppm C18O. No significant differences were found. As a result, we find no evidence to support a CO carrier hypothesis.


1988 ◽  
Vol 74 (1) ◽  
pp. 29-36 ◽  
Author(s):  
Andrew R. Guyatt ◽  
Andrew J. T. Kirkham ◽  
Derek C. Mariner ◽  
Gordon Cumming

1. We measured alveolar carbon monoxide (CO) after a 20 s breath-holding period and carboxyhaemoglobin both before and after smoking a cigarette on 500 occasions (101 individuals). The two measurements were closely correlated but there was a marked difference in the change or ‘boost’ after smoking one cigarette. The mean relative boosts ([post value—pre value]/[pre + post]/2) for alveolar CO and carboxyhaemoglobin were 7.7% and 20.3%, while negative boosts (fall rather than the expected rise) were seen in 103 of 500 and three of 500 occasions respectively. In 140 studies a third alveolar CO reading taken 5 min later was slightly larger, but the difference was insignificant. 2. In seven subjects where the carboxyhaemoglobin level was raised by breathing a 2% CO gas mixture, the alveolar CO and carboxyhaemglobin boosts were similar (71.7% and 75.2% respectively), and they fell sharply subsequently rather than increasing further as occurred after smoking. 3. We conclude that alveolar CO measurements give a useful estimate of carboxyhaemoglobin level if the subject has not smoked for at least half an hour but that measurements of alveolar CO boost are useless since the act of smoking interferes with alveolar sampling. We postulate that cigarette smoking induces a transient change in pulmonary gas exchange.


Author(s):  
William Payman ◽  
H. Titman ◽  
Jocelyn Field Thorpe

This series of papers has so far dealt mainly with non-maintained or partially maintained atmospheric shock waves, and only incidentally with the fully maintained "detonation" wave. It is generally accepted that the detonation wave in an explosive gas mixture is a shock wave produced by the rapid combustion of the mixture, sufficiently intense to cause almost instantaneous ignition of the gas through which it passes, and continuous maintained by the combustion thereby started. An account of some preliminary experiments, using the "wave-speed" camera to record the movement of the flame and of the invisible shock waves in front of the flame in gas mixtures prior to detonation, has already been given by one of us. Those experiments related mainly to hydrogen-oxygen and methane-oxygen mixtures whose aptitude to detonate may be regarded as moderate, for the continuation of the work, mixtures with oxygen have again been used, but a more readily detonating gas, ethylene, was chosen. Experiments were also made with carbon monoxide, because the flame usually requires a comparatively long run before detonation is established. These two gases have the advantage, not shared by hydrogen and methane, that their predetonation flames are sufficiently actinic for good records to be obtained by direct photography for comparison with corresponding "wave-speed" records. All gas mixtures used were saturated with water vapour.


2014 ◽  
Vol 1644 ◽  
Author(s):  
Renate Kellermann ◽  
Dan Taroata ◽  
Martin Schiemann ◽  
Helmut Eckert ◽  
Peter Fischer ◽  
...  

ABSTRACTIn this work, electrochemically recyclable lithium is analyzed as high energy density, large scale storage material for stranded renewable energy in a closed loop. The strongly exothermic reaction of lithium with carbon dioxide (CO2) yields thermal energy directly comparable to the combustion of coal or methane in an oxygen containing atmosphere. The thermal level of the reaction is sufficient for re-electrification in a thermal power plant compatible process.The reaction of single lithium particles, avoiding particle-particle interactions, is compared to the combustion of atomized lithium spray in a CO2 containing atmosphere. Particle temperatures of up to 4000K were found for the reaction of single lithium particles in a CO2, nitrogen (N2), oxygen (O2) and steam gas mixture. Furthermore the combustion of atomized lithium spray in both dry CO2 atmosphere and CO2/steam gas mixture was analyzed. The identified solid reaction products are lithium carbonate, lithium oxide and lithium hydroxide. The formation of carbon monoxide (CO) as gaseous reaction product is demonstrated. Carbon monoxide is a valuable by-product, which could be converted to methanol or gasoline using hydrogen.


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