Composite salt corrosion deterioration characteristics and damage calculation models of concrete incorporated with corrosion inhibiting admixtures

2021 ◽  
pp. 103221
Author(s):  
Hang Meiyan ◽  
Jiang Minghui ◽  
Zhao Wenlei ◽  
Yang Yubin ◽  
Cheng Teng ◽  
...  
2019 ◽  
pp. 43-48
Author(s):  
Ben Nengjun ◽  
Zhou Pengfei ◽  
Oleksandr Labartkava ◽  
Mykhailo Samokhin

This work involves an analysis of high-chromium high-temperature deformable wieldable nickel alloys for use in GTE repair assemblies. It is shown that the alloys EP868 (VZh98) and Haynes 230 can be used in welded assemblies with an operating temperature of 800-1100 °C. The alloys Nimonic 81, Nimonic 91, IN 935, IN 939, and Nicrotan 2100 GT also have a high potential for use in welded assemblies. They are characterized by a combination of good weldability, high-temperature strength, and resistance to scaling. There have been conducted studies on high-temperature salt corrosion of model nickel alloys. They allowed establishing the patterns of the impact of base metal alloying with chromium, aluminum, titanium, cobalt, tungsten, molybdenum, niobium, tantalum and rare earth metals on the critical temperature of the start of salt corrosion Tcor and the alloy mass loss. It has been established that alloys with a moderate concentration (13-16%) of chromium can possess satisfactory hightemperature corrosion resistance (HTC resistance) under the operating conditions of ship GTE. The HTC resistance of CrAl-Ti alloys improves upon reaching the ratio Ti/Al ˃ 1. Meanwhile, the ratio Ti/Al ˂ 1 promotes the formation of corrosion products with low protective properties. The positive effect of tantalum on the HTC resistance of alloys is manifested at higher test temperatures than that of titanium, and the total content of molybdenum and tungsten in alloys is limited by the condition 8Mo2 – 2W2 = 89. The presence of refractory elements stabilizes the strengthening phase and prevents formation of the ɳ-phase. However, their excess promotes formation of the embrittling topologically close packed (TCP) phases and boundary carbides of an unfavorable morphology. Based on the studies of the HTC resistance, there has been identified a class of model high-temperature corrosionresistant nickel alloys with a moderate or high chromium content (30%), Ti/Al ˃ 1, and a balanced content of refractory and rare-earth elements.


1994 ◽  
Vol 29 (3) ◽  
pp. 95-106
Author(s):  
Alfred P. Benoist ◽  
Gerard H. Broseliske

For priority pollutants, the international Rhine Action Programme (RAP) aims to meet the quality objectives for the Rhine, set by the International Rhine Commission (IRC), by the year 2000. An assessment must be carried out to define additional measures exceeding best available technology (BAT) for point sources and best environmental practice (BEP) for diffuse sources for those priority pollutants still violating the quality objectives of the Rhine after implementing BAT and BEP only. To carry out the required assessments, an excessive amount of work and money is needed, including the application of sophisticated calculation models. For prioritizing reasons, the Institute for Inland Water Management and Waste Water Treatment (RIZA) initiated a project called EVER, which was conducted by DHV Water BV. EVER is the abbreviation of the Dutch equivalent for Effective Distribution of Emission Reductions (Effective Verdeling van Emissie Reducties). The aim of this project is to carry out a first and crude evaluation of the impact of abatement measures (BAT and BEP), as set by the IRC for the period 1985-1995. For those pollutants still showing a violation of the quality objectives for the Rhine in the year 1995, a range finding method is used, to predict the costs and impact of abatement measures exceeding BAT and BEP on the water quality of the Rhine. So, EVER is a management tool to prioritize the work to be done within the frame-work of the IRC, triggering the application of e.g. sophisticated calculation models for a selected number of priority pollutants. In EVER, the prognosis of the reduction of specific discharge rates for approximately forty priority pollutants is given for twelve sub-catchment areas for the year 1995. This prognosis is used to predict concentrations at eight international monitoring locations in the Rhine basin, using the discharges and concentrations of the year 1985 as a reference. The predicted concentrations for the year 1995 are compared with the (preliminary) water quality objectives as set by the IRC. The results indicate, that for six of the selected pollutants the number of available data is too small for sound predictions. Fifteen of the selected pollutants will satisfy the water quality objectives in 1995. Twenty (half) of the selected pollutants will still violate the quality objectives at several monitoring locations. These twenty pollutants are the basis for priorities to be set within the frame-work of the IRC for phase 3 (1995-2000) of the RAP. For these pollutants, additional abatement measures exceeding BAT and BEP are selected in EVER for the manageable groups of sources (anthropogenic non-point sources, industrial sources and municipal sources). Each measure is analyzed separately for costs and effectiveness. Finally the results of this project are integrated into a matrix system which will enable us to select the most effective mix of pollution abatement measures at the lowest costs. The result of the selected additional measures exceeding BAT and BEP shows that 17 pollutants will still violate the quality objectives.


Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 543
Author(s):  
Ketan Kumar Sandhi ◽  
Jerzy Szpunar

Nickel superalloy Hastelloy-N, alloy X-750, stainless steel 316 (SS316), and stainless steel 304 (SS304) are among the alloys used in the construction of molten salt reactor (MSR). These alloys were analyzed for their corrosion resistance behavior in molten fluoride salt, a coolant used in MSR reactors with 46.5% LiF+ 11.5% NaF+ 42% KF. The corrosion tests were run at 700 °C for 100 h under the Ar cover gas. After corrosion, significant weight loss was observed in the alloy X750. Weight loss registered in SS316 and SS304 was also high. However, Hastelloy-N gained weight after exposure to molten salt corrosion. This could be attributed to electrochemical plating of corrosion products from other alloys on Hastelloy-N surface. SEM–energy-dispersive X-ray spectroscopy (EDXS) scans of cross-section of alloys revealed maximum corrosion damage to the depth of 250 µm in X750, in contrast to only 20 µm on Hastelloy-N. XPS wide survey scans revealed the presence of Fe, Cr, and Ni elements on the surface of all corroded alloys. In addition, Cr clusters were formed at the triple junctions of grains, as confirmed by SEM–EBSD (Electron Back Scattered Diffraction) analysis. The order of corrosion resistance in FLiNaK environment was X750 < SS316 < SS304 < Hastelloy-N.


2021 ◽  
Vol 1885 (3) ◽  
pp. 032005
Author(s):  
Dandan Men ◽  
Jian Xiong ◽  
Wenyi Peng ◽  
Lingyun Bai

2012 ◽  
Vol 35 (1) ◽  
pp. 135-145 ◽  
Author(s):  
Leonilde Roselli ◽  
Elena Stanca ◽  
Francesco Paparella ◽  
Annunziata Mastrolia ◽  
Alberto Basset

CORROSION ◽  
2001 ◽  
Vol 57 (6) ◽  
pp. 489-496 ◽  
Author(s):  
M. Amaya ◽  
J. Porcayo-Calderon ◽  
L. Martinez

Abstract The performance of Fe-Si coatings and an iron aluminide (FeAl) intermetallic alloy (FeAl40at%+0.1at%B+10vol%Al2O3) in molten salts containing vanadium pentoxide (V2O5) and sodium sulfate (Na2SO4) is reported. Corrosion and fouling by ash deposits containing V2O5 and Na2SO4 are typical corrosion problems in fuel oil-fired electric power units. High-temperature corrosion tests were performed using both electrochemical polarization and immersion techniques. The temperature interval of this study was 600°C to 900°C, and the molten salts were 80wt%V2O5-20wt%Na2SO4. Curves of corrosion current density vs temperature obtained by the potentiodynamic studies are reported, as well as the weight loss vs temperature curves from molten salt immersion tests. Both Fe-Si coatings and FeAl40at%+0.1at%B+10vol%Al2O3 showed good behavior against molten salt corrosion. The final results show the potential of these coatings and alloys to solve the high-temperature corrosion in fuel oil-fired electric power units.


2013 ◽  
Vol 303-306 ◽  
pp. 2203-2206
Author(s):  
Cai Li Fang ◽  
Lin Wu

As a important part of teaching, Traditional paper analysis algorithm is complicated and not comprehensive enough. This paper according to the indicators of education measurement and improves the traditional calculation models, the system assesses the perfect calculation model, The teacher also can get the true and fast reaction to students' knowledge and the quality of the paper. This method thereby provides a convincing basis for the improvement on the future teaching and increase the effectiveness in teaching


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