Preparation of Co-Mo/γ-Al2O3 catalyst and the catalytic hydrogenation effects on coal-related model compounds

2021 ◽  
Vol 96 ◽  
pp. 52-60
Author(s):  
Hao Xu ◽  
Xing Fan ◽  
Guo-Sheng Li ◽  
Yang-Yang Xu ◽  
Wen-Long Mo ◽  
...  
2014 ◽  
Vol 4 (4) ◽  
pp. 1132-1143 ◽  
Author(s):  
Zhangping Shi ◽  
Xiuzhen Xiao ◽  
Dongsen Mao ◽  
Guanzhong Lu

Efficient catalytic hydrogenation of l-phenylalanine methyl ester to l-phenylalaninol over the Cu/ZnO/Al2O3 catalyst with ~100% ee selectivity.


2018 ◽  
Vol 67 ◽  
pp. 02045
Author(s):  
SD Sumbogo Murti ◽  
J. Prasetyo ◽  
G.W. Murti ◽  
Z. D. Hastuti ◽  
F. M. Yanti

The attractiveness of biodiesel as an alternative fuel compared to fossil fuels because it has many advantages such as the availability of abundant raw materials, more environmentally friendly, high combustion efficiency, low sulphur content, high cetane number and biodegradability. Making biodiesel from straight vegetable oil (VGO) has been done through the catalytic hydrogenation process. A VGO of callophylum inophyllum oil was treated via degumming and neutralisation to remove all impurities before hydroprocessing. Hydroprocessing was carried out in a 500ml autoclave at 30 – 50 MPa of initial hydrogen pressure, 300 – 400oC of reaction temperature and equipped with stirrer and cooling system. NiMo/Al2O3 catalyst was activated with CS2 mixture at 370oC prior to the reaction. Some physical and chemical properties of the catalytic hydroprocessing product have been investigated in accordance to ASTM standard. The measurement result of product varies according to the operation condition. The result showed that callophyllum inophyllum oil can be used as raw material for biodiesel production over NiMo/Al2O3. Sulfided NiMo/Al2O3 catalysts are preferred due to high diesel yield.


1977 ◽  
Vol 55 (5) ◽  
pp. 782-784 ◽  
Author(s):  
Larry D. Pedersen ◽  
Larry Weiler

4,4′-Bis(dicyanomethylene)bicyclohexylidine and its dihydro derivative, 4,4′-bis(dicyanomethylene)bicyclohexyl were prepared from the condensation of malononitrile with the corresponding diketone. Bicyclohexylidene-4,4′-dione was synthesized from the monoketal of cyclohexanedione via the symmetric azosulfide.The uv spectra of the 4,4′-bis(dicyanomethylene)bicyclohexylidine and related model compounds indicate the presence of a long range interaction between the dicyanomethylene groups of the title compound.


Fuel ◽  
2014 ◽  
Vol 117 ◽  
pp. 556-563 ◽  
Author(s):  
Shou-Ze Wang ◽  
Xing Fan ◽  
Ai-Li Zheng ◽  
Yu-Gao Wang ◽  
You-Quan Dou ◽  
...  

1958 ◽  
Vol 80 (5) ◽  
pp. 1109-1113 ◽  
Author(s):  
Jui H. Wang ◽  
Akitsugu Nakahara ◽  
Everly B. Fleischer

1977 ◽  
Vol 55 (18) ◽  
pp. 3304-3311 ◽  
Author(s):  
Donald W. Hughes ◽  
Bala C. Nalliah ◽  
Herbert L. Holland ◽  
David B. MacLean

The natural abundance 13C nuclear magnetic resonance spectra of a number of spirobenzylisoquinoline alkaloids and related model compounds have been recorded. The carbon resonances of the alkaloids were assigned by comparison with the spectra of other isoquinoline alkaloids and with those of the model compounds. It has been shown that 13C nmr spectroscopy may be used to differentiate between diastereomers in this series.


2018 ◽  
Vol 32 (16) ◽  
pp. 1462-1472 ◽  
Author(s):  
Guo-Sheng Li ◽  
Xueming Dong ◽  
Xing Fan ◽  
Chun-Yan You ◽  
Ge Wu ◽  
...  

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