A photoluminescent molecular host with aggregation-induced emission enhancement, multi-stimuli responsive properties and tunable photoluminescence host-guest interaction in the solid state

Author(s):  
Hamideh Nikookar ◽  
Parviz Rashidi-Ranjbar
2021 ◽  
Vol 903 ◽  
pp. 168-173
Author(s):  
Elmārs Zariņš ◽  
Deins Alksnis ◽  
Patricija Paulsone ◽  
Karlis Balodis ◽  
Aivars Vembris ◽  
...  

In order to develop reliable methods for the synthesis of various 5-substituted-8-oxyquinoline derivatives for the preparation of Alq3-type complexes, we have improved the reaction conditions on some syntheses described in the literature, successfully synthesized new ligands based on quinolin-8-ol and characterized their chemical structures by NMR. Some of the synthesized quinolin-8-ol derivatives containing incorporated bulky triphenyl or tert-butyl groups showed blue luminescence in the solid state due to the possible aggregation induced emission enhancement (AIEE) with a maximum wavelength around 510 nm. More detailed light-emission property investigation of the mentioned bulky group containing compounds is currently underway.


RSC Advances ◽  
2016 ◽  
Vol 6 (39) ◽  
pp. 32697-32704 ◽  
Author(s):  
Yong Zhan ◽  
Peng Gong ◽  
Peng Yang ◽  
Zhe Jin ◽  
Ying Bao ◽  
...  

Conjugated organic molecules exhibiting AIE are characterized by the strongly twisted conjugated skeleton, which could provide loose intermolecular stacking and weak π–π interactions in the solid state to generate stimuli-responsive materials.


2017 ◽  
Vol 1 (9) ◽  
pp. 1804-1817 ◽  
Author(s):  
Tristan Butler ◽  
Fang Wang ◽  
Michal Sabat ◽  
Cassandra L. Fraser

Dimethylamino β-diketones with electron donating and withdrawing substituents displayed solvatochromism and aggregation induced emission. In the solid state, a blue to orange color range and thermal and mechanoresponsive properties were achieved.


CrystEngComm ◽  
2015 ◽  
Vol 17 (3) ◽  
pp. 498-502 ◽  
Author(s):  
Katarzyna Ostrowska ◽  
Łukasz Dudek ◽  
Jarosław Grolik ◽  
Marlena Gryl ◽  
Katarzyna Stadnicka

The article describes the synthesis of selective dual emissive intramolecular charge transfer (ICT) receptor for zinc ion in acetonitrile, exhibiting aggregation induced emission enhancement (AIEE) in solid state.


2015 ◽  
Vol 44 (7) ◽  
pp. 3326-3341 ◽  
Author(s):  
Yasuhiro Kubota ◽  
Kouhei Kasatani ◽  
Hiroki Takai ◽  
Kazumasa Funabiki ◽  
Masaki Matsui

Although non-, trifluoromethyl-, and cyano-substituted derivatives showed AIEE effects, methoxy- and dimethylamino-substituted analogues resulted in relatively strong fluorescence in solution.


2017 ◽  
Vol 1 (10) ◽  
pp. 2013-2026 ◽  
Author(s):  
Melanie Denißen ◽  
Nithiya Nirmalananthan ◽  
Thomas Behnke ◽  
Katrin Hoffmann ◽  
Ute Resch-Genger ◽  
...  

One-pot insertion-coupling-addition synthesis gives piperazinyl indolones showing aggregation induced emission and crystallization-induced emission enhancement.


2016 ◽  
Vol 4 (14) ◽  
pp. 2793-2801 ◽  
Author(s):  
Abdelhamid Ghodbane ◽  
W. Brett Fellows ◽  
John R. Bright ◽  
Debashree Ghosh ◽  
Nathalie Saffon ◽  
...  

Most of the conjugates exhibited aggregation-induced emission enhancement, probably involving a unusual type of excimer.


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